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Nuclear fission products are the atomic fragments left after a large atomic nucleus fissions. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons and a large release of energy in the form of heat (kinetic energy of the nuclei), gamma rays and neutrinos. The two smaller nuclei are the "fission products".


Formation and decay

The sum of the atomic weight of the two atoms produced by the fission of one atom is always less than the atomic weight of the original atom. This is because some of the mass is lost as free neutrons and large amounts of energy.

Since the nuclei that can readily undergo fission are particularly neutron-rich (e.g. 61% of the nucleons in uranium-235 are neutrons), the initial fission products are almost always more neutron-rich than stable nuclei of the same mass as the fission product (e.g. stable ruthenium-100 is 56% neutrons, stable xenon-134 is 60%). The initial fission products therefore may be unstable and typically undergo beta decay towards stable nuclei, converting a neutron to a proton with each beta emission. (Fission products do not emit alpha particles.)

A few neutron-rich and short-lived initial fission products first decay by emitting a neutron. This is the source of delayed neutrons which play an important role in control of a nuclear reactor.

The first beta decays are rapid, and may release high energy beta particles or gamma radiation. However, as the fission products approach stable nuclear conditions, the last one or two decays may have a long halflife and release less energy. There are a few exceptions with relatively long halflives and high decay energy, such as:

  • Sr-90 (high energy beta, halflife 30 years)
  • Cs-137 (high energy gamma, halflife 30 years)
  • Sn-126 (even higher energy gamma, but long halflife of 230,000 years means a slow rate of radiation release, and the yield of this nuclide per fission is very low)

Radioactivity over time

Actinides Half-life Fission products
244Cm 241Pu f 250Cf 243Cmf 10–30 y 137Cs 90Sr 85Kr
232 f 238Pu f is for
69–90 y 151Sm nc➔
4n 249Cf  f 242Amf 141–351 No fission product
has half-life 102
to 2×105 years
241Am 251Cf  f 431–898
240Pu 229Th 246Cm 243Am 5–7 ky
4n 245Cmf 250Cm 239Pu f 8–24 ky
233U    f 230Th 231Pa 32–160
4n+1 234U 4n+3 211–290 99Tc 126Sn 79Se
248Cm 242Pu 340–373 Long-lived fission products
237Np 4n+2 1–2 my 93Zr 135Cs nc➔
236U 4n+1 247Cmf 6–23 107Pd 129I
244Pu 80 my >7% >5% >1% >.1%
232Th 238U 235U    f 0.7–12by fission product yield

Fission products have half-lives of 90 years (Samarium-151) or less, except for seven long-lived fission products with half-lives of 211,100 years (Technetium-99) and more. Therefore the total radioactivity of fission products decreases rapidly for the first several hundred years, before stabilizing at a low level that changes little for hundreds of thousands of years. This contrasts with actinides produced in the open (no reprocessing) nuclear fuel cycle, a number of which have half-lives in the missing range of about 102 to 105 years.

Proponents of nuclear fuel cycles which aim to consume all their actinides by fission, such as the Integral Fast Reactor and molten salt reactor, use this fact to claim that within 200 years, their wastes are no more radioactive than the original uranium ore.[1]

Fission products emit beta radiation, while actinides primarily emit alpha radiation. Many of each also emit gamma radiation.


Fission product yields by mass for thermal neutron fission of U-235, Pu-239, a combination of the two typical of current nuclear power reactors, and U-233 used in the thorium cycle.

Each fission of a parent atom produces a different set of fission product atoms. However, while an individual fission is not predictable, the fission products are statistically predictable. The amount of any particular isotope produced per fission is called its yield, typically expressed as % per parent fission; therefore, yields total to 200% not 100%.

While fission products include every element from zinc through the lanthanides, the majority of the fission products occurs in two peaks. One peak occurs at about (expressed by atomic number) strontium to ruthenium while the other peak is at about tellurium to neodymium. The exact yield is somewhat dependent on the parent atom, and also on the energy of the initiating neutron.[2]

In general the higher the energy of the state that undergoes nuclear fission, the more likely that the two fission products have similar mass. Hence as the neutron energy increases and/or the energy of the fissile atom increases, the valley between the two peaks becomes more shallow.[3]

For instance, the curve of yield against mass for Pu-239 has a more shallow valley than that observed for U-235 when the neutrons are thermal neutrons. The curves for the fission of the later actinides tend to make even more shallow valleys. In extreme cases such as 259Fm, only one peak is seen.

