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osmiumiridiumplatinum
Rh

Ir

Mt
Appearance
silvery white
Two square pieces of gray foil
General properties
Name, symbol, number iridium, Ir, 77
Element category transition metal
Group, period, block 96, d
Standard atomic weight 192.217g·mol−1
Electron configuration [Xe] 4f14 5d7 6s2
Electrons per shell 2, 8, 18, 32, 15, 2 (Image)
Physical properties
Phase solid
Density (near r.t.) 22.56 [1] g·cm−3
Liquid density at m.p. 19 g·cm−3
Melting point 2739 K, 2466 °C, 4471 °F
Boiling point 4701 K, 4428 °C, 8002 °F
Heat of fusion 41.12 kJ·mol−1
Heat of vaporization 563 kJ·mol−1
Specific heat capacity (25 °C) 25.10 J·mol−1·K−1
Vapor pressure
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 2713 2957 3252 3614 4069 4659
Atomic properties
Oxidation states −3,−1, 0, 1, 2, 3, 4, 5, 6
Electronegativity 2.20 (Pauling scale)
Ionization energies 1st: 880 kJ·mol−1
2nd: 1600 kJ·mol−1
Atomic radius 136 pm
Covalent radius 141±6 pm
Miscellanea
Crystal structure face-centered cubic
Magnetic ordering paramagnetic[2]
Electrical resistivity (20 °C) 47.1 nΩ·m
Thermal conductivity (300 K) 147 W·m−1·K−1
Thermal expansion 6.4 µm/(m·K)
Speed of sound (thin rod) (20 °C) 4825 m/s
Young's modulus 528 GPa
Shear modulus 210 GPa
Bulk modulus 320 GPa
Poisson ratio 0.26
Mohs hardness 6.5
Vickers hardness 1760 MPa
Brinell hardness 1670 MPa
CAS registry number 7439-88-5
Most stable isotopes
Main article: Isotopes of iridium
iso NA half-life DM DE (MeV) DP
188Ir syn 1.73 d ε 1.64 188Os
189Ir syn 13.2 d ε 0.532 189Os
190Ir syn 11.8 d ε 2.000 190Os
191Ir 37.3% 191Ir is stable with 114 neutrons
192Ir syn 73.827 d β- 1.460 192Pt
ε 1.046 192Os
192m2Ir syn 241 y IT 0.161 192Ir
193Ir 62.7% 193Ir is stable with 116 neutrons
193mIr syn 10.5 d IT 0.080 193Ir
194Ir syn 19.3 h β- 2.247 194Pt
194m2Ir syn 171 d IT  ? 194Ir

Iridium (pronounced /ɨˈrɪdiəm/, i-RID-ee-əm) is the chemical element with atomic number 77, and is represented by the symbol Ir. A very hard, brittle, silvery-white transition metal of the platinum family, iridium is the second densest element (after osmium) and is the most corrosion-resistant metal, even at temperatures as high as 2000 °C. Although only certain molten salts and halogens are corrosive to solid iridium, finely divided iridium dust is much more reactive and can even be flammable. The most important iridium compounds in use are the salts and acids it forms with chlorine, though iridium also forms a number of organometallic compounds used in catalysis and in research. 191Ir and 193Ir are the only two naturally occurring isotopes of iridium as well as the only stable isotopes; the latter is the more abundant of the two.

Iridium was discovered in 1803 by Smithson Tennant in London, England, among insoluble impurities in natural platinum from South America. Although it is one of the rarest elements in the Earth's crust, with annual production and consumption of only three tonnes, it has a number of specialized industrial and scientific applications. Iridium is employed when high corrosion resistance at high temperatures is needed, as in spark plugs, crucibles for recrystallization of semiconductors at high temperatures, electrodes for the production of chlorine in the chloralkali process, and radioisotope thermoelectric generators used in unmanned spacecraft. Iridium compounds also find applications as catalysts for the production of acetic acid.

An unusually high abundance of iridium in a clay layer of the K–T geologic boundary was a crucial clue that led to the theory that the extinction of dinosaurs and many other species 65 million years ago was caused by the impact of a massive extraterrestrial object—the so-called Alvarez hypothesis. Iridium is found in meteorites with an abundance much higher than its average abundance in the Earth's crust. It is thought that the amount of iridium in the planet Earth is much higher than that observed in crustal rocks, but because of the high density and tendency of iridium to bond with iron, most iridium descended below the crust and into the Earth's core when the planet was young and still molten.

