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More info on 1,3-Diaminopropane

1,3-Diaminopropane: Wikis

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1,3-Diaminopropane
1,3-Diaminopropane.svg
IUPAC name
Other names Trimethylenediamine; TMEDA; propandiamine; 1,3-propylenediamine
Identifiers
CAS number 109-76-2 Yes check.svgY
PubChem 428
SMILES
InChI
InChI key XFNJVJPLKCPIBV-UHFFFAOYAG
ChemSpider ID 415
Properties
Molecular formula C3H10N2
Molar mass 74.12 g mol−1
Hazards
MSDS External MSDS
EU classification Toxic T Corrosive C
 Yes check.svgY (what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

1,3-Diaminopropane is a simple amine. The potassium salt is used in the alkyne zipper reaction, first reported by Charles Allen Brown and Ayako Yamashita in 1975.[1]

References

  1. ^ C. A. Brown and A. Yamashita (1975). "Saline hydrides and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide". J. Am. Chem. Soc. 97 (4): 891–892. doi:10.1021/ja00837a034.  

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