The adjacent figure shows a typical fission product distribution from the fission of uranium. Note that in the calculations used to make this graph, the activation of fission products was ignored and the fission was assumed to occur in a single moment rather than a length of time. In this bar chart results are shown for different cooling times — time after fission.

Because of the stability of nuclei with even numbers of protons and/or neutrons, the curve of yield against element is not a smooth curve but tends to alternate. Note that the curve against mass number is smooth.[2]


fission products
Q *
155Eu 4.76 .0803 252 βγ
85Kr 10.76 .2180 687 βγ
113mCd 14.1 .0008 316 β
90Sr 28.9 4.505 2826 β
137Cs 30.23 6.337 1176 βγ
121mSn 43.9 .00005 390 βγ
151Sm 90 .5314 77 β
fission products
Q *
99Tc 0.211 6.1385 294 β
126Sn 0.230 0.1084 4050 βγ
79Se 0.295 0.0447 151 β
93Zr 1.53 5.4575 91 βγ
135Cs 2.3  6.9110 269 β
107Pd 6.5  1.2499 33 β
129I 15.7  0.8410 194 βγ

The adjacent tables provides information on the half-life, yield and decay energies for some more important fission products. A more detailed description of individual products is provided in Fission products (by element), in Long-lived fission products, in articles on specific radionuclides, and in general atomic chemistry articles.

Fission product production

Small amounts of fission products are naturally formed as the result of either spontaneous fission of natural uranium, which occurs at a low rate, or as a result of neutrons from radioactive decay or reactions with cosmic ray particles. The microscopic tracks left by these fission products in some natural minerals (mainly apatite and zircon) are used in fission track dating to provide the cooling ages of natural rocks. The technique has an effective dating range of 0.1 Ma to >1.0 Ga depending on the mineral used and the concentration on uranium in that mineral.

About 1.5 billion years ago, in a uranium ore body in Africa, a natural nuclear fission reactor operated for a few hundred thousand years and produced approximately 5 tonnes of fission products. These fission products were important in providing proof that the natural reactor had occurred. More details are provided in the linked article.

Fission products are produced in nuclear weapon explosions, with the amount depending on the type of weapon. After the Castle Bravo test, the United States refused to tell the Japanese doctors treating theDaigo Fukuryu Maru crew the composition of the fallout they were subjected to, out of fear it would reveal clues about the bomb's design.

The largest source of fission products is from nuclear reactors. In current nuclear power reactors, about 3% of the uranium in the fuel is converted into fission products as an unavoidable by-product of energy generation. Most of these fission products remain in the fuel unless there is fuel element failure, or a nuclear accident, or the fuel is reprocessed.



Supply of radioactive isotopes

Some fission products (such as Cs-137) are used in medical and industrial radioactive sources.

Nuclear reactor control

Some fission products decay with the release of a neutron. Since there may be a short delay in time between the original fission event (which release its own "prompt" neutrons immediately) and the release of these neutrons, the latter are termed "delayed neutrons". These delayed neutrons are important to nuclear reactor control.

Nuclear reactor poisons

Some of the fission products, such as xenon-135 and samarium-149, have a high neutron absorption capacity. Since a nuclear reactor depends on a balance in the neutron production and absorption rates, those fission products that remove neutrons from the reaction will tend to shut the reactor down or "poison" the reactor. Nuclear fuels and reactors are designed to address this phenomenon through such features as burnable poisons and control rods. Build-up of xenon-135 during shutdown or low-power operation may poison the reactor enough to impede restart or to interfere with normal control of the reaction during restart or restoration of full power, possibly causing or contributing to an accident scenario.

Fission product decay with time

The external gamma dose for a person in the open near the Chernobyl site.
The portion of the total radiation dose (in air) contributed by each isotope versus time after the Chernobyl disaster, at the site thereof. Note that this image was drawn using data from the OECD report, and the second edition of 'The radiochemical manual'.[4]

For fission of uranium-235, the predominant radioactive fission products include isotopes of iodine, caesium, strontium, xenon and barium. It is important to understand that the size of the threat becomes smaller with the passage of time. Locations where radiation fields once posed immediate mortal threats, such as much of the Chernobyl power plant on day one of the accident and the ground zero sites of Japanese atomic bombings (6 hours after detonation), are now safe as the radioactivity has decayed to a very low level.