Contents

Characteristics

Physical

A flattened drop of dark gray substance.
1 troy ounce (31 g) of arc-melted iridium

A member of the platinum group metals, iridium is white, resembling platinum, but with a slight yellowish cast. Because of its hardness, brittleness, and very high melting point (the ninth highest of all elements), solid iridium is difficult to machine, form, or work, and thus powder metallurgy is commonly employed instead.[3] It is the only metal to maintain good mechanical properties in air at temperatures above 1600 °C.[4] Iridium has a very high boiling point (11th among all elements) and becomes a superconductor at temperatures below 0.14 K.[5]

Iridium's modulus of elasticity is the second highest among the metals, only being surpassed by osmium.[4] This, together with a high modulus of rigidity and a very low figure for Poisson's ratio (the relationship of longitudinal to lateral strain), indicate the high degree of stiffness and resistance to deformation that have rendered its fabrication into useful components a matter of great difficulty. Despite these limitations and iridium's high cost, a number of applications have developed where mechanical strength is an essential factor in some of the extremely severe conditions encountered in modern technology.[4]

The measured density of iridium is only slightly lower (by about 0.1%) than that of osmium, the densest element known.[6][7] There had been some ambiguity regarding which of the two elements was denser, due to the small size of the difference in density and difficulties in measuring it accurately,[8] but, with increased accuracy in factors used for calculating density X-ray crystallographic data yielded densities of 22.56 g/cm3 for iridium and 22.59 g/cm3 for osmium.[9]

Chemical

Iridium is the most corrosion-resistant metal known:[10] it is not attacked by any acid, by aqua regia, by any molten metals, or by silicates at high temperatures. It can, however, be attacked by some molten salts, such as sodium cyanide and potassium cyanide,[10] as well as oxygen and the halogens (particularly fluorine)[11] at higher temperatures.[12]

Compounds

Oxidation states
of iridium[note 1]
−3 [Ir(CO)3]3−
−1 [Ir(CO)3(PPh3)]
0 Ir4(CO)12
+1 [Ir(CO)Cl(PPh3)2]
+2 IrCl2
+3 IrCl3
+4 IrO2
+5 Ir4F20
+6 IrF6

Iridium forms compounds in oxidation states between −3 to +6; the most common oxidation states are +3 and +4.[3] Well-characterized examples of the highest oxidation state are rare, but include IrF6 and two mixed oxides Sr2MgIrO6 and Sr2CaIrO6.[3][13]

Iridium dioxide, IrO2, a brown powder, is the only well-characterized oxide of iridium.[3] A sesquioxide, Ir2O3, has been described as a blue-black powder which is oxidized to IrO2 by HNO3.[11] The corresponding disulfides, diselenides, sesquisulfides and sesquiselenides are known and IrS3 has also been reported.[3] Iridium also forms iridates with oxidation states +4 and +5, such as K2IrO3 and KIrO3, which can be prepared from the reaction of potassium oxide or potassium superoxide with iridium at high temperatures.[14]

While no binary hydrides of iridium, IrxHy are known, complexes are known that contain IrH4−5 and IrH3−6, where iridium has the +1 and +3 oxidation states, respectively.[15] The ternary hydride Mg6Ir2H11 is believed to contain both the IrH4−5 and the 18-electron IrH5−4 anion.[16]

No monohalides or dihalides are known, whereas trihalides, IrX3, are known for all of the halogens.[3] For oxidation states +4 and above, only the tetrafluoride, pentafluoride and hexafluoride are known.[3] Iridium hexafluoride, IrF6, is a volatile and highly reactive yellow solid, composed of octahedral molecules. It decomposes in water and is reduced to IrF4, a crystalline solid, by iridium black.[3] Iridium pentafluoride has similar properties but it is actually a tetramer, Ir4F20, formed by four corner-sharing octahedra.[3]

