Electrostatics is the branch of science that deals with the phenomena arising from stationary or slowmoving electric charges.
Since classical antiquity it was known that some materials such as amber attract light particles after rubbing. The Greek word for amber, ήλεκτρον (electron), was the source of the word 'electricity'. Electrostatic phenomena arise from the forces that electric charges exert on each other. Such forces are described by Coulomb's law. Even though electrostatically induced forces seem to be rather weak, the electrostatic force between e.g. an electron and a proton, that together make up a hydrogen atom, is about 40 orders of magnitude stronger than the gravitational force acting between them.
Electrostatic phenomena include many examples as simple as the attraction of the plastic wrap to your hand after you remove it from a package, to the apparently spontaneous explosion of grain silos, to damage of electronic components during manufacturing, to the operation of photocopiers. Electrostatics involves the buildup of charge on the surface of objects due to contact with other surfaces. Although charge exchange happens whenever any two surfaces contact and separate, the effects of charge exchange are usually only noticed when at least one of the surfaces has a high resistance to electrical flow. This is because the charges that transfer to or from the highly resistive surface are more or less trapped there for a long enough time for their effects to be observed. These charges then remain on the object until they either bleed off to ground or are quickly neutralized by a discharge: e.g., the familiar phenomenon of a static 'shock' is caused by the neutralization of charge built up in the body from contact with nonconductive surfaces.
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The fundamental equation of electrostatics is Coulomb's law, which describes the force between two point charges. The magnitude of the electrostatic force between two point electric charges is directly proportional to the product of the magnitudes of each charge and inversely proportional to the square of the distance between the charges.Q_{1} and Q_{2}:
where ε_{0} is a constant called the permittivity of free space, a defined value:
The electric field (in units of volts per meter) at a point is defined as the force (in newtons) per unit charge (in coulombs) on a charge at that point:
From this definition and Coulomb's law, it follows that the magnitude of the electric field E created by a single point charge Q is:
The electric field produced by a distribution of charges given by the volume charge density is obtained by a triple integral of a vector function:
Gauss' law states that "the total electric flux through a closed surface is proportional to the total electric charge enclosed within the surface". The constant of proportionality is the permittivity of free space.
Mathematically, Gauss's law takes the form of an integral equation:
Alternatively, in differential form, the equation becomes
where is the divergence operator.
The definition of electrostatic potential, combined with the differential form of Gauss's law (above), provides a relationship between the potential φ and the charge density ρ:
This relationship is a form of Poisson's equation. Where is vacuum permittivity.
In the absence of unpaired electric charge, the equation becomes
which is Laplace's equation.
The validity of the electrostatic approximation rests on the assumption that the electric field is irrotational:
From Faraday's law, this assumption implies the absence or nearabsence of timevarying magnetic fields:
In other words, electrostatics does not require the absence of magnetic fields or electric currents. Rather, if magnetic fields or electric currents do exist, they must not change with time, or in the worstcase, they must change with time only very slowly. In some problems, both electrostatics and magnetostatics may be required for accurate predictions, but the coupling between the two can still be ignored.
Because the electric field is irrotational, it is possible to express the electric field as the gradient of a scalar function, called the electrostatic potential (also known as the voltage). An electric field, E, points from regions of high potential, φ, to regions of low potential, expressed mathematically as
The electrostatic potential at a point can be defined as the amount of work per unit charge required to move a charge from infinity to the given point.
The triboelectric effect is a type of contact electrification in which certain materials become electrically charged when they are brought into contact with a different material and then separated. One of the materials acquires a positive charge, and the other acquires an equal negative charge. The polarity and strength of the charges produced differ according to the materials, surface roughness, temperature, strain, and other properties. Amber, for example, can acquire an electric charge by friction with a material like wool. This property, first recorded by Thales of Miletus, was the first electrical phenomenon investigated by man. Other examples of materials that can acquire a significant charge when rubbed together include glass rubbed with silk, and hard rubber rubbed with fur.
The presence of surface charge imbalance means that the objects will exhibit attractive or repulsive forces. This surface charge imbalance, which yields static electricity, can be generated by touching two differing surfaces together and then separating them due to the phenomena of contact electrification and the triboelectric effect. Rubbing two nonconductive objects generates a great amount of static electricity. This is not just the result of friction; two nonconductive surfaces can become charged by just being placed one on top of the other. Since most surfaces have a rough texture, it takes longer to achieve charging through contact than through rubbing. Rubbing objects together increases amount of adhesive contact between the two surfaces. Usually insulators, e.g., substances that do not conduct electricity, are good at both generating, and holding, a surface charge. Some examples of these substances are rubber, plastic, glass, and pith. Conductive objects only rarely generate charge imbalance except, for example, when a metal surface is impacted by solid or liquid nonconductors. The charge that is transferred during contact electrification is stored on the surface of each object. Static electric generators, devices which produce very high voltage at very low current and used for classroom physics demonstrations, rely on this effect.
Note that the presence of electric current does not detract from the electrostatic forces nor from the sparking, from the corona discharge, or other phenomena. Both phenomena can exist simultaneously in the same system.
Natural electrostatic phenomena are most familiar as an occasional annoyance in seasons of low humidity, but can be destructive and harmful in some situations (e.g. electronics manufacturing). When working in direct contact with integrated circuit electronics (especially delicate MOSFETs), or in the presence of flammable gas, care must be taken to avoid accumulating and suddenly discharging a static charge (see electrostatic discharge).
Charge induction occurs when a negatively charged object repels electrons from the surface of a second object. This creates a region in the second object that is more positively charged. An attractive force is then exerted between the objects. For example, when a balloon is rubbed, the balloon will stick to the wall as an attractive force is exerted by two oppositely charged surfaces (the surface of the wall gains an electric charge due to charge induction, as the free electrons at the surface of the wall are repelled by the negative balloon, creating a positive wall surface, which is subsequently attracted to the surface of the balloon). You can explore the effect with a simulation of the balloon and static electricity.
Before the year 1832, when Michael Faraday published the results of his experiment on the identity of electricities, physicists thought "static electricity" was somehow different from other electrical charges. Michael Faraday proved that the electricity induced from the magnet, voltaic electricity produced by a battery, and static electricity are all the same.
Static electricity is usually caused when certain materials are rubbed against each other, like wool on plastic or the soles of shoes on carpet. The process causes electrons to be pulled from the surface of one material and relocated on the surface of the other material.
A static shock occurs when the surface of the second material, negatively charged with electrons, touches a positivelycharged conductor, or viceversa.
Static electricity is commonly used in xerography, air filters, and some automotive paints. Static electricity is a build up of electric charges on two objects that have become separated from each other. Small electrical components can easily be damaged by static electricity. Component manufacturers use a number of antistatic devices to avoid this.
When different materials are brought together and then separated, an accumulation of electric charge can occur which leaves one material positively charged while the other becomes negatively charged. The mild shock that you receive when touching a grounded object after walking on carpet is an example of excess electrical charge accumulating in your body from frictional charging between your shoes and the carpet. The resulting charge buildup upon your body can generate a strong electrical discharge. Although experimenting with static electricity may be fun, similar sparks create severe hazards in those industries dealing with flammable substances, where a small electrical spark may ignite explosive mixtures with devastating consequences.
A similar charging mechanism can occur within low conductivity fluids flowing through pipelines—a process called flow electrification. Fluids which have low electrical conductivity (below 50 picosiemens per meter, where picosiemens per meter is a measure of electrical conductivity), are called accumulators. Fluids having conductivities above 50 pS/m are called nonaccumulators. In nonaccumulators, charges recombine as fast as they are separated and hence electrostatic charge generation is not significant. In the petrochemical industry, 50 pS/m is the recommended minimum value of electrical conductivity for adequate removal of charge from a fluid.
An important concept for insulating fluids is the static relaxation time. This is similar to the time constant (tau) within an RC circuit. For insulating materials, it is the ratio of the static dielectric constant divided by the electrical conductivity of the material. For hydrocarbon fluids, this is sometimes approximated by dividing the number 18 by the electrical conductivity of the fluid. Thus a fluid that has an electrical conductivity of 1 pS/cm (100 pS/m) will have an estimated relaxation time of about 18 seconds. The excess charge within a fluid will be almost completely dissipated after 4 to 5 times the relaxation time, or 90 seconds for the fluid in the above example.
Charge generation increases at higher fluid velocities and larger pipe diameters, becoming quite significant in pipes 8 inches (200 mm) or larger. Static charge generation in these systems is best controlled by limiting fluid velocity. The British standard BS PD CLC/TR 50404:2003 (formerly BS5958Part 2) Code of Practice for Control of Undesirable Static Electricity prescribes velocity limits. Because of its large impact on dielectric constant, the recommended velocity for hydrocarbon fluids containing water should be limited to 1 m/s.
Bonding and earthing are the usual ways by which charge buildup can be prevented. For fluids with electrical conductivity below 10 pS/m, bonding and earthing are not adequate for charge dissipation, and antistatic additives may be required.
1.BS PD CLC/TR 50404:2003 Code of Practice for Control of Undesirable Static Electricity
2.NFPA 77 (2007) Recommended Practice on Static Electricity
3.API RP 2003 (1998) Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents
The principle of electrostatic induction has been harnessed to beneficial effect in industry for many years, beginning with the introduction of electrostatic industrial painting systems for the economical and even application of enamel and polyurethane paints to consumer goods, including automobiles, bicycles, and other products.
ELECTROSTATICS, the name given to that department of electrical science in which the phenomena of electricity at rest are considered. Besides their ordinary condition all bodies are capable of being thrown into a physical state in which they are said to be electrified or charged with electricity. When in this condition they become sources of electric force, and the space round them in which this force is manifested is called an " electric field " (see Electricity). Electrified bodies exert mechanical forces on each other, creating or tending to create motion, and also induce electric charges on neighbouring surfaces.