See for instance the graph (below right) of the gamma dose rate due to Chernobyl fallout as a function of time after the accident. Many of the fission products decay through very short-lived isotopes to form stable isotopes, but a considerable number of the radioisotopes have half lives longer than a day.

The radioactivity in the fission product mixture is mostly due to short lived isotopes such as I-131 and 140Ba, after about four months 141Ce, 95Zr/95Nb and 89Sr take the largest share, while after about two or three years the largest share is taken by 144Ce/144Pr, 106Ru/106Rh and 147Pm. Later 90Sr and 137Cs are the main radioisotopes, being succeeded by 99Tc. In the case of a release of radioactivity from a power reactor or used fuel, only some elements are released; as a result, the isotopic signature of the radioactivity is very different from an open air nuclear detonation, where all the fission products are dispersed.

Fission products in power reactors

In a nuclear power reactor, the main types of radioactivity are fission products, actinides and activation products. Fission products are the largest amount of radioactivity for the first several hundred years, while actinides are dominant roughly 103 to 105 years after fuel use.

Fission occurs in the nuclear fuel, and the fission products are primarily retained within the fuel close to where they are produced. These fission products are important to the operation of the reactor because (as noted above) some fission products contribute delayed neutrons that are useful for reactor control while others are neutron poisons that tend to inhibit the nuclear reaction. The buildup of the fission product poisons is a key factor in determining the maximum duration a given fuel element can be kept within the reactor. The decay of short-lived fission products also provide a source of heat within the fuel that continues even after the reactor has been shutdown and the fission reactions stopped. It is this decay heat that sets the requirements for cooling of a reactor after shutdown. More details on these topics are provided in the articles on nuclear power plants and used nuclear fuel.

If the fuel cladding around the fuel develops holes, then fission products can leak into the primary coolant. Depending on the fission product chemistry, it may settle within the reactor core or travel through the coolant system. Coolant systems include chemistry control systems that among other purposes, will tend to remove such fission products. In a well-designed power reactor running under normal conditions, the radioactivity of the coolant is very low.

Fission products in nuclear weapons

Nuclear weapons use fission as either the partial or the main energy source. Depending on the weapon design and where it is exploded, the relative importance of the fission product radioactivity will vary compared to the activation product radioactivity in the total fallout radioactivity.

The immediate fission products from nuclear weapon fission are essentially the same as those from any other fission source, depending slightly on the particular nuclide that is fissioning. However, the very short time scale for the reaction makes a difference in the particular mix of isotopes produced from an atomic bomb.

For example, the 134Cs/137Cs ratio provides an easy method of distinguishing between fallout from a bomb and the fission products from a power reactor. Almost no Cs-134 is formed by nuclear fission (because xenon-134 is stable). The 134Cs is formed by the neutron activation of the stable 133Cs which is formed by the decay of isotopes in the isobar (A = 133). so in a momentary criticality by the time that the neutron flux becomes zero too little time will have passed for any 133Cs to be present. While in a power reactor plenty of time exists for the decay of the isotopes in the isobar to form 133Cs, the 133Cs thus formed can then be activated to form 134Cs only if the time between the start and the end of the criticality is long.

According to Jiri Hala's textbook the radioactivity in the fission product mixture (due to an atom bomb) is mostly caused by short-lived isotopes such as I-131 and Ba-140. After about four months Ce-141, Zr-95/Nb-95, and Sr-89 represent the largest share of radioactive material. After two to three years, Ce-144/Pr-144, Ru-106/Rh-106, and Promethium-147 are the bulk of the radioactivity. After a few years, the radiation is dominated by Strontium-90 and Caesium-137, whereas in the period between 10,000 and a million years it is Technetium-99 that dominates.

Countermeasures against the worst fission products found in accident fallout

The purpose of radiological emergency preparedness is to protect people from the effects of radiation exposure after a nuclear accident or bomb. Evacuation is the most effective protective measure. However, if evacuation is impossible or even uncertain (you don't want to be stuck in the open), then local shelter and other measures provide the best protection.[5].