Hexachloroiridic(IV) acid, H2IrCl6, and its ammonium salt are the most important iridium compounds from an industrial perspective.[17] They are involved in the purification of iridium and used as precursors for most other iridium compounds, as well as in the preparation of anode coatings. The IrCl2−6 ion has an intense dark brown color, and can be readily reduced to the lighter-colored IrCl3−6 and vice versa.[17] Iridium trichloride, IrCl3, which can be obtained in anhydrous form from direct oxidation of iridium powder by chlorine at 650 °C,[17] or in hydrated form by dissolving Ir2O3 in hydrochloric acid, is often used as a starting material for the synthesis of other Ir(III) compounds.[3] Another compound used as a starting material is ammonium hexachloroiridate(III), (NH4)3IrCl6. Iridium(III) complexes are diamagnetic (low-spin) and generally have an octahedral molecular geometry.[3]

Organoiridium compounds contain iridium–carbon bonds where the metal is usually in lower oxidation states. For example, oxidation state zero is found in tetrairidium dodecacarbonyl, Ir4(CO)12, which is the most common and stable binary carbonyl of iridium.[3] In this compound, each of the iridium atoms is bonded to the other three, forming a tetrahedral cluster. Some organometallic Ir(I) compounds are notable enough to be named after their discoverers. One is Vaska's complex, IrCl(CO)[P(C6H5)3]2, which has the unusual property of binding to the dioxygen molecule, O2.[18] Another one is Crabtree's catalyst, a homogeneous catalyst for hydrogenation reactions.[19] These compounds are both square planar, d8 complexes, with a total of 16 valence electrons, which accounts for their reactivity.[20]

Isotopes

Iridium has two naturally occurring, stable isotopes, 191Ir and 193Ir, with natural abundances of 37.3% and 62.7%, respectively.[21] At least 34 radioisotopes have also been synthesized, ranging in mass number from 164 to 199. 192Ir, which falls between the two stable isotopes, is the most stable radioisotope, with a half-life of 73.827 days, and finds application in brachytherapy[22] and in industrial radiography, particularly for non-destructive testing of welds in steel in the oil and gas industries; iridium-192 sources have been responsible for a number of radiological accidents. Three other isotopes have half-lives of at least a day—188Ir, 189Ir, 190Ir.[21] Isotopes with masses below 191 decay by some combination of β+ decay, α decay, and proton emission, with the exceptions of 189Ir, which decays by electron capture, and 190Ir, which decays by positron emission. Synthetic isotopes heavier than 191 decay by β decay, although 192Ir also has a minor electron capture decay path.[21] All known isotopes of iridium were discovered between 1934 and 2001; the most recent is 171Ir.[23]

At least 32 metastable isomers have been characterized, ranging in mass number from 164 to 197. The most stable of these is 192m2Ir, which decays by isomeric transition with a half-life of 241 years,[21] making it more stable than any of iridium's synthetic isotopes in their ground states. The least stable isomer is 190m3Ir with a half-life of only 2 µs.[21] The isotope 191Ir was the first one of any element to be shown to present a Mössbauer effect. This renders it useful for Mössbauer spectroscopy for research in physics, chemistry, biochemistry, metallurgy, and mineralogy.[24]

History

The discovery of iridium is intertwined with that of platinum and the other metals of the platinum group. Native platinum used by ancient Ethiopians[25] and by South American cultures[26] always contained a small amount of the other platinum group metals, including iridium. Platinum reached Europe as platina ("small silver"), found in the 17th century by the Spanish conquerors in a region today known as the department of Chocó in Colombia.[27] The discovery that this metal was not an alloy of known elements, but instead a distinct new element, did not occur until 1748.[28]

Chemists who studied platinum dissolved it in aqua regia (a mixture of hydrochloric and nitric acids) to create soluble salts. They always observed a small amount of a dark, insoluble residue.[4] Joseph Louis Proust thought that the residue was graphite.[4] The French chemists Victor Collet-Descotils, Antoine François, comte de Fourcroy, and Louis Nicolas Vauquelin also observed the black residue in 1803, but did not obtain enough for further experiments.[4]

In 1803, British scientist Smithson Tennant (1761–1815) analyzed the insoluble residue and concluded that it must contain a new metal. Vauquelin treated the powder alternatively with alkali and acids[10] and obtained a volatile new oxide, which he believed to be of this new metal—which he named ptene, from the Greek word πτηνος (ptènos) for winged.[29][30] Tennant, who had the advantage of a much greater amount of residue, continued his research and identified the two previously undiscovered elements in the black residue, iridium and osmium.[4][10] He obtained dark red crystals (probably of Na2[IrCl6nH2O) by a sequence of reactions with sodium hydroxide and hydrochloric acid.[30] He named iridium after Iris (Ιρις), the Greek winged goddess of the rainbow and the messenger of the Olympian gods, because many of the salts he obtained were strongly colored.[note 2][31] Discovery of the new elements was documented in a letter to the Royal Society on June 21, 1804.[4][32]

Photo of part of a black vase with brown picture on it: A woman with wings on her back hold an arrow with right hand and gives a jar to a man. A small deer is standing in front of the woman.
The Greek goddess Iris, after whom iridium was named.