The reader possessed of no previous knowledge of electrical phenomena will best appreciate the meaning of the terms employed by the aid of a few simple experiments. For this purpose the following apparatus should be provided:  (i) two small metal teatrays and some clean dry tumblers, the latter preferably varnished with shellac varnish made with alcohol free from water; (2) two sheets of ebonite rather larger than the teatrays; (3) a rod of sealingwax or ebonite and a glass tube, also some pieces of silk and flannel; (4) a few small gilt pith balls suspended by dry silk threads; (5) a goldleaf electroscope, and, if possible, a simple form of quadrant electrometer (see Electroscope and Electrometer); (6) some brass balls mounted on the ends of ebonite penholders, and a few tin canisters. With the aid of this apparatus, the principal facts of electrostatics can be experimentally verified, as follows: Experiment I.  Place one teatray bottom side uppermost upon three warm tumblers as legs. Rub the sheet of ebonite vigorously with warm flannel and lay it rubbed side downwards on the top of the tray. Touch the tray with the finger for an instant, and lift up the ebonite without letting the hand touch the tray a second time. The tray is then found to be electrified. If a suspended gilt pith ball is held near it, the ball will first be attracted and then repelled. If small fragments of paper are scattered on the tray and:then the other tray held in the hand over them, they will fly up and down rapidly. If the knuckle is approached to the electrified tray, a small spark will be seen, and afterwards the tray will be found to be discharged or unelectrified. If the electrified tray is touched with the sealingwax or ebonite rod, it will not be discharged, but if touched with a metal wire, the hand, or a damp thread, it is discharged at once. This shows that some bodies are conductors and others nonconductors or insulators of electricity, and that bodies can be electrified by friction and impart their electric charge to other bodies. A charged conductor supported on a nonconductor retains its charge. It is then said to be insulated.
Experiment II.  Arrange two teatrays, each on dry tumblers as before. Rub the sheet of ebonite with flannel, lay it face downwards on one tray, touch that tray with the finger for a moment and lift up the ebonite sheet, rub it again, and lay it face downwards on the second tray and leave it there. Then take two suspended gilt pith balls and touch them (a) both against one tray; they will be found to repel each other; (b) touch one against one tray and the other against the other tray, and they will be found to attract each other. This proves the existence of two kinds of electricity, called positive and negative. 1 See Lord Kelvin, " Report on Electrometers and Electrostatic Measurements," Brit. Assoc. Report for 1867, or Lord Kelvin's Reprint of Papers on Electrostatics and Magnetism, p. 260.
FIG. 7.  Wilson's Electroscope.
The first teatray is positively electrified, and the second negatively. If an insulated brass ball is touched against the first tray and then against the knob or plate of the electroscope, the gold leaves will diverge. If the ball is discharged and touched against the other tray, and then afterwards against the previously charged electroscope, the leaves will collapse. This shows that the two electricities neutralize each other's effect when imparted equally to the same conductor.
Experiment III.  Let one tray be insulated as before, and the electrified sheet of ebonite held over it, but not allowed to touch the tray. If the ebonite is withdrawn without touching the tray, the latter will be found to be unelectrified. If whilst holding the ebonite sheet over the tray the latter is also touched with an insulated brass ball, then this ball when removed and tested with the electroscope will be found to be negatively electrified. The sign of the electrification imparted to the electroscope when so charged  that is, whether positive or negative  can be determined by rubbing the sealingwax rod with flannel and the glass rod with silk, and approaching them gently to the electroscope one at a time. The sealingwax so treated is electrified negatively or resinously, and the glass with positive or vitreous electricity. Hence if the electrified sealingwax rod makes the leaves collapse, the electroscopic charge is positive, but if the glass rod does the same, the electroscopic charge is negative. Again, if, whilst holding the electrified ebonite over the tray, we touch the latter for a moment and then withdraw the ebonite sheet, the tray will be found to be positively electrified. The electrified ebonite is said to act by " electrostatic induction " on the tray, and creates on it two induced charges, one of positive and the other of negative electricity. The last goes to earth when the tray is touched, and the first remains when the tray is insulated and the ebonite withdrawn.
Experiment I V.  Place a tin canister on a warm tumbler and connect it by a wire with the goldleaf electroscope. Charge positively a brass ball held on an ebonite stem, and introduce it, without touching, into the canister. The leaves of the electroscope will diverge with positive electricity. Withdraw the ball and the leaves will collapse. Replace the ball again and touch the outside of the canister; the leaves will collapse. If then the ball be withdrawn, the leaves will diverge a second time with negative electrification. If, before withdrawing the ball, after touching the outside of the canister for a moment the ball is touched against the inside of the canister, then on withdrawing it the ball and canister are found to be discharged. This experiment proves that when a charged body acts by induction on an insulated conductor it causes an electrical separation to take place; electricity of opposite sign is drawn to the side nearest the inducing body, and that of like sign is repelled to the remote side, and these quantities are equal in amount.
Table of contents 
So far we have spoken of electric charge as if it resided on the conductors which are electrified. The work of Benjamin Franklin, Henry Cavendish, Michael Faraday and J. Clerk Maxwell demonstrated, however, that all electric charge or electrification of conductors consists simply in the establishment of a physical state in the surrounding insulator or dielectric, which state is variously called electric strain, electric displacement or electric polarization. Under the action of the same or identical electric forces the intensity of this state in various insulators is determined by a quality of them called their dielectric constant, specific inductive capacity or inductivity. In the next place we must notice that electrification is a measurable magnitude and in electrostatics is estimated in terms of a unit called the electrostatic unit of electric quantity. In the absolute C.G.S. system this unit quantity is defined as follows:  If we consider a very small electrified spherical conductor, experiment shows that it exerts a repulsive force upon another similar and similarly electrified body. Cavendish and C. A. Coulomb proved that this mechanical force varies inversely as the square of the distance between the centres of the spheres. The unit of mechanical force in the " centimetre, gramme, second " (C.G.S.) system of units is the dyne, which is approximately equal to 1/981 part of the weight of one gramme. A very small sphere is said then to possess a charge of one electrostatic unit of quantity, when it repels another similar and similarly electrified body with a force of one dyne, the centres being at a distance of one centimetre, provided that the spheres are in vacuo or immersed in some insulator, the dielectric constant of which is' taken as unity. If the two small conducting spheres are placed with centres at a distance d centimetres, and immersed in an insulator of dielectric constant K, and carry charges of Q and Q' electrostatic units respectively, measured as above described, then the mechanical force between them is equal to QQ'/Kd 2 dynes. For constant charges and distances the mechanical force is inversely as the dielectric constant.
If a small conducting body is charged with Q electrostatic units of electricity, and placed in any electric field at a point where the electric force has a value E, it will be subject to a mechanical force equal to QE dynes, tending to move it in the direction of the resultant electric force. This provides us with a definition of a unit of electric force, for it is the strength of an electric field at that point where a small conductor carrying a unit charge is acted upon by unit mechanical force, assuming the dielectric constant of the surrounding medium to be unity. To avoid unnecessary complications we shall assume this latter condition in all the following discussion, which is equivalent simply to assuming that all our electrical measurements are made in air or in vacuo. Owing to the confusion introduced by the employment of the term force, Maxwell and other writers sometimes use the words electromotive intensityinstead of electric force. The reader should, however, notice that what is generally called electric force is the analogue in electricity of the socalled acceleration of gravity in mechanics, whilst electrification or quantity_of electricity is analogous to mass. If a mass of M grammes be placed in the earth's field at a place where the acceleration of gravity has a value g centimetres per second, then the mechanical force acting on it and pulling it downwards is Mg dynes. In the same manner, if an electrified body carries a positive charge Q electrostatic units and is placed in an electric field at a place where the electric force or electromotive intensity has a value E units, it is urged in the direction of the electric force with a mechanical force equal to QE dynes. We must, however, assume that the charge Q is so small that it does not sensibly disturb the original electric field, and that the dielectric constant of the insulator is unity.
Faraday introduced the important and useful conception of lines and tubes of electric force. If we consider a very small conductor charged with a unit of positive electricity to be placed in an electric field, it will move or tend to move under the action of the electric force in a certain direction. The path described by it when removed from the action of gravity and all other physical forces is called a line of electric force. We may otherwise define it by saying that a line of electric force is a line so drawn in a field of electric force that its direction coincides at every point with the resultant electric force at that point. Let any line drawn in an electric field be divided up into small elements of length. We can take the sum of all the products of the length of each element by the resolved part of the electric force in its direction. This sum, or integral, is called the " line integral of electric force" or the electromotive force (E.M.F.) along this line. In some cases the value of this electromotive force between two points or conductors is independent of the precise path selected, and it is then called the potential difference (P.D.) of the two points or conductors. We may define the term potential difference otherwise by saying that it is the work done in carrying a small conductor charged with one unit of electricity from one point to the other in a direction opposite to that in which it would move under the electric forces if left to itself.
Suppose then that we have a conductor charged with electricity,we may imagine its surface to be divided up into small unequal areas, each of which carries a unit charge of electricity. If we consider lines of electric force to be drawn from the boundaries of these areas, they will cut up the space round the conductor into tubular surfaces called tubes of electric force, and each tube will spring from an area of the conductor carrying a unit electric charge. Hence the charge on the conductor can be measured by the number of unit electric tubes springing from it. In the next place we may consider the charged body to be surrounded by a number of closed surfaces, such that the potential difference between any point on one surface and the earth is the same. These surfaces are called "equipotential" or "level surfaces," and we may so locate them that the potential difference between two adjacent surfaces is one unit of potential; that is, it requires one absolute unit of work (I erg) to move a small body charged with one unit of electricity from one surface to the next. These enclosing surfaces, therefore, cut up the space into shells of potential, and divide up the tubes of force into electric cells. The surface of a charged conductor is an equipotential surface, because when the electric charge is in equilibrium there is no tendency for electricity to move from one part to the other.
We arbitrarily call the potential of the earth zero, since all potential difference is relative and there is no absolute potential any more than absolute level. We call the difference of potential between a charged conductor and the earth the potential of the conductor. Hence when a body is charged positively its potential is raised above that of the earth, and when negatively it is lowered beneath that of the earth. Potential in a certain sense is to electricity as difference of level is to liquids or difference of temperature to heat. It must be noted, however, that potential is a mere mathematical concept, and has no objective existence like difference of level, nor is it capable per se of producing physical changes in bodies, such as those which are brought about by rise of temperature, apart from any question of difference of temperature. There is, however, this similarity between them. Electricity tends to flow from places of high to places of low potential, water to flow down hill, and heat to move from places of high to places of low temperature. Returning to the case of the charged body with the space around it cut up into electric cells by the tubes of force and shells of potential, it is obvious that the number of these cells is represented by the product QV, where Q is the charge and V the potential of the body in electrostatic units. An electrified conductor is a store of energy, and from the definition of potential it is clear that the work done in increasing the charge q of a conductor whose potential is v by a small amount dq, is vdq, and since this added charge increases in turn the potential, it is easy to prove that the work done in charging a conductor with Q units to a potential V units is z QV units of work. Accordingly the number of electric cells into which the space round is cut up is equal to twice the energy stored up, or each cell contains half a unit of energy. This harmonizes with the fact that the real seat of the energy 3f electrification is the dielectric or insulator surrounding the charged conductor.' We have next to notice three important facts in electrostatics and some consequences flowing therefrom.
