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All names before Maternus ('II') are to be approached with considerable scepticism since no contemporary evidence is available. Maternus was present at a council in Rome in 313. The bishops between Severinus and Charentius are also apocryphal. Domitianus was bishop of Maastricht (Mosa Traiectum). The given dates of office before bishop Gunther are also conjectural at best.
| Image | Name | From | To | Notes |
|---|---|---|---|---|
| Konrad von Hochstaden | 1238 | 1261 | ||
| Engelbert II von Falkenstein | 1261 | 1274 | ||
| Siegfried II of Westerburg | 1274 | 1297 | ||
| Wikbold I von Holte | 1297 | 1304 | ||
| Heinrich II von Virneburg | 1304 | 1332 | ||
| Walram von Jülich | 1332 | 1349 | ||
| Wilhelm von Gennep | 1349 | 1362 | First Elector of Cologne under the Golden Bull of 1356 | |
| Adolf II von der Marck | 1363 | 1363 | ||
| Engelbert III von der Marck | 1364 | 1369 | ||
| Kuno von Falkenstein | 1370 | 1371 | ||
| Friedrich III von Saarwerden | 1372 | 1414 | ||
| Dietrich II von Mors | 1414 | 1463 | ||
| Rupprecht of the Palatinate | 1463 | 1480 | ||
| Hermann IV of Hesse | 1480 | 1508 | ||
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Philipp II von Daun-Oberstein | 1508 | 1515 | |
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Hermann V von Wied | 1515 | 1546 | Sought to reform religious practice in the Electorate; converted to Protestantism; deposed and excommunicated. |
| Adolf III von Schauenburg | 1546 | 1556 | ||
| Anton von Schauenburg | 1556 | 1558 | ||
| Gebhard I von Mansfeld-Vorderort | 1558 | 1562 | A founding member of the Schmalkaldic League | |
| Friedrich IV von Wied | 1562 | 1567 | ||
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Salentin von Isenburg-Grenzau | 1567 | 1577 | Upon the deaths of his younger and older brothers, there were no more brothers to carry on the family name; he left Church administration in 1577, married, had two sons, and conducted a successful military career. He died in 1610. |
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Gebhard II Truchsess von Waldburg | 1577 | 1583 | Converted to Calvinism in 1582; married Agnes von Mansfeld-Eisleben (cousin once removed of the archbishop and Prince-Elector Gebhard I von Mansfeld-Vorderort); Competing archbishop elected;Cologne War war decides the outcome. |
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Ernest of Bavaria | 1583 | 1612 | Brother of William V, Duke of Bavaria; Papal Nunciate established permanently in Cologne. |
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Ferdinand of Bavaria | 1612 | 1650 | Brother of Maximilian I, Elector of Bavaria, nephew of Ernest of Bavaria. Principle of Secundogeniture. |
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Maximilian Henry of Bavaria | 1650 | 1688 | First cousin of Ferdinand Maria, Elector of Bavaria |
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Joseph Clemens of Bavaria | 1688 | 1723 | Brother of Maximilian II Emanuel, Elector of Bavaria. Put under Imperial ban for siding with France in the War of the Spanish Succession. |
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Clemens Augustus I of Bavaria | 1723 | 1761 | Brother of Charles, Elector of Bavaria and Emperor. Last Wittelsbach to hold the office. |
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Maximilian Frederick of Königsegg-Rothenfels | 1761 | 1784 | |
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Maximilian Francis of Austria | 1784 | 1801 | Electorate "secularized" in German Mediatization |
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