British scientist John George Children was the first to melt a sample of iridium in 1813 with the aid of "the greatest galvanic battery that has ever been constructed" (at that time).[4] The first to obtain high purity iridium was Robert Hare in 1842. He found that it had a density of around 21.8 g/cm3 and noted that the metal is nearly unmalleable and very hard. The first melting in appreciable quantity was done by Henri Sainte-Claire Deville and Jules Henri Debray in 1860. They required burning more than 300 L of pure O2 and H2 for each kilogram of iridium.[4]

These extreme difficulties in melting the metal limited the possibilities for handling iridium. John Isaac Hawkins was looking to obtain a fine and hard point for fountain pen nibs and in 1834 managed to create an iridium-pointed gold pen. In 1880 John Holland and William Lofland Dudley were able to melt iridium by adding phosphorus and patented the process in the United States; British company Johnson Matthey later stated that they had been using a similar process since 1837 and had already presented fused iridium at a number of World Fairs.[4] The first use of an alloy of iridium with ruthenium in thermocouples was made by Otto Feussner in 1933. These allowed for the measurement of high temperatures in air up to 2000 °C.[4]

In 1957 Rudolf Mössbauer, in what has been called one of the "landmark experiments in twentieth century physics",[33] discovered the resonant and recoil-free emission and absorption of gamma rays by atoms in a solid metal sample containing only 191Ir.[34] This phenomenon, known as the Mössbauer effect (which has since been observed for other nuclei, such as 57Fe), and developed as Mössbauer spectroscopy, has made important contributions to research in physics, chemistry, biochemistry, metallurgy, and mineralogy.[24] Mössbauer received the Nobel Prize in Physics in 1961, just three years after he published his discovery.[35]

Occurrence

A large black egg)shaped boulder of porous structure standing on its top, tilted.
The Willamette Meteorite, the sixth largest meteorite found in the world, has 4.7 ppm iridium.[36]

Iridium is one of the least abundant elements in the Earth's crust, having an average mass fraction of 0.001 ppm in crustal rock; gold is 4 times more abundant, platinum is 10 times more abundant, and silver and mercury are 80 times more abundant.[3] Tellurium is about as abundant as iridium, and only three naturally occurring elements are less abundant: rhenium, ruthenium, and rhodium, iridium being 10 times more abundant than the last two.[3] In contrast to its low abundance in crustal rock, iridium is relatively common in meteorites, with concentrations of 0.5 ppm or more.[37] It is thought that the overall concentration of iridium on Earth is much higher than what is observed in crustal rocks, but because of the density and siderophilic ("iron-loving") character of iridium, it descended below the crust and into the Earth's core when the planet was still molten.[17]

Iridium is found in nature as an uncombined element or in natural alloys; especially the iridium–osmium alloys, osmiridium (osmium rich), and iridiosmium (iridium rich).[10] In the nickel and copper deposits the platinum group metals occur as sulfides (i.e. (Pt,Pd)S)), tellurides (i.e. PtBiTe), antimonides (PdSb), and arsenides (i.e. PtAs2). In all of these compounds platinum is exchanged by a small amount of iridium and osmium. As with all of the platinum group metals, iridium can be found naturally in alloys with raw nickel or raw copper.[38]

Within the Earth's crust, iridium is found at highest concentrations in three types of geologic structure: igneous deposits (crustal intrusions from below), impact craters, and deposits reworked from one of the former structures. The largest known primary reserves are in the Bushveld igneous complex in South Africa,[39] though the large copper–nickel deposits near Norilsk in Russia, and the Sudbury Basin in Canada are also significant sources of iridium. Smaller reserves are found in the United States.[39] Iridium is also found in secondary deposits, combined with platinum and other platinum group metals in alluvial deposits. The alluvial deposits used by pre-Columbian people in the Chocó Department of Colombia are still a source for platinum-group metals. As of 2003 the world reserves had not been estimated.[10]

K–T boundary presence

A cliff with pronounced layered structure: yellow, gray, white, gray. A red arrow points between the yellow and gray layers.
The red arrow points to the K–T boundary.

