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Cyclosarin
Identifiers
ChemSpider 58069
SMILES
InChI
InChI key SNTRKUOVAPUGAY-UHFFFAOYAC
Properties
Molecular formula C7H14FO2P
Molar mass 180.16 g mol−1
Appearance Colorless liquid
Density 1.1278 g/cm3
Melting point

-30 °C, 243 K, -22 °F

Boiling point

239 °C, 512 K, 462 °F

Solubility in water Almost insoluble
Hazards
Flash point 94 °C
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Cyclosarin or GF (cyclohexyl methylphosphonofluoridate) is an extremely toxic substance used as a chemical weapon. It is a member of the G-series family of nerve agents, a group of chemical weapons discovered and synthesized by a German team led by Dr. Gerhard Schrader. The major nerve gases are the G agents, sarin (GB), soman, tabun, and the V agents such as VX. The original agent, tabun, was discovered in Germany in 1936 in the process of work on organophosphorus insecticides. Next came sarin, soman and finally the most toxic, VX, a product of commercial insecticide laboratories prior to World War II.

As a chemical weapon, it is classified as a weapon of mass destruction by the United Nations, according to UN Resolution 687, and its production and stockpiling was outlawed by the Chemical Weapons Convention of 1993.

Contents

Chemical characteristics

Like its predecessor sarin, cyclosarin is a liquid organophosphate nerve agent. Its physical characteristics are however quite different from sarin.

At room temperature, cyclosarin is a colorless liquid whose odor has been variously described as sweet and musty, or resembling peaches or shellac. Unlike sarin, cyclosarin is a persistent liquid, meaning that it has a low vapor pressure and therefore evaporates relatively slowly, about 69 times slower than sarin and 20 times slower than water.

Also unlike sarin, cyclosarin is flammable, with a flash point of 94°C (201 °F).

Cyclosarin also demonstrates greater toxicity than sarin (GB) in humans, with an LD50 of 5 mg (for a 70 kg human) compared to an LD50 of 1.2 mg for GF. The LCt50 of cyclosarin is 50 mg·min/m³, which is half that of GB.

History

First synthesized during World War II as part of Germany's chemical weapons research on organophosphate compounds after their military potential was discovered, cyclosarin was also studied later in the United States and Great Britain in the early 1950s as part of a systematic study of potential nerve agents. However, cyclosarin was never selected for mass production due to its having more expensive precursors than other G-series nerve agents such as sarin (GB).

To date, Iraq is the only nation known to have manufactured significant quantities of cyclosarin for use as a chemical agent and to actually deploy it in battle. During the Iran-Iraq war (1986-1988) the Iraqis used sarin and cyclosarin together as a mixture. This was likely done to obtain a more persistent chemical agent as well as in response to an existing embargo placed on alcohol precursors for sarin.[1]

Munitions

Binary weapons

Like other nerve agents, cyclosarin can be shipped in binary munitions.

A cyclosarin binary weapon would most likely contain methylphosphonyl difluoride in one capsule, with the other capsule containing either cyclohexanol or a mixture of cyclohexylamine and cyclohexanol.

GB-GF Mixtures

According to CBWInfo.com, Iraq fielded munitions filled with a mixture of GB (sarin) and GF (cyclosarin). Tests on mice indicated that GB-GF mixtures have a relative toxicity between GF and GB.

References








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