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The primary embrittlement mechanism of plastics is gradual loss
of plasticizers,
usually by overheating or aging.
The primary embrittlement mechanism of asphalt is by oxidation, which is most severe
in warmer climates. Asphalt pavement embrittlement can lead to
various forms of cracking patterns, including longitudinal,
transverse, and block (hexagonal). Asphalt oxidation is related to
polymer
degradation, as these materials bear similarities in their
chemical composition.