The K–T boundary of 65 million years ago, marking the temporal border between the Cretaceous and Tertiary periods of geological time, was identified by a thin stratum of iridium-rich clay.[40] A team led by Luis Alvarez proposed in 1980 an extraterrestrial origin for this iridium, attributing it to an asteroid or comet impact.[40] Their theory, known as the Alvarez hypothesis, is now widely accepted to explain the demise of the dinosaurs. A large buried impact crater structure with an estimated age of about 65 million years was later identified under what is now the Yucatán Peninsula (the Chicxulub crater).[41][42] Dewey M. McLean and others argue that the iridium may have been of volcanic origin instead, as the Earth's core is rich in iridium, and active volcanoes such as Piton de la Fournaise, in the island of Réunion, are still releasing iridium.[43][44]

Production

Year Price
($/ozt)[45][46]
2001 415.25
2002 294.62
2003 93.02
2004 185.33
2005 169.51
2006 349.45
2007 440.00

Iridium is obtained commercially as a by-product from nickel and copper mining and processing. During electrorefining of copper and nickel, noble metals such as silver, gold and the platinum group metals as well as selenium and tellurium settle to the bottom of the cell as anode mud, which forms the starting point for their extraction.[45][47] In order to separate the metals, they must first be brought into solution. Several methods are available depending on the separation process and the composition of the mixture; two representative methods are fusion with sodium peroxide followed by dissolution in aqua regia, and dissolution in a mixture of chlorine with hydrochloric acid.[17][39]

After it is dissolved, iridium is separated from the other platinum group metals by precipitating (NH4)2IrCl6 or by extracting IrCl2−6 with organic amines.[48] The first method is similar to the procedure Tennant and Wollaston used for their separation. The second method can be planned as continuous liquid–liquid extraction and is therefore more suitable for industrial scale production. In either case, the product is reduced using hydrogen, yielding the metal as a powder or sponge that can be treated using powder metallurgy techniques.[49][50]

Annual production of iridium circa 2000 was around 3 tonnes or about 100,000 troy ounces (ozt).[note 3][10] The price of iridium as of 2007 was $440 USD/ozt,[45] but the price fluctuates considerably, as shown in the table. The high volatility of the prices of the platinum group metals has been attributed to supply, demand, speculation, and hoarding, amplified by the small size of the market and instability in the producing countries.[51]

Applications

The global demand for iridium in 2007 was 119,000 troy ounces (3,700 kg), out of which 25,000 ozt (780 kg) were used for electrical applications such as spark plugs; 34,000 ozt (1,100 kg) for electrochemical applications such as electrodes for the chloralkali process; 24,000 ozt (750 kg) for catalysis; and 36,000 ozt (1,100 kg) for other uses.[52]

Industrial and medical

Skeletal formula of a chemical compound with iridium atom in its center, bonded to 6 benzol rings. The rings are pairwise connected to each other.
Molecular structure of Ir(mppy)3

The high melting point, hardness and corrosion resistance of iridium and its alloys determine most of its applications. Iridium and especially iridium–platinum alloys or osmium–iridium alloys have a low wear and are used, for example, for multi-pored spinnerets, through which a plastic polymer melt is extruded to form fibers, such as rayon.[53] Osmium–iridium is used for compass bearings and for balances.[10]

Corrosion and heat resistance makes iridium an important alloying agent. Certain long-life aircraft engine parts are made of an iridium alloy and an iridium–titanium alloy is used for deep-water pipes because of its corrosion resistance.[10] Iridium is also used as a hardening agent in platinum alloys. The Vickers hardness of pure platinum is 56 HV while platinum with 50% of iridium can reach over 500 HV.[54][55]

Devices that must withstand extremely high temperatures are often made from iridium. For example, high-temperature crucibles made of iridium are used in the Czochralski process to produce oxide single-crystals (such as sapphires) for use in computer memory devices and in solid state lasers.[56][57] The crystals, such as gadolinium gallium garnet and yttrium gallium garnet, are grown by melting pre-sintered charges of mixed oxides under oxidizing conditions at temperatures up to 2100 °C.[4] Its resistance to arc erosion makes iridium alloys ideal for electrical contacts for spark plugs.[57][58]