The mixture of radioactive fission products found in the fallout from a nuclear bomb are very different in nature to those found in spent power reactor fuel. This is because the reactor fuel will have had more time for the short lived isotopes to decay, and because for many accident types that the volatile elements are liberated while the involatiles are retained at the accident site. As a result the contribution of many short-lived (e.g. 97Zr) and/or involatiles is less for accident fallout than it is bomb fallout. A definitive report on Chernobyl is at [1] - Chapter 2, Table 1 lists the radioisotopes released in the fire. The percentage of the inventory which was released was controlled largely by how volatile the fission product is. Hence a greater proportion of xenon and iodine were released than of cerium and plutonium.

For the longer term response, a review of the methods that can be used to decontaminate an urban environment is provided in the scope report Behaviour and Decontamination of Artificial Radionuclides in the Urban Environment. Also see chapter four of the NEA reports Chernobyl ten years on and Chernobyl twenty years on for details of how farming methods can be changed to reduce the impact of accident fallout.


At least three isotopes of iodine are important. 129I, 131I (radioiodine) and 132I. An overview of iodine exposure in the USA (resulting from bomb tests) can be seen at [2]. Open air nuclear testing and the Chernobyl disaster both released iodine-131.

Per capita thyroid doses in the continental United States of iodine-131 resulting from all exposure routes from all atmospheric nuclear tests conducted at the Nevada Test Site. See also Downwinders.

The short-lived isotopes of iodine are particularly harmful because the thyroid collects and concentrates iodide — radioactive as well as stable. Absorption of radioiodine can lead to acute, chronic, and delayed effects. Acute effects from high doses include thyroiditis, while chronic and delayed effects include hypothyroidism, thyroid nodules, and thyroid cancer. It has been shown that the active iodine released from Chernobyl and Mayak[6] has resulted in an increase in the incidence of thyroid cancer in the former Soviet Union.

One measure which protects against the risk from radio-iodine is taking a dose of potassium iodide before exposure to radioiodine. The non-radioactive iodide 'saturates' the thyroid, causing less of the radioiodine to be stored in the body. Administering potassium iodide reduces the effects of radio-iodine by 99%, and is a prudent, inexpensive supplement to fallout shelters. The Food and Drug Administration (FDA) has approved potassium iodide as an over-the-counter medication. As with any medication, individuals should check with their doctor or pharmacist before using it.

A low-cost alternative to commercially available iodine pills is a saturated solution of potassium iodide. It usually possible to obtain several thousand doses for prices near US$ 0.01/dose. Long term storage of KI is normally in the form of reagent grade crystals, which are convenient and available commercially. The purity is superior to "pharmacologic grade". Its concentration depends only on temperature, which is easy to determine, and the required dose is easily administered by measuring the required volume of the liquid. At room temperature, the U.S. standard adult radiological protective dose of 130 mg is four drops of a saturated solution. A baby's dose is 65 mg, or two drops. It should be noted that these doses are sufficient to cause nausea and sometimes emesis in most individuals. It's normally administered in a ball of bread, because it tastes incredibly bad. Use is contraindicated in individual known to be allergic to iodine; for such persons sodium perchlorate is one alternative.[7].


The Chernobyl accident released a large amount of caesium isotopes, these were dispersed over a wide area. 137Cs is an isotope which is of long term concern as it remains in the top layers of soil. Plants with shallow root systems tend to absorb it for many years. Hence grass and mushrooms can carry a considerable amount of 137Cs which can be transferred to humans through the food chain.

One of the best countermeasures in dairy farming against 137Cs is to mix up the soil by deeply ploughing the soil. This has the effect of putting the 137Cs out of reach of the shallow roots of the grass, hence the level of radioactivity in the grass will be lowered. Also the removal of top few cm of soil and its burial in a shallow trench will reduce the dose to humans and animals as the gamma photons from 137Cs will be attenuated by their passage through the soil. The deeper and more remote the trench is, the better the degree of protection.

Fertilizers containing potassium can be used to dilute caesium and limit its uptake by plants.