(i) Electrical Equilibrium and Potential.  If there be any number of charged conductors in a field, the electrification on them being in equilibrium or at rest, the surface of each conductor is an equipotential surface. For since electricity tends to move between points or conductors at different potentials, if the electricity is at rest on them the potential must be everywhere the same. It follows from this that the electric force at the surface of the conductor has no component along the surface, in other words, the electric force at the bounding surface of the conductor and insulator is everywhere at right angles to it.
By the surface density of electrification on a conductor is meant the charge per unit of area, or the number of tubes of electric force which spring from unit area of its surface. Coulomb proved experimentally that the electric force just outside a conductor at any point is proportional to the electric density at that point. It can be shown that the resultant electric force normal to the surface at a point just outside a conductor is 1 See Maxwell, Elementary Treatise on Electricity (Oxford, 1881), P. 47.
equal to 47ro, where ois the surface density at that point. This is usually called Coulomb's Law.2 (ii) Seat of Charge.  The charge on an electrified conductor is wholly on the surface, and there is no electric force in the interior of a closed electrified conducting surface which does not contain any other electrified bodies. Faraday proved this experimentally (see Experimental Researches, series xi. § 1173) by constructing a large chamber or box of paper covered with tinfoil or thin metal. This was insulated and highly electrified. In the interior no trace of electric charge could be found when tested by electroscopes or other means. Cavendish proved it by enclosing a metal sphere in two hemispheres of thin metal held on insulating supports. If the sphere is charged and then the jacketing hemispheres fitted on it and removed, the sphere is found to be perfectly discharged. 3 Numerous other demonstrations of this fact were given by Faraday. The thinnest possible spherical shell of metal, such as a sphere of insulator coated with goldleaf, behaves as a conductor for static charge just as if it were a sphere of solid metal. The fact that there is no electric force in the interior of such a closed electrified shell is one of the most certainly ascertained facts in the science of electrostatics, and it enables us to demonstrate at once that particles of electricity attract and repel each other with a force which is inversely as the square of their distance.
We may give in the first place an elementary proof of the converse proposition by the aid of a simple lemma: Lemma.  If particles of matter attract one another according to the law of the inverse square the attraction of all sections of a cone for a particle at the vertex is the same. Definition.  The solid angle subtended by any surface at a point is measured by the quotient of its apparent surface by the square of its distance from that point. Hence the total solid angle round any point is 47r. The solid angles subtended by all normal sections of a cone at the vertex are therefore equal, and since the attractions of these sections on a particle at the vertex are proportional to their distances from the vertex, they are numerically equal to one another and to the solid angle of the cone.
Let us then suppose a spherical shell 0 to be electrified. Select any point P in the interior and let a line drawn through it sweep out a small double cone (see fig. I). Each cone cuts out an area on the surface equally inclined to the cone axis. The electric density on the sphere being uniform, the quantities of electricity on these areas are proportional to the areas, and if the electric force varies inversely as the square of the distance, the forces exerted by these two surface charges at the point in question are proportional to the solid angle of the little cone. Hence the forces due to the two areas at opposite ends of the chord are equal and opposed. Hence we see that if the whole surface of the sphere is divided into pairs of elements by cones described through any interior point, the resultant force at that point must consist of the sum of pairs of equal and opposite forces, and is therefore zero. For the proof of the converse proposition we must refer the reader to the Electrical Researches of Cavendish, p. 419, or to Maxwell's Treatise on Electricity and Magnetism, 2nd ed., vol. i. p. 76, where Maxwell gives an elegant proof that if the force in the interior of a closed conductor is zero, the law of the force must be that of the inverse square of the distance.' From this fact it follows that we can shield any conductor entirely from external influence by other "charged conductors by enclosing it in a metal case. It is not even necessary that 2 See Maxwell, Treatise on Electricity and Magnetism (3rd ed., Oxford, 1892), vol. i. p. 80.
Maxwell, Ibid. vol. i. § 74a; also Electrical Researches of the Hon. Henry Cavendish, edited by J. Clerk Maxwell (Cambridge, 1879), 104.
P 4 Lplace (Mec. Cel. vol. i. ch. ii.) gave the first direct demonstration that no function of the distance except the inverse square can satisfy the condition that a uniform spherical shell exerts no force on a particle within it.
FIG. I.
this envelope should be of solid metal; a cage made of fine metal wire gauze which permits objects in its interior to be seen will yet be a perfect electrical screen for them. Electroscopes and electrometers, therefore, standing in proximity to electrified bodies can be perfectly shielded from influence by enclosing them in cylinders of metal gauze.
Even if a charged and insulated conductor, such as an open canister or deep cup, is not perfectly closed, it will be found that a proofplane consisting of a small disk of gilt paper carried at the end of a rod of gumlac will not bring away any charge if applied to the deep inside portions. In fact it is curious to note how large an opening may be made in a vessel which yet remains for all electrical purposes " a closed conductor." Maxwell (Elementary Treatise, &c., p. 15) ingeniously applied this fact to the insulation of conductors. If we desire to insulate a metal ball to make it hold a charge of electricity, it is usual to do so by attaching it to a handle or stem of glass or ebonite. In this case the electric charge exists at the point where the stem is attached, and there leakage by creeping takes place. If, however, we employ a hollow sphere and let the stem pass through a hole in the side larger than itself, and attach the end to the interior of the sphere, then leakage cannot take place.
Another corollary of the fact that there is no electric force in the interior of a charged conductor is that the potential in the interior is constant and equal to that at the surface. For by the definition of potential it follows that the electric force in any direction at any point is measured by the space rate of change of potential in that direction or E = + dVldx. Hence if the force is zero the potential V must be constant.
(iii.) Association of Positive and Negative Electricities.  The third leading fact in electrostatics is that positive and negative electricity are always created in equal quantities, and that for every charge, say, of positive electricity on one conductor there must exist on some other bodies an equal total charge of negative electricity. Faraday expressed this fact by saying that no absolute electric charge could be given to matter. If we consider the charge of a conductor to be measured by the number of tubes of electric force which proceed from it, then, since each tube must end on some other conductor, the above statement is equivalent to saying that the charges at each end of a tube of electric force are equal.
The facts may, however, best be understood and demonstrated by considering an experiment due to Faraday, commonly called the ice pail experiment, because he employed for it a pewter ice pail (Exp. Res. vol. ii. p. 279, or Phil. Mag. 1843, 22). On the plate of a goldleaf electroscope place a metal canister having a loose lid. Let a metal ball be suspended by a silk thread, and the canister lid so fixed to the thread that when the lid is in place the ball hangs in the centre of the canister. Let the ball and lid be removed by the silk, and let a charge, say, of positive electricity (} Q) be given to the ball. Let the canister be touched with the finger to discharge it perfectly. Then let the ball be lowered into the canister. It will be found that as it does so the goldleaves of the electroscope diverge, but collapse again if the ball is withdrawn. If the ball is lowered until the lid is in place, the leaves take a steady deflection. Next let the canister be touched with the finger, the leaves collapse, but diverge again when the ball is withdrawn. A test will show that in this last case the canister is left negatively electrified. If before the ball is withdrawn, after touching the outside of the canister with the finger, the ball is tilted over to make it touch the inside of the canister, then on withdrawing it the canister and ball are found to be perfectly discharged. The explanation is as follows: the charge (} Q) of positive electricity on the ball creates by induction an equal charge ( Q) on the inside of the canister when placed in it, and repels to the exterior surface of the canister an equal charge (+ Q). On touching the canister this last charge goes to earth. Hence when the ball is touched against the inside of the canister before withdrawing it a second time, the fact that the system is found subsequently to be completely discharged proves that the charge  Q induced on the inside of the canister must be exactly equal to the charge +Q on the ball, and also that the inducing action of the charge {Q on the ball created equal quantities of electricity of opposite sign, one drawn to the inside and the other repelled to the outside of the canister.
We must next consider the quality of a conductor called its electrical capacity. The potential of a conductor has already been defined as the mechanical work which must be done to bring up a very small body charged with a unit of positive electricity from the earth's surface or other boundary taken as the place of zero potential to the surface of this conductor in question. The mathematical expression for this potential can in some cases be calculated or predetermined.
Thus, consider a sphere uniformly charged with Q units of positive electricity. It is a fundamental theorem in attractions that a thin spherical shell of matter which attracts according to the potential law of the inverse square acts on all external points as of a if it were concentrated at its centre. Hence a sphere s p here. having a charge Q repels a unit charge placed at a distance x from its centre with a force Q/x 2 dynes, and therefore the work W in ergs expended in bringing the unit up to that point from an infinite distance is given by the integral W = Q x 2 dx = Hence the potential at the surface of the sphere, and therefore the potential of the sphere, is Q/R, where R is the radius of the sphere in centimetres. The quantity of electricity which must be given to the sphere to raise it to unit potential is therefore R electrostatic units. The capacity of a conductor is defined to be the charge required to raise its potential to unity, all other charged conductors being at an infinite distance. This capacity is then a function of the geometrical dimensions of the conductor, and can be mathematically determined in certain cases. Since the potential of a small charge of electricity dQ at a distance r is equal to dQ/r, and since the potential of all parts of a conductor is the same in those cases in which the distribution of surface density of electrification is uniform or symmetrical with respect to some point or axis in the conductor, we can calculate the potential by simply summing up terms like rdS/r, where dS is an element of surface, o the surface density of electricity on it, and r the distance from the symmetrical centre. The capacity is then obtained as the quotient of the whole charge by this potential. Thus the distribution of electricity on a sphere in free space must be uniform, and all parts of the charge are at an equal distance R from the centre. Accordingly the potential at the centre is Q/R. But this must be the potential of the Capacity sphere, since all parts are at the same potential V. Since of a the capacity C is the ratio of charge to potential, the sphere. capacity of the sphere in free space is Q/V = R, or is numerically the same as its radius reckoned in centimetres.