Iridium compounds are used as catalysts in the Cativa process for carbonylation of methanol to produce acetic acid.[59] Iridium itself is used as a catalyst in a type of automobile engine introduced in 1996 called the direct-ignition engine.[10]

The radioisotope iridium-192 is one of the two most important sources of energy for use in industrial γ-radiography for non-destructive testing of metals.[60][61] Additionally, 192Ir is used as a source of gamma radiation for the treatment of cancer using brachytherapy, a form of radiotherapy where a sealed radioactive source is placed inside or next to the area requiring treatment. Specific treatments include high dose rate prostate brachytherapy, bilary duct brachytherapy, and intracavitary cervix brachytherapy.[10]

Scientific

An alloy of 90% platinum and 10% iridium was used in 1889 to construct the International Prototype Meter and kilogram mass, kept by the International Bureau of Weights and Measures near Paris.[10] The meter bar was replaced as the definition of the fundamental unit of length in 1960 by a line in the atomic spectrum of krypton,[note 4][62] but the kilogram prototype is still the international standard of mass.[63]

Iridium has been used in the radioisotope thermoelectric generators of unmanned spacecraft such as the Voyager, Viking, Pioneer, Cassini, Galileo, and New Horizons. Iridium was chosen to encapsulate the plutonium-238 fuel in the generator because it can withstand the operating temperatures of up to 2000 °C and for its great strength.[4]

Another use concerns X-ray optics, especially X-ray telescopes.[64] The mirrors of the Chandra X-ray Observatory are coated with a layer of iridium 60 nm thick. Iridium proved to be the best choice for reflecting X-rays after nickel, gold, and platinum were tested. The iridium layer, which had to be smooth to within a few atoms, was applied by depositing iridium vapor under high vacuum on a base layer of chromium.[65]

Iridium is used in particle physics for the production of antiprotons, a form of antimatter. Antiprotons are made by shooting a high-intensity proton beam at a conversion target, which needs to be made from a very high density material. Although tungsten may be used instead, iridium has the advantage of better stability under the shock waves induced by the temperature rise due to the incident beam.[66]

Skeletal formula presentation of a chemical transformation. The initial compounds have a C5H5 ring on their top and an iridium atom in the center, which is bonded to two hydrogen atoms and a P-PH3 group or to two C-O groups. Reaction with alkane under UV light alters those groups.
Oxidative addition to hydrocarbons in organoiridium chemistry.[67][68]

Carbon–hydrogen bond activation (C–H activation) is an area of research on reactions that cleave carbon–hydrogen bonds, which were traditionally regarded as unreactive. The first reported successes at activating C–H bonds in saturated hydrocarbons, published in 1982, used organometallic iridium complexes that undergo an oxidative addition with the hydrocarbon.[68][67]

Iridium complexes are being investigated as catalysts for asymmetric hydrogenation. These catalysts have been used in the synthesis of natural products and able to hydrogenate certain difficult substrates, such as unfunctionalized alkenes, enantioselectively (generating only one of the two possible enantiomers).[69][70]

Iridium forms a variety of complexes of fundamental interest in triplet harvesting.[71][72][73]

Historical

Fountain pen tip made of yellowish metal
Fountain pen nib labeled Iridium Point

Iridium–osmium alloys were used to tip fountain pen nibs. The first major use of iridium was in 1834 in nibs mounted on gold.[4] Since 1944, the famous Parker 51 fountain pen was fitted with a nib tipped by a ruthenium and iridium alloy (with 3.8% iridium). The tip material in modern fountain pens is still conventionally called "iridium," although there is seldom any iridium in it; other metals such as tungsten have taken its place.[74]

An iridium–platinum alloy was used for the touch holes or vent pieces of cannon. According to a report of the Paris Exhibition of 1867, one of the pieces being exhibited by Johnson and Matthey "has been used in a Withworth gun for more than 3000 rounds, and scarcely shows signs of wear yet. Those who know the constant trouble and expense which are occasioned by the wearing of the vent-pieces of cannon when in active service, will appreciate this important adaptation".[75]

The pigment iridium black, which consists of very finely divided iridium, is used for painting porcelain an intense black; it was said that "all other porcelain black colors appear grey by the side of it".[76]