In livestock farming another countermeasure against 137Cs is to feed to animals a little prussian blue. This iron potassium cyanide compound acts as a ion-exchanger. The cyanide is so tightly bonded to the iron that it is safe for a human to eat several grams of prussian blue per day. The prussian blue reduces the biological half life (different from the nuclear half life) of the caesium. The physical or nuclear half life of 137Cs is about 30 years. This is a constant which can not be changed but the biological half life is not a constant. It will change according to the nature and habits of the organism it is expressed for. Caesium in humans normally has a biological half life of between one and four months. An added advantage of the prussian blue is that the caesium which is stripped from the animal in the droppings is in a form which is not available to plants. Hence it prevents the caesium from being recycled. The form of prussian blue required for the treatment of humans or animals is a special grade. Attempts to use the pigment grade used in paints have not been successful. For further details of the use of prussian blue please see the IAEA report on the Goiânia accident.[3]


The addition of lime to soils which are poor in calcium can reduce the uptake of strontium by plants. Likewise in areas where the soil is low in potassium, the addition of a potassium fertiliser can discourage the uptake of caesium into plants. However such treatments with either lime or potash should not be undertaken lightly as they can alter the soil chemistry greatly so resulting in a change in the plant ecology of the land.

Miscellaneous Fission Products Notes

It is known that the isotope responsible for the majority of the gamma exposure in fuel reprocessing plants (and the Chernobyl site in 2005) is Cs-137. 129I is one of the major radioactive elements released from reprocessing plants.

In nuclear reactors both 137Cs and 90Sr are found in locations remote from the fuel. This is because these isotopes are formed by the beta decay of noble gases (xenon-137 {halflife of 3.8 minutes} and krypton-90 {halflife 32 seconds}) which enable these isotopes to be deposited in locations remote from the fuel (e.g. on control rods).

Iodine-129 and technetium-99 are mobile in water as they form anionic species (I- and TcO4-).

99TcO4- ion can react with steel surfaces to form a corrosion resistant layer. In this way these metaloxo anions act as anodic corrosion inhibitors - it renders the steel surface passive. The formation of 99TcO2 on steel surfaces is one effect which will retard the release of 99Tc from nuclear waste drums and nuclear equipment which has become lost prior to decontamination (e.g. nuclear submarine reactors which have been lost at sea).

In a similar way the release of radio-iodine in a serious power reactor accident could be retarded by adsorption on metal surfaces within the nuclear plant.[8] A lot of other work on the iodine chemistry which would occur during a bad accident has been done.[4]

Alimentary absorption of fission products

For introduction of radionuclides into organism, ingestion is the most important route. Insoluble compounds are not absorbed from the gut and cause only local irradiation before they are excreted. Soluble forms however show wide range of absorption percentages.[9]

Isotope Radiation Half-life GI absorption
Strontium-90/yttrium-90 β 28 years 30%
Caesium-137 β,γ 29 years 100%
Promethium-147 β 2.6 years 0.01%
Cerium-144 β,γ 285 days 0.01%
Ruthenium-106/rhodium-106 β,γ 1.0 years 0.03%
Zirconium-95 β,γ 65 days 0.01%
Strontium-89 β 51 days 30%
Ruthenium-103 β,γ 39.7 days 0.03%
Niobium-95 β,γ 35 days 0.01%
Cerium-141 β,γ 33 days 0.01%
Barium-140/lanthanum-140 β,γ 12.8 days 5%
Iodine-131 β,γ 8.05 days 100%
Tritium β 13 years 100%, as tritiated water can absorb through skin


  1. ^
  2. ^ a b "Nuclear Fission Yield". Retrieved 2009-05-13. 
  3. ^
  4. ^ "Nuclear Data Evaluation Lab". Retrieved 2009-05-13. 
  5. ^ C. Kearney, Nuclear War Survival Skills, Oregon Institute of Science and Medicine,
  6. ^ G. Mushkacheva, E. Rabinovich, V. Privalov, S. Povolotskaya, V. Shorokhova, S. Sokolova, V. Turdakova, E. Ryzhova, P. Hall, A. B. Schneider, D. L. Preston, and E. Ron, "Thyroid Abnormalities Associated with Protracted Childhood Exposure to 131I from Atmospheric Emissions from the Mayak Weapons Facility in Russia", Radiation Research, 2006, 166(5), 715-722
  7. ^ C. Kearney, Nuclear War Survival Skills (Ch. 13), Oregon Institute of Science and Medicine,
  8. ^ H. Glänneskog. Interactions of I2 and CH3I with reactive metals under BWR severe-accident conditions, Nucl. Engineering and Design, 2004, 227, 323-329
  9. ^


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