We can thus easily calculate the capacity of a long thin wire like a telegraph wire far removed from the earth, as follows: Let 2r be the diameter of the wire, 1 its length, and the uniform Capac ity surface electric density.. Then consider a thin annulus thin of the wire of width dx; the charge on it is equal to thin rod. 21rry/dx units, and the potential V at a point on the axis at a distance x from the annulus due to this elementary charge is ll2 2?rrc V=2 j o (r2+x2) dx=47rrvj log e (2l+1,/ r2 +412 ')  loge'} If, then, r is small compared with 1, we have V =47rry log e llr. But the charge is Q = 21rra, and therefore the capacity of the thin wire is given by C =1/2 log e llr (2). A more difficult case is presented by the ellipsoid.' We have first to determine the mode in which electricity distributes itself on a conducting ellipsoid in free space. It must be such a potential distribution that the potential in the interior will be to constant, since the electric force must be zero. It is a ellipsoid. wellknown theorem in attractions that if a shell is made of gravitative matter whose inner and outer surfaces are similar ellipsoids, it exercises no attraction on a particle of matter in its interior. 2 Consider then an ellipsoidal shell the axes of whose bounding surfaces are (a, b, c) and (a+da), (b+db), (c+dc), where da/a =db b =dc/c =,u. The potential of such a shell at any internal point is constant, and the equipotential surfaces for external space are ellipsoids confocal with the ellipsoidal shell. Hence if we distribute electricity. over an ellipsoid, so that its density is everywhere proportional to the thickness of a shell formed by describing round ' The solution of the problem of determining the distribution en an ellipsoid of a fluid the particles of which repel each other with a force inversely as the nth power of the distance was first given by George Green (see Ferrer's edition of Green's Collected Papers, p. 119, 1871).
See Thomson and Tait, Treatise on Natural Philosophy, § 519. (I).
capacity of two concentric spheres, of two coaxial cylinders and of two parallel planes.
Consider the case of two concentric spheres, a solid one enclosed in a hollow one. Let R 1 be the radius of the inner sphere, R2 the inside radius of the outer sphere, and R2 the outside radius of the outer spherical shell. Let a charge +Q be f t the ellipsoid a similar and slightly larger one, that distribution will be in equilibrium and will produce a constant potential throughout the interior. Thus if Q is the surface density, S the thickness of the shell at any point, and p the assumed volume density of the matter of the shell, we have v =Abp. Then the quantity of electricity on any element of surface dS is A times the mass of the corresponding element of the shell; and if Q is the whole quantity of electricity on the ellipsoid, Q =A times the whole mass of the shell. This mass is equal to 47rabcp,u; therefore Q = A47rabcp s and b =pp, where p is the length of the perpendicular let fall from the centre of the ellipsoid on the tangent plane. Hence = Qpl47rabc (3) .
Accordingly for a given ellipsoid the surface density of free distribution of electricity on it is everywhere proportional to the the tangent e plane e att that point. all from thhiseweecan of determine the capacity of the ellipsoid as follows: Let p be the length of the perpendicular from the centre of the ellipsoid, whose equation is x 2 /a 2 1y2/b2 1,2c2 = i to the tangent plane at x, y, z. Then it can be shown that I /p2 = x2/a4+y2/b4+z2/c4 (see Frost's Solid Geometry, p. 172). Hence the density v is given by 47rabc (x2/a4+y2/b4Iz2/c4), and the potential at the centre of the ellipsoid, and therefore its potential as a whole is given by the expression, adS Q dS V f r 47rabc r' (x2/a4Iy2/b4+z2/c4) Accordingly the capacity C of the ellipsoid is given by the equation 1 I J dS C 47rabc Y (x 2 +y 2 + z2) V (x2/a4+y2/b4+z2/c4) (5) It has been shown by Professor Chrystal that the above integral may also be presented in the form,' foo C 2 J o J { (a2 + X) (b +X) (c 2 + X) } (6).
The above expressions for the capacity of an ellipsoid of three unequal axes are in general elliptic integrals, but they can be evaluated for the reduced cases when the ellipsoid is one of revolution, and hence in the limit either takes the form of a long rod or of a circular disk.
Thus if the ellipsoid is one of revolution, and ds is an element of arc which sweeps out the element of surface dS, we have dS = 27ryds = 27rydx/ ( Ts) = 27rydx/ (b y ) = 2 p2 dx. Hence, since a= Qp147rab 2 ,vdS = Qdx/2a.
Accordingly the distribution of electricity is such that equal parallel slices of the ellipsoid of revolution taken normal to the axis of revolution carry equal charges on their curved surface.
The capacity C of the ellipsoid of revolution is therefore given by the expression I I dx (7) C 2a ? (x2+3,2) If the ellipsoid is one of revolution round the major axis a (prolate) and of eccentricity e, then the above formula reduces to I I l og e (I +e) C  tae Whereas if it is an ellipsoid of revolution round the minor axis b (oblate), we have I sin  tae C2  ae (9). In each case we have C = a when e= 0, and the ellipsoid thus becomes a sphere.
In the extreme case when e=1, the prolate ellipsoid becomes a long thin rod, and then the capacity is given by C 1 = a/log e 2a/b (io), which is identical with the formula (2) already obtained. In the other extreme case the oblate spheroid becomes a circular disk when e = i, and then the capacity C2 = 2a17r. This last result shows that the capacity of a thin disk is 2/7r =1/1.571 of that of a sphere of the same radius. Cavendish (Elec. Res. pp. 137 and 347) determined in 1773 experimentally that the capacity of a sphere was 1.541 times that of a disk of the same radius, a truly remarkable result for that date.
Three other cases of practical interest present themselves, viz. the 1 See article " Electricity," Encyclopaedia Britannica (9th edition), vol. viii. p. 30. The reader is also referred to an article by Lord Kelvin (Reprint of Papers on Electrostatics and Magnetism, p. 178), entitled " Determination of the Distribution of Electricity on a Circular Segment of a Plane, or Spherical Conducting Surface under any given Influence," where another equivalent expression is given for the capacity of an ellipsoid.
are radial. Hence the electric force E in the interspace 1dRccor the potential V at any point in the interspace is given by varies inversely E = as  the distance distance =A/R from or V the  axis. R  A, Accordingly var where R is the distance of the point in the interspace from the axis, and A is a constant. Hence V 2  V 1 =  A log R 2 /R 1. If we consider a length l of the cylinder, the charge Q on the inner cylinder is Q=27rR l ly, where v is the surface density, and by Coulomb's law v = E i /47r, where E 1 = A/R 1 is the force at the surface of the inner Ai cylinder.
Accordingly Q=27rR 1 1A/47rR 1 =Al/2. If then the outer cylinder be at zero potential the potential V of the inner one is V =A log (R 2 /R 1), and its capacity C =1/2 log R2/R1.
This formula is important in connexion with the capacity of electric cables, which consist of a cylindrical conductor (a wire) enclosed in a conducting sheath. If the dielectric or separating insulator has a constant K, then the capacity becomes K times as great.
The capacity of two parallel planes can be calculated at once if we neglect the distribution of the lines of force near the edges of the plates, and assume that the only field is the uniform field between the plates. Let V 1 and V2 be the potentials of the plates, and let a charge Q be given to one of them.
If S is the surface of each plate, and d their distance, then the electric force E in the space between them is E = es. (V1  V2)/d. But if v is the surface density, E=47rv, and a=Q/S. Hence we have (V 1  V 2) d=47rQ/S or C= Q/(V i  V 2) = S/47rd (13). In this calculation we neglect altogether the fact that electric force distributed on curved lines exists outside the interspace between the plates, and these lines in fact extend from the back of one "Edge plate to that of the other. G. R. Kirchhoff (Gesammelte effect. Abhandl. p. 112) has given a full expression for the capacity C of two circular plates of thickness t and radius r placed at any distance d apart in air from which the edge effect can be calculated. Kirchhoff's expression is as follow d+47 r rd l dlog e 167x 2 + t) ,+t log,: t t I (4) In the above formula e is the base of the Napierian logarithms. The first term on the righthand side of the equation is the expression for the capacity, neglecting the curved edge distribution of electric force, and the other terms take into account, not only the uniform field between the plates, but also the nonuniform field round the edges and beyond the plates.
In practice we can avoid the difficulty due to irregular distribution of electric force at the edges of the plate by the use of a guard plate as first suggested by Lord Kelvin. 2 If a large plate has a Guard circular hole cut in it, and this is nearly filled up by a circular plate lying in the same plane, and if we place another large plate parallel to the first, then the electric field between this second plate and the small circular plate is nearly uniform; and if S is the area of the small plate and d its distance from the opposed plate, its capacity may be calculated by the simple formula C=S/47rd. The outer larger plate in which the hole is cut is called the " guard plate," and must be kept at the same potential as the smaller inner or " trapdoor plate." The same arrangement can be supplied to a pair of coaxial cylinders. By placing metal plates on either side of a larger sheet of dielectric or insulator we can construct a condenser of relatively large capacity. The instrument known as a Leyden jar consists of a glass bottle coated within and without for three parts of the way up with tinfoil.
See Maxwell, Electricity and Magnetism, vol. i. pp. 28 43 0 5 (3rd ed., 1892).
given to the inner sphere. Then this produces a charge  Q on the inside of the enclosing spherical shell, and a concentric charge +Q on the outside of the shell. Hence the potential V at the centre of the inner sphere is given by V =Q/R1  Q/R2+Q/R3. If the outer shell is connected to the earth, the charge +Q on it disappears, and we have the capacity C of the inner sphere given by C= I /R 1  I /R2=(R2  R1) R1R2 (II). Such a pair of concentric spheres constitute a condenser (see Leyden Jar), and it is obvious that by making R2 nearly equal to R 1, we may enormously increase the capacity of the inner sphere. Hence the name condenser. The other case of importance is that of two coaxial cylinders. Let a solid circular sectioned cylinder of radius R 1 be enclosed in a coaxial tube of inner radius R2. Then when the inner cylinder is at potential V 1 and the outer one kept at of two potential V 2 the lines of electric force between the cylinders Q (4).
I It is an interesting fact that Cavendish measured capacity in " globular inches," using as his unit the capacity of a metal ball, in. in diameter. Hence multiplication of his values for capacities by 2.54 reduces them to E.S. units in the C.G.S. system. See Elec. Res. p. 347.
For fuller details of these methods of comparison of capacities see J. A. Fleming, A Handbook for the Electrical Laboratory and Testing Room, vol. ii. ch. ii. (London, 1903).
In the absolute determination of capacity we have to measure the ratio of the charge of a condenser to its plate potential difference. One of the best methods for doing this is to charge the Ab l condenser by the known voltage of a battery, and then d e t erdischarge it through a galvanometer and repeat this minations. process rapidly and successively. If a condenser of capacity C is charged to potential V, and discharged n times per second through a galvanometer, this series of intermittent discharges is equivalent to a current nCV. Hence if the galvanometer is calibrated by a potentiometer we can determine the value of this current in amperes, and knowing the value of n and V thus determine C. Various forms of commutator have been devised for effecting this charge and discharge rapidly by J. J. Thomson, R. T. Glazebrook, J. A. Fleming and W. C. Clinton and others.' One form consists of a tuningfork electrically maintained in vibration of known period, which closes an electric contact at every vibration and sets another electromagnet in operation, which reverses a switch and moves over one terminal of the condenser from a battery to a galvanometer contact. In another form, a revolving contact is used driven by an electric motor, which consists of an insulating disk having on its surface slips of metal and three wire brushes a, b, c (see fig. 2) pressing against them. The metal slips are so placed that, as the disk revolves, the middle brush, connected to one terminal of the condenser C, is alternately put in conductive connexion with first one and then the other outside brush, which are joined respectively to the battery B and galvanometer G terminals. From the speed of this motor the number of commutations per second can be determined. The above method is especially useful for the determinations of very small capacities of the order of Ioo electrostatic units or so and upwards.
Dielectric constant.Since all electric charge consists in a state of strain or polarization of the dielectric, it is evident that the physical state and chemical composition of the insulator must be of great importance in determining electrical phenomena. Cavendish and subsequently Faraday discovered this fact, and the latter gave the name " specific inductive capacity," or " dielectric constant," to that quality of an insulator which determines the charge taken by a conductor embedded in it when charged to a given potential. The simplest method of determining it numerically is, therefore, that adopted by Faraday.4 Table Dielectric Constants (K) of Solids (K for Air = I).
Substance. 
K. 
Authority. 
Glass, double extra dense flint, density 4.5 . 
9.8 9 6 
J. Hopkinson 
Glass, light flint, density 3.2 
6.72 
„ 
Glass, hard crown, density 2.485 . 
6.61 
„ 
2.24 
M. Faraday 