Precautions

Iridium in bulk metallic form is not biologically important or hazardous to health due to its lack of reactivity with tissues; there are only about 20 parts per trillion of iridium in human tissue.[10] However, finely divided iridium powder can be hazardous to handle, as it is an irritant and may ignite in air.[39] Very little is known about the toxicity of iridium compounds because they are used in very small amounts, but soluble salts, such as the iridium halides, could be hazardous due to elements other than iridium or due to iridium itself.[22] However, most iridium compounds are insoluble, which makes absorption into the body difficult.[10]

A radioisotope of iridium, 192Ir, is dangerous like other radioactive isotopes. The only reported injuries related to iridium concern accidental exposure to radiation from 192Ir used in brachytherapy.[22] High-energy gamma radiation from 192Ir can increase the risk of cancer. External exposure can cause burns, radiation poisoning, and death. Ingestion of 192Ir can burn the linings of the stomach and the intestines.[77] 192Ir, 192mIr, and 194mIr tend to deposit in the liver, and can pose health hazards from both gamma and beta radiation.[37]

Notes

  1. ^ Common oxidation states are in bold.
  2. ^ Iridium literally means "of rainbows".
  3. ^ Like other precious metals, iridium is customarily traded in troy ounces, which are equivalent to about 31.1 grams.
  4. ^ The definition of the meter was changed again in 1983. The meter is currently defined as the distance traveled by light in a vacuum during a time interval of 1299,792,458 of a second.

References

  1. ^ J. W. Arblaster: Densities of Osmium and Iridium, in: Platinum Metals Review, 1989, 33, 1, S. 14–16; Volltext.
  2. ^ Magnetic susceptibility of the elements and inorganic compounds, in Handbook of Chemistry and Physics 81st edition, CRC press.
  3. ^ a b c d e f g h i j k l m n Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. pp. 1113–1143,1294. ISBN 0-7506-3365-4. OCLC 37499934 41901113 213025882 37499934 41901113. 
  4. ^ a b c d e f g h i j k l m n o Hunt, L. B. (1987). "A History of Iridium". Platinum Metals Review 31 (1): 32–41. http://www.platinummetalsreview.com/dynamic/article/view/pmr-v31-i1-032-041. 
  5. ^ Kittel, C. (2004). Introduction to Solid state Physics, 7th Edition. Wiley-India. ISBN 8126510455. 
  6. ^ Arblaster, J. W. (1995). "Osmium, the Densest Metal Known". Platinum Metals Review 39 (4): 164. http://www.platinummetalsreview.com/dynamic/article/view/pmr-v39-i4-164-164. 
  7. ^ Cotton, Simon (1997). Chemistry of Precious Metals. Springer-Verlag New York, LLC. p. 78. 
  8. ^ Lide, D. R. (1990). CRC Handbook of Chemistry and Physics (70th Edn.). Boca Raton (FL):CRC Press. 
  9. ^ Arblaster, J. W. (1989). "Densities of osmium and iridium: recalculations based upon a review of the latest crystallographic data" (PDF). Platinum Metals Review 33 (1): 14–16. http://www.platinummetalsreview.com/pdf/pmr-v33-i1-014-016.pdf. 
  10. ^ a b c d e f g h i j k l m n Emsley, J. (2003). "Iridium". Nature's Building Blocks: An A-Z Guide to the Elements. Oxford, England, UK: Oxford University Press. pp. 201–204. ISBN 0198503407. 
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External links


1911 encyclopedia

Up to date as of January 14, 2010

From LoveToKnow 1911

IRIDIUM (symbol Ir.; atomic weight 193.1), one of the metals of the platinum group, discovered in 1802 by Smithson Tennant during the examination of the residue left when platinum ores are dissolved in aqua regia; the element occurs in platinum ores in the form of alloys of platinum and iridium, and of osmium and iridium. Many methods have been devised for the separation of these metals (see Platinum), one of the best being that of H. St. C. Deville and H. J. Debray (Comptes rendus, 1874, 78, p. 1502). In this process the osmiridium is fused with zinc and the excess of zinc evaporated; the residue is then ignited with barium nitrate, extracted with water and boiled with nitric acid. The iridium is then precipitated from the solution (as oxide) by the addition of baryta, dissolved in aqua regia, and precipitated as iridium ammonium chloride by the addition of ammonium chloride. The double chloride is fused with nitre, the melt extracted with water and the residue fused with lead, the excess of lead being finally removed by solution in nitric acid and aqua regia. It is a brittle metal of specific gravity 22 . 4 (Deville and Debray), and is only fusible with great difficulty. It may be obtained in the spongy form by igniting iridium ammonium chloride, and this variety of the metal readily oxidizes when heated in air.