2.88 
Coullner 

Sulphur. ... . 
3.84 
L. Boltzmann 
4 . 0 
P. J. Curie 

2.94 
P. R. Blondlot 

2.05 
Rosetti 

Ebonite 
3.15 2.21 
Boltzmann Schiller 
2.86 
Elsas 

Indiarubber, pure brown.. . 
2.12 
Schiller 
Indiarubber, vulcanized, grey. . 
2.69 
„ 
Guttapercha 
2.462 
J. E. H. Gordon 
I. 977 
Gibson and Barclay 

Paraffin.. . 
2.32 2.29 
Boltzmann J. Hopkinson 
i99 
Gordon 

2'95 
Wollner 

Shellac. ... . 
2.74 
Gordon 
3.04 
A. A. Winkelmann 

6.64 
I. Klemencic 

Mica. ... . 
8 oo 
P. J. Curie 
7.98 
E. M. L. Bouty 

5.97 
Elsas 

Quartz along optic axis. . 
4.55 
P. Curie 
perp. to optic axis . 
4.49 
P. J. Curie 
Ice at 23°. .. . 
78 . 0 
Bouty 
See Fleming, Handbook for the Electrical Laboratory, vol. ii. p. 130.
4 Faraday, Experimental Researches on Electricity, vol. i. § 1252. For a very complete set of tables of dielectric constants of solids, liquids and gases see A. Winkelmann, Handbuch der Physik, vol. iv. pp. 98148 (Breslau, 1905); also see Landolt and Bornstein's Tables of Physical Constants (Berlin, 1894) If we have a number of such condensers we can combine them in " parallel " or in " series." If all the plates on one side are connected together and also those on the other, the condensers are j oined i n parallel. If C1, C2, C3, &c., are the separate. capacities, then E(C) =C 1 fC 2 +C 3 + &c., is the total capacity in parallel. If the condensers are so joined that the inner coating of one is connected to the outer coating of the next, they are said to be in series. Since then they are all charged with the same quantity of electricity, and the total over all potential difference V is the sum of each of the individual potential differences V1, V2, V3, &c., we have Q=C I V I =C 2 V 2 =C 3 V 3 =&c., and V=V1FV2+V3+&c. The resultant capacity is C = Q/V, and C= I/(I/C1 +I /C2+1/C3+&c) = I/Z(I /C) (15). These rules provide means for calculating the resultant capacity when any number of condensers are joined up in any way.
If one condenser is charged, and then joined in parallel with another uncharged condenser, the charge is divided between them in the ratio of their capacities. For if C l and C2 are the capacities and Q i and Q2 are the charges after contact, then Qi/CI and Q2/C2 are the potential differences of the coatings and must be equal. Hence Qi /CI =Q2/C2 or Q I /Q 2 =C I /C 2. It is worth noting that if we have a charged sphere we can perfectly discharge it by introducing it into the interior of another hollow insulated conductor and making contact. The small sphere then becomes part of the interior of the other and loses all charge.
Measurement of Capacity.Numerous methods have been devised for the measurement of the electrical capacity of conductors in those cases in which it cannot be determined by calculation. Such a measurement may be an absolute determination or a relative one. The dimensions of a capacity in electrostatic measure is a length (see Physical Units). Thus the capacity of a sphere in electrostatic units (E.S.U.) is the same as the number denoting its radius in centimetres. The unit of electrostatic capacity is therefore that of a sphere of I cm. radius.' This unit is too small for practical purposes, and hence a unit of capacity 900,000 greater, called a microfarad, is generally employed. Thus for instance the capacity in free space of a sphere 2 metres in diameter would be 100/900,000 = 1/9000 of a microfarad. The electrical capacity of the whole earth considered as a sphere is about 800 microfarads. An absolute measurement of capacity means, therefore, a determination in E.S. units made directly without reference to any other condenser. On the other hand there are numerous methods by which the capacities of condensers may be compared and a relative measurement made in terms of some standard.
One wellknown comparison method is that of C. V. de Sauty. The two condensers to be compared are connected in the branches of a Wheatstone's Bridge and the other two arms R deter completed with variable resistance boxes. These arms. are then altered until on raising or depressing the battery key there is no sudden deflection either way of the galvano meter. If R I and R2 are the arms' resistances and C 1 and C2 the condenser capacities, then when the bridge is balanced we have R l: R2= C l: C2.
Another comparison method much used in submarine cable work is the method of mixtures, originally due to Lord Kelvin and usually called Thomson and Gott's method. It depends on the principle that if two condensers of capacity C I and C2 are respectively charged to potentials V I and V2, and then joined in parallel with terminals of opposite charge together, the resulting potential difference of the two condensers will be V, such that V = (C,V 2 CiV2) /(C1+C2) (16); and hence if V is zero we have C I: C2 = V2 The method is carried out by charging the two condensers to be compared at the two sections of a high resistance joining the ends of a battery which is divided into two parts by a movable contact.' This contact is shifted until such a point is found by trial that the two condensers charged at the different sections and then joined as above described and tested on a galvanometer show no charge. Various special keys have been invented for performing the electrical operations expeditiously.
A simple method for condenser comparison is to charge the two condensers to the same voltage by a battery and then discharge them successively through a ballistic galvanometer and observe the respective " throws " or deflections of the coil or needle. These are proportional to the capacities. For the various precautions necessary in conducting the above tests special treatises on electrical testing must be consulted.
He constructed two equal condensers, each consisting of a metal ball enclosed in a hollow metal sphere, and he provided also certain hemispherical shells of shellac, sulphur, glass, resin, &c., which he could so place in one condenser between the ball and enclosing sphere that it formed a condenser with solid dielectric. He then determined the ratio of the capacities of the two condensers, one with air and the other with the solid dielectric. This gave the dielectric constant K of the material. Taking the dielectric constant of air as unity he obtained the following values, for shellac K = 2.0, glass K. 76, and sulphur K = 2.24.
Since Faraday's time, by improved methods, but depending essentially upon the same principles, an enormous number of determinations of the dielectric constants of various insulators, solid, liquid and gaseous, have been made (see tables I., II., III. and IV.). There are very considerable differences between the values assigned by different observers, sometimes no doubt due to differences in method, but in most cases unquestionably depending on variations in the quality of the specimens examined. The value of the dielectric constant is greatly affected by the temperature and the frequency of the applied electric force.
Liquid. 
K. 
Authority. 
Water at 17° C.. .. . 
80 88 
F. Heerwagen 
„ „ 25° C.. ... . 
75.7 
E. B. Rosa 
25 3° C. . 
78.87 
Franke 
Oli v e oil. .. . 
3.16 
Hopkinson 
Castor oil. .. .. . 
4.78 
„ 
Turpentine. .. .. . 
2.15 
P. A. Silow 
„ 
2.23 
Hopkinson 
Petroleum. .. .. . 
2.072 
Silow 
2.07 
Hopkinson 

Ethyl alcohol at 25° C. . 
25.7 
Rosa 
Ethyl ether. . 
4.57 
Doule 
„ 
4.8 
Bouty 
Acetic acid.. . 
9.7 
Franke 
Substance. 
at 15° C. 
at185°C. 
Water. .. .. . 
80 
2.4 to 2.9 
Formic acid. .. .. . 
62 
2.41 
Glycerine.. ... . 
56 
3.2 
Methyl alcohol. ... . 
34 
3.13 
Nitrobenzene. .. .. . 
32 
2.6 
Ethyl alcohol. .. .. . 
25 
3. I 
Acetone. .. ... . 
21.85 
2.62 
Ethyl nitrat 
17.7 
2.73 
Amyl alcoho 
16 
2.I 4 
Aniline. .. . 
7.5 
2.92 
Castor oil. .. .. . 
4.78 
2.19 
Ethyl ether 
4.25 
2.31 
[[Table Ii]].Dielectric Constant (K) of Liquids. [[Table Ii]]I.Dielectric Constant of some Bodies at a very low Temperature (185° C.) (Fleming and Dewar). The above determinations at low temperature were made with either a steady or a slowly alternating electric force applied a hundred times a second. They show that the dielectric constant of a liquid generally undergoes great reduction in value when the liquid is frozen and reduced to a low temperature.1 The dielectric constants of gases have been determined by L. Boltzmann and I. Klemencic as follows: 1 See the following papers by J. A. Fleming and James Dewar on dielectric constants at low temperatures: " On the Dielectric Constant of Liquid Oxygen and Liquid Air," Proc. Roy. Soc., 1897, 60, p. 360; " Note on the Dielectric Constant of Ice and Alcohol at very low Temperatures," ib., 1897, 61, p. 2; " On the Dielectric Constants of Pure Ice, Glycerine, Nitrobenzol and Ethylene Dibromide at and above the Temperature of Liquid Air," id. ib. p. 316; " On the Dielectric Constant of Certain Frozen Electrolytes at and above the Temperature of Liquid Air," id. ib. p. 299this paper describes the cone condenser and methods used; " Further Observations on the Dielectric Constants of Frozen Electrolytes at and above the Temperature of Liquid Air," id. ib. p. 381; " The Dielectric Constants of Certain Organic Bodies at and below the Temperature of Liquid Air," id. ib. p. 358; " Ors the Dielectric Constants of Metallic Oxides dissolved or suspended in Ice cooled to the Temperature of Liquid Air," id. ib. p. 368.
[[Table Iv]].Dielectric Constants (K) of Gases at '15°' C. and 760 mm. Vacuum = I.
Gas. 
Dielectric Constant K. 
Optical Refractive Index. µ. 