Two oxides of iridium are known, namely the sesquioxide, Ir203, and the dioxide, Ir02, corresponding to which there are two series of salts, the sesqui-salts and the iridic salts; a third series of salts is also known (the iridious salts) derived from an oxide IrO. Iridium sesquioxide, Ir 2 0 3, is obtained when potassium iridium chloride is heated with sodium or potassium carbonates, in a stream of carbon dioxide. It is a bluish-black powder which at high temperatures decomposes into the metal, dioxide and oxygen. The hydroxide, Ir(OH) 3, may be obtained by the addition of caustic potash to iridium sodium chloride, the mixture being then heated with alcohol. Iridium dioxide, Ir0 2, may be obtained as small needles by heating the metal to bright redness in a current of oxygen (G. Geisenheimer, Comptes rendus, 1890, 110, p. 855). The corresponding hydroxide, Ir(OH) 4, is formed when potassium iridate is boiled with ammonium chloride, or when the tetrachloride is boiled with caustic potash or sodium carbonate. It is an indigo-blue powder, soluble in hydrochloric acid, but insoluble in dilute nitric and sulphuric acids. On the oxides see L. Wohler and W. Witzmann, Zeit. anorg. Chem. (1908), 57, p. 323. Iridium sesquichloride, IrC1 31 is obtained when one of the corresponding double chlorides is heated with concentrated sulphuric acid, the mixture being then thrown into water. It is thus obtained as an olive green precipitate which is insoluble in acids and alkalis. Potassium iridium sesquichloride, K 3 IrC1 6.3H 2 O, is obtained by passing sulphur dioxide into a suspension of potassium chloriridate in water until all dissolves, and then adding potassium carbonate to the solution (C. Claus, Jour. prak. Chem., 18 47, 42, p. 35 1). It forms green prisms which are readily soluble in water. Similar sodium and ammonium compounds are known. Iridium tetrachloride, IrC1 41 is obtained by dissolving the finely divided metal in aqua regia; by dissolving the hydroxide in hydrochloric acid; and by digesting the hydrated sesquichloride with nitric acid. On evaporating the solution (not above 40° C.) a dark mass is obtained, which contains a little sesquichloride. It forms double chlorides with the alkaline chlorides. For a bromide see A. Gautbier and M. Riess, Ber., 1909, 42, p. 39 0 5. Iridium sulphide, IrS, is obtained when the metal is ignited in sulphur vapour. The sesquisulphide, Ir 2 S 3, is obtained as a brown precipitate when sulphuretted hydrogen is passed into a solution of one of the sesqui-salts. It is slightly soluble in potassium sulphide. The disulphide, IrS2, is formed when powdered iridium is heated with sulphur and an alkaline carbonate. It is a dark brown powder. Iridium forms many ammine derivatives, which are analogous to the corresponding platinum compounds (see M. Skoblikoff, Jahresb., 1852, p. 428; W. Palmer, Ber., 1889, 22, p. 15; 1890, 23, p. 3810; 1891, 24, p. 2090; Zeit. anorg. Chem., 1896, 13, p. 211).

Iridium is always determined quantitatively by conversion into the metallic state. The atomic weight of the element has been determined in various ways, C. Seubert (Ber., 1878, I I, p. 1770), by the analysis of potassium chloriridate obtaining the value 192.74, and A. Joly (Comptes rendus, 1890, 110, p. 1131) from analyses of potassium and ammonium chloriridites, the value 191.78 (0 =15.88).


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Wiktionary

Up to date as of January 15, 2010

Definition from Wiktionary, a free dictionary

See also iridium

German

Chemical Element: Ir (atomical number 77)

Noun

Iridium n

  1. iridium

Simple English

Iridium is the 77th element on the periodic table. Its symbol is Ir.

Iridium is a metal. It is very hard to find and costs a lot. It is known as a "noble metal". It looks like platinum and is found in asteroids and comets. It can be used to find out when an asteroid or comet will hit the Earth. It is a very costly metal that can fold and bend just like aluminum.

Iridium is not needed in the body.

A man named Smithson Tennant first found it in the year 1803.








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