Air. .. .. .. . 
1.000590 
1.000295 
I .000293 
Hydrogen 
1.000264 
I 000132 
1.000139 
Carbon dioxide. .. . 
1.000946 
1.000475 
1.000454 
Carbon monoxide.. . 
1.000690 
1.000 345 
1.000335 
Nitrous oxide 
1.000994 
1.000497 
1.00051 6 
Ethylene 
1.001312 
1.000656 
1.000720 
Marsh gas (methane). . 
1.000944 
1.000478 
1.000442 
Carbon bisulphide.. . 
1.002900 
1.001450 
1.001478 
Sulphur dioxide. .. . 
1.00954 
1.004770 
1.000703 
Ether. .. .. . 
1.00744 
1.003720 
1.00154 
Ethyl chloride. .. . 
1.01552 
1.007760 
1.00 1174 
Ethyl bromide. .. . 
1.01546 
1.007730 
1.00122 
In general the dielectric constant is reduced with decrease of temperature towards a certain limiting value it would attain at the absolute zero. This variation, however, is not always linear. In some cases there is a very sudden drop at or below a certain temperature to a much lower value, and above and below the point the temperature variation is small. There is also a large difference in most cases between the value for a steadily applied electric force and a rapidly reversed or intermittent forcein the last case a decrease with increase of frequency. Maxwell (Elec. and Magn. vol. ii. § 788) showed that the square root of the dielectric constant should be the same number as the refractive index for waves of the same frequency (see Electric Waves). There are very few substances, however, for which the optical refractive index has the same value as K for steady or slowly varying electric force, on account of the great variation of the value of K with frequency.
There is a close analogy between the variation of dielectric constant of an insulator with electric force frequency and that of the rigidity or stiffness of an elastic body with the frequency of applied mechanical stress. Thus pitch is a soft and yielding body under steady stress, but a bar of pitch if struck gives a musical note, which shows that it vibrates and is therefore stiff or elastic for high frequency stress.
Residual Charges in Dielectrics.In close connexion with this lies the phenomenon of residual charge in dielectrics. 2 If a glass Leyden jar is charged and then discharged and allowed to stand awhile, a second discharge can be obtained from it, and in like manner a third, and so on. The reappearance of the residual charge is promoted by tapping the glass. It has been shown that this behaviour of dielectrics can be imitated by a mechanical model consisting of a series of perforated pistons placed in a tube of oil with spiral springs between each piston. 3 If the pistons are depressed and then released, and then the upper piston fixed awhile, a second discharge can be obtained from it, and the mechanical stressstrain diagram of the model is closely similar to the discharge curve of a dielectric. R. H. A. Kohlrausch called attention to the close analogy between residual charge and the elastic recovery of strained bodies such as twisted wire or glass threads. If a charged condenser is suddenly discharged and then insulated, the reappearance of a potential difference between its coatings is analogous to the reappearance of a torque In the case of a glass fibre which has been twisted, released suddenly, and then gripped again at the ends.
For further information on the qualities of dielectrics the reader is referred to the following sources:J. Hopkinson, " On the Residual Charge of the Leyden Jar," Phil. Trans., 1876, 166 [ii.], P. 489, where it is shown that tapping the glass of a Leyden jar permits the reappearance of the residual charge; " On the Residual Charge of 2 See Faraday, Experimental Researches, vol. i. § 1245; R. H. A. Kohlrausch, Pogg. Ann., 18J4, 91; see also Maxwell, Electricity and Magnetism, vol. i. § 327, who shows that a composite or stratified dielectric composed of layers of materials of different dielectric constants and resistivities would exhibit the property of residual charge.
3 Fleming and Ashton, " On a Model which imitates the behaviour of Dielectrics," Phil. Mag., 1901 [6], 2, p. 228.
the Leyden Jar," ib. 167 [ii.], p. 599, containing many valuable observations on the residual charge of Leyden jars; W. E. Ayrton and J. Perry, " A Preliminary Account of the Reduction of Observations on Strained Material, Leyden Jars and Voltameters," Proc. Roy. Soc., 1880, 30, p. 411, showing experiments on residual charge of condensers and a comparison between the behaviour of dielectrics and glass fibres under torsion. In connexion with this paper the reader may also be referred to one by L. Boltzmann, " Zur Theorie der elastischen Nachwirkung," Wien. Acad. Sitz.Ber., 18 74, 70.
We now proceed to consider in more detail the laws which govern the distribution of electricity at rest upon conductors. It has been shown above that the potential due to a charge of q units placed on a very small sphere, commonly called a pointcharge, at any distance x is q/x. The mathematical importance of this function called the potential is that it is a scalar quantity, and the potential at any point due to any number of point charges ql, q2, q3, &c., distributed in any manner, is the sum of them separately, or qi/xl+q2/x2+q3/x3+&c. =F (q/x) =V (17), where xi, x2, x 3, &c., are the distances of the respective point charges from the point in question at which the total potential is required. The resultant electric force E at that point is then obtained by differentiating V, since E =  dV/dx, and E is in the direction in which V diminishes fastest. In any case, therefore, in which we can sum up the elementary potentials at any point we can calculate the resultant electric force at the same point.
We may describe, through all the points in an electric field which have the same potential, surfaces called equipotential surfaces, and these will be everywhere perpendicular or orthogonal to the lines of electric force. Let us assume the field divided up into tubes of electric force as already explained, and these cut normally by equipotential surfaces. We can then establish some important properties of these tubes and surfaces. At each point in the field the electric force can have but one resultant value. Hence the equipotential surfaces cannot cut each other. Let us suppose any other surface described in the electric field so as to cut the closel y compacted tubes. At each point on this surface the resultant force has a certain value, and a certain direction inclined at an angle 0 to the normal to the selected surface at that point. Let dS be an element of the surface. Then the quantity E cos OdS is the product of the normal component of the force and an element of the surface, and if this is summed up all over the surface we have the total electric flux or induction through the surface, or the surface integral of the normal force mathematically expressed by JE cos OdS, provided that the dielectric constant of the medium is unity.
We have then a very important theorem as follows:  If any closed surface be described in an electric field which wholly encloses or wholly excludes electrified bodies, then the total flux through this surface is equal to 47r  times the total quantity of electricity within it.' This is commonly called Stokes's theorem. The proof is as follows:  Consider any pointcharge E of electricity included in any surface S, S, S (see fig. 3), and describe through it as centre a cone of small solid angle dw cutting out of the enclosing surface in two small areas dS and dS' at distances x and x'. Then the electric force due to the point s' charge q at distance x is q/x, and the resolved part normal to the element of surface dS is q cos0/x 2. The normal section of the cone at that point is equal to dS cosO, and the solid angle dw is equal to dS cos0/x 2. Hence the flux through dS is qdw. Accordingly, since the total solid angle round a point is 47r, it follows that the total flux through the closed surface due to the single point charge q is 41rq, and what is true for one point charge is true for any collection forming a total charge Q of any form. Hence the total electric flux due to a charge Q through an enclosing surface is 41rQ, and therefore is zero through one enclosing no electricity.
Stokes's theorem becomes an obvious truism if applied to an incompressible fluid. Let a source of fluid be a point from which an incompressible fluid is emitted in all directions. Close to the source the stream lines will be radial lines. Let a very small sphere be described round the source, and let the strength of the source be defined as the total flow per second through the surface of this small sphere. Then if we have any number of sources enclosed by any surface, the total flow per second through this surface is equal to the total strengths of all the sources. If, however, we defined the strength of the source by the statement that the strength divided 1 The beginner is often puzzled by the constant appearance of the factor 47r in electrical theorems. It arises from the manner in which the unit quantity of electricity is defined. The electric force due to a pointcharge q at a distance r is defined to be q/r 2 , and the total flux or induction through the sphere of radius r is therefore 41rq. If, however, the unit point charge were defined to be that which produces a unit of electric flux through a circumscribing spherical surface or the electric force at distance r defined to be 1/47rr2, many theorems would be enunciated in simpler forms.
by the square of the distance gives the velocity of the liquid at that point, then the total flux through any enclosing surface would be 47r times the strengths of all the sources enclosed. To every proposition in electrostatics there is thus a corresponding one in the hydrokinetic theory of incompressible liquids.
Let us apply the above theorem to the case of a small parallelepipedon or rectangular prism having sides dx, dy, dz respectively, its centre having coordinates (x, y, z). Its angular points have then coordinates (x t Zdx, y t Zdy, z * zdz). Let this rectangular prism be supposed to be wholly filled up with electricity of density p; then the total quantity in it is p dx dy dz. Consider the two faces perpendicular to the xaxis. Let V be the potential at the centre of the prism, then the normal forces on the two faces of area dy.dx are respectively RI dx2 d xl and (dx 2 d x) , dV d2 and similar expressions for the normal forces to the other pairs of faces dx.dy, dz.dx. Hence, multiplying these normal forces by the areas of the corresponding faces, we have the total flux parallel to the xaxis given by  (d 2 V/dx 2)dxdydz, and similar expressions for the other sides. Hence the total flux is  (+ d2V d 2 V d2V dye + dz2) dy dz, dx2 and by the previous theorem this must be equal to 4'rrp dxdydz. d 2 V d 2 V d2V Hence d x2+ d y e { t47P=0 (18). This celebrated equation was first given by S. D. Poisson, although previously demonstrated by Laplace for the case when p=0. It defines the condition which must be fulfilled by the potential at any and every point in an electric field, through which p is finite and the electric force continuous. It may be looked upon as an equation to determine p when V is given or vice versa. An exactly similar expression holds good in hydrokinetics, provided that for the electric potential we substitute velocity potential, and for the electric force the velocity of the liquid.
The Poisson equation cannot, however, be applied in the above form to a region which is partly within and partly without an electrified conductor, because then the electric force undergoes a sudden change in value from zero to a finite value, in passing outwards through the bounding surface of the conductor. We can, however, obtain another equation called the " surface characteristic equation " as follows:  Suppose a very small area dS described on a conductor having a surface density of electrification a. Then let a small, very short cylinder be described of which dS is a section, and the generating lines are normal to the surface. Let V i and V2 be the potentials at points just outside and inside the surface dS, and let n l and n 2 be the normals to the surface dS drawn outwards and inwards; then  dV i /dn i and  dV 2 dn 2 are the normal components of the force over the ends of the imaginary small cylinder. But the force perpendicular to the curved surface of this cylinder is everywhere zero. Hence the total flux through the surface considered is  {(dV i /dn l)}(dV 2 /dn 2)}dS, and this by a previous theorem must be equal to 47radS, or the total included electric quantity. Hence we have the surface characteristic equation,2 /dn2)  47ra = o (19).
Let us apply these theorems to a portion of a tube of electric force. Let the part selected not include any charged surface. Then since the generating lines of the tube are lines of force, the component of the electric force perpendicular to the curved surface of the tube is everywhere zero. But the electric force is normal to the ends of the tube. Hence if dS and dS' are the areas of the ends, and +E and  E' the oppositely directed electric forces at the ends of the tube, the surface integral of normal force on the flux over the tube is EdS  E'dS' (20), and this by the theorem already given is equal to zero, since the tube includes no electricity. Hence the characteristic quality of a tube of electric force is that its section is everywhere inversely as the electric force at that point. A tube so chosen that EdS for one section has a value unity, is called a unit tube, since the product of force and section is then everywhere unity for the same tube.
In the next place apply the surface characteristic equation to any point on a charged conductor at which the surface density is a. The electric force outward from that point is  dV/dn, where do is a distance measured along the outwardly drawn normal, and the force within the surface is zero. Hence we have  dV /dn = 4lra or a =  (1 /47r) dV /dn = E/42r.
The above is a statement of Coulomb's law, that the electric fores at the surface of a conductor is proportional to the surface density of the charge at that point and equal to 41r times the density.3 See Maxwell, Electricity and Magnetism, vol. i. § 78b (2nd ed.).
Id. ib. vol. i. § 80. Coulomb proved the proportionality of electric surface force to density, but the above numerical relation E= 42ra was first established by Poisson.
dS FIG. 3.
If we define the positive direction along a tube of electric force as the direction in which a small body charged with positive electricity would tend to move, we can summarize the above facts in a simple form by saying that, if we have any closed surface described in any manner in an electric field, the excess of the number of unit tubes which leave the surface over those which enter it is equal to 47rtimes the algebraic sum of all the electricity included within the surface. Every tube of electric force must therefore begin and end on electrified surfaces of opposite sign, and the quantities of positive and negative electricity on its two ends are equal, since the force E just outside an electrified surface is normal to it and equal to a/41r, where a is the surface density; and since we have just proved that for the ends of a tube of force EdS = E 1 dS', it follows that adS = a'dS', or Q = Q', where Q and Q' are the quantities of electricity on the ends of the tube of force. Accordingly, since every tube sent out from a charged conductor must end somewhere on another charge of opposite sign, it follows that the two electricities always exist in equal quantity, and that it is impossible to create any quantity of one kind without creating an equal quantity of the opposite sign.
We have next to consider the energy storage which takes place when electric charge is created, i.e. when the dielectric is strained or polarized. Since the potential of a conductor is defined to be the work required to move a unit of positive electricity from the surface of the earth or from an infinite distance from all electricity to the surface of the conductor, it follows that the work done in putting a small charge dq into a conductor at a potential v is v dq. Let us then suppose that a conductor originally at zero potential has its potential raised by administering to it small successive doses of electricity dq. The first raises its potential to v, the second to v' and so on, and the nth to V. Take any horizontal line and divide it into small elements of length each representing dq, and draw vertical lines representing the potentials v, v', &c., and after each dose. Since the potential rises proportionately to the quantity in the conductor, the ends of these ordinates will lie on a straight line and define a triangle whose base line is a length equal to the total quantity Q and V height a length equal to the final potential V. The element of work done in introducing the quantity of electricity dq at a potential v is represented by the element of area of this triangle (see fig.
FIG. 4.4), and hence the work done in charging the conductor with quantity Q to final potential V is zQV, or since Q=CV, where C is its capacity, the work done is represented by 1CV 2 or by 2Q2/C.
If a is the surface density and dS an element of surface, then fadS is the whole charge, and hence afV adS is the expression for the energy of charge of a conductor.
We can deduce a remarkable expression for the energy stored up in an electric field containing electrified bodies as follows:' Let V denote the potential at any point in the field. Consider the integral W dx dy dz . (21) where the integration extends throughout the whole space unoccupied by conductors. We have by partial integration ff1 fV dd  ' 2 dy JJ dx y JJ y dxd dz = V  d dzdxd dz, and Itwo (similar equations in y and z. Hence 8?rJJJ.dx l i 2 + i dy ) 2 2 dxdydz= 8 Jfv d s_JJJvvvdx dngr dy dz. (22) where dV/dn means differentiation along the normal, and v stands d 2 d 2 d2 for the operator a x2  P dy2 { D. Let E be the resultant electric force at any point in the field. Then bearing in mind that a= (I/4x1)dV/dn, and p =(1/4xr)VV, we have finally E 2 c/v=2 f f v.dS+ 2J J J Vp dv. The first term on the right hand side expresses the energy of the surface electrification of the conductors in the field, and the second the energy of volume density (if any). Accordingly the term on the left hand side gives us the whole energy in the field.
Suppose that the dielectric has a constant K, then we must multiply both sides by K and the expression for the energy per unit of volume of the field is equivalent to z DE where D is the displacement or polarization in the dielectric.
Furthermore it can be shown by the application of the calculus of variations that the condition for a minimum value of the function W, is that vV = o. Hence that distribution of potential which is neces 1 See Maxwell, Electricity and Magnetism, vol. i. § 99a (3rd ed., 1892), where the expression in question is deduced as a corollary of Green's theorem.
sary to satisfy Laplace's equation is also one which makes the potential energy a minimum and therefore the energy stable. Thus the actual distribution of electricity on the conductor in the field is not merely a stable distribution, it is the only possible stable distribution.
A very powerful method of attacking problems in electrical distribution was first made known by Lord Kelvin in 1845 and is described as the method of electrical images.' By older mathematical methods it had only been possible to predict in a few simple cases the distribution of electricity at rest on conductors of various forms. The notion of an electrical image may be easily grasped by the following illustration: Let there be at A (see fig. 5) a pointcharge of positive electricity +q _q/ +q and an infinite conducting plate PO, shown in section, connected to earth and therefore at zero potential. Then the charge at A together with the induced surface charge on the plate makes a certain field of electric force on the left of the plate PO, which is a zero equipotential surface. If we remove the plate, and FIG. 5.
yet by any means can keep the identical surface occupied by it a plane of zero potential, the boundary conditions will remain the same, and therefore the field of force to the left of PO will remain unaltered. This can be done by placing at B an equal negative pointcharge q in the place which would be occupied by the optical image of A if PO were a mirror, that is, let q be placed at B, so that the distance BO is equal to the distance AO, whilst AOB is at right angles to PO. Then the potential at any point P in this ideal plane PO is equal to q/APq/BP=0, whilst the resultant force at P due to the two point charges is 2gAO/AP 3, and is parallel to AB or normal to PO. Hence if we remove the charge q at B and distribute electricity over the surface PO with a surface density a, according to the CoulombPoisson law, a = qAO/21rAP3, the field of force to the left of PD will fulfil the required boundary conditions, and hence will be the law of distribution of the induced electricity in the case of the actual plate. The pointcharge q at B is called the " electrical image " of the pointcharge +q at A.
We find a precisely analogous effect in optics which justifies the term " electrical image." Suppose a room lit by a single candle. There is everywhere a certain illumination due to it. Place across the room a plane mirror. All the space behind the mirror will become dark, and all the space in front of the mirror will acquire an exalted illumination. Whatever this increased illumination may be, it can be precisely imitated by removing the mirror and placing a second lighted candle at the place occupied by the optical image of the first candle in the mirror, that is, as far behind the plane as the first candle was in front. So the potential distribution in the space due to the electric pointcharge +q as A together with q at B is the same as that due to +q at A and the negative induced charge erected on the infinite plane (earthed) metal sheet placed halfway between A and B.
The same reasoning can be applied to determine the electrical image of a pointcharge of positive electricity in a spherical surface, and therefore the distribution of induced electricity over a metal sphere connected to earth produced by a pointcharge near it. Let +q be any positive pointcharge placed at a point A outside a sphere (fig. 6) of radius r, and centre at C, and let P be any point on it. Let CA =d. Take a point B in CA such that CB CA =r 2, or CB =r 2 /d. It is easy then to show that PA: PB =d: r. If then we put a negative pointcharge qr/d at B, it follows that the spherical surface will be a zero potential surface, for q rq 1 (24).
PA d PB o Another equipotential surface is evidently a very small sphere described round A. The resultant force due to these two pointcharges must then be in the direction CP, and its value E is the vector sum of the two forces along AP and BP due to the two pointcharges. It is not difficult to show that E =  (d 2 r 2)q/rAP 3   (25), in other words, the force at P is inversely as the cube of the distance from A. Suppose then we remove the negative pointcharge, and let the sphere be supposed to become conductive and be connected to earth. If we make a distribution of negative electricity over it, which has a density a varying according to the law a = (d 2 r 2) q /42rr AP3. .. (26), that distribution, together with the pointcharge +q at A, will make a distribution of electric force at all points outside the sphere 2 See Lord Kelvin's Papers on Electrostatics and Magnetism, p. 144.
d Q  ?  4 B 0 A FIG. 6.
exactly similar to that which would exist if the sphere were removed and a negative point charge  grid were placed at B. Hence this charge is the electrical image of the charge +q at A in the spherical surface.
We may generalize these statements in the following theorem, which is an important deduction from a wider theorem due to G. Green. Suppose that we have any distribution of electricity at rest over conductors, and that we know the potential at all points and consequently the level or equipotential surfaces. Take any equipotential surface enclosing the whole of the electricity, and suppose this to become an actual sheet of metal connected to the earth. It is then a zero potential surface, and every point outside is at zero potential as far as concerns the electric charge on the conductors inside. Then if U is the potential outside the surface due to this electric charge inside alone, and V that due to the opposite charge it induces on the inside of the metal surface, we must have U+V =O or U =  V at all points outside the earthed metal surface. Therefore, whatever may be the distribution of electric force produced by the charges inside taken alone, it can be exactly imitated for all space outside the metal surface if we suppose the inside charge removed and a distribution of electricity of the same sign made over the metal surface such that its density follows the law Q =  (1 /47r)dU/dn (27), where dUldn is the electric force at that point on the closed equipotential surface considered, due to the original charge alone.
Bibliography.  For further developments of the subject we must refer the reader to the numerous excellent treatises on electrostatics now available. The student will find it to be a great advantage to read through Faraday's three volumes entitled Experimental Researches on Electricity, as soon as he has mastered some modern elementary book giving in compact form a general account of electrical phenomena. For this purpose he may select from the following books: J. Clerk Maxwell, Elementary Treatise on Electricity (Oxford, 1881); J. J. Thomson, Elements of the Mathematical Theory of Electricity and Magnetism (Cambridge, 1895); J. D. Everett, Electricity, founded on part iii. of Deschanel's Natural Philosophy (London, 1901); G. C. Foster and A. W. Porter, Elementary Treatise on Electricity and Magnetism (London, 1903); S. P. Thompson, Elementary Lessons on Electricity and Magnetism (London, 1903).
When these elementary books have been digested, the advanced student may proceed to study the following: J. Clerk Maxwell, A Treatise on Electricity and Magnetism (1st ed., Oxford, 1873; 2nd ed. by W. D. Niven, 1881; 3rd ed. by J. J. Thomson, 1892); Joubert and Mascart, Electricity and Magnetism, English translation by E. Atkinson (London, 1883); Watson and Burbury, The Mathematical Theory of Electricity and Magnetism (Oxford, 188.5); A. Gray, A Treatise on Magnetism and Electricity (London, 1898). In the collected Scientific Papers of Lord Kelvin (3 vols., Cambridge, 1882), of James Clerk Maxwell (2 vols., Cambridge, 1890), and of Lord Rayleigh (4 vols., Cambridge, 1903), the advanced student will find the means for studying the historical development of electrical knowledge as it has been evolved from the minds of some of the master workers of the 19th century. (J. A. F.)
<< Electroscope 
Electrostatics (also known as static electricity) is the branch of physics that deals with apparently stationary electric charges.
This means for instance the attraction of plastic wrap to ones hand when one has removed it from a package, but also apparently spontaneous explosion of grain silos and damage of electronic components during manufacturing or the operation of photocopiers.
Electrostatics involves the buildup of charge on the surface of objects due to contact with other surfaces. Although charge exchange happens whenever any two surfaces contact and separate, the effects of charge exchange are usually only noticed when at least one of the surfaces has a high resistance to electrical flow. This is because the charges that transfer to or from the highly resistive surface are more or less trapped there for a long enough time for their effects to be observed. These charges then remain on the object until they either bleed off to ground or are quickly neutralized by a discharge: e.g., the familiar phenomenon of a static 'shock' is caused by the neutralization of charge built up in the body from contact with nonconductive surfaces.
invisible wall of static: [1]
