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In Liming for parchment or leather processing, the hides are soaked in an alkali solution by a drum/paddle or pit based operation where four main objectives are met. The objectives are ^[1]:

• Removal of interfibrillary proteins .
• Removal of Keratin proteins.
• Collagen swelling due to the alkaline pH.
• Collagen fibre bundle splitting.

Liming operations of cattle hides usually last 18 hours and are generally associated with the alkaline phase of beamhouse operations. Historically, the liming pits were used and were one the longest operations.

Removal of interfibrillary proteins

• The interfibrillary proteins are denatured by the presence of alkali (particularly sodium sulfide), rendered soluble, facilitating their removal from the leather. Removal is done by the mechanical action of liming or reliming, but more prominently when the pelt is deswelled (during deliming). Failure to remove these proteins results in a hard, tinny leather (due to fibre glueing upon drying) that is brittle and inflexible.

Keratin removal

• Keratin that is present in the hair, scales and in the epidermis of the skin is hydrolyzed in the presence of alkali (at pH values greater than 11.5). The disulfide bridges found in keratin protein is cleaved but can reform. Long periods of liming will result in hair removal. The main removal of keratin is performed using the unhairing operation. In traditional processing liming/unhairing was indivisible and took place at the same time. Modern liming methods, and in particular, the processing of sheepskins the hair is removed first and then limed in a liming drum. In hair-save technology, the hides are unhaired first and then limed for a further 12-18 hours.

Alkaline collagen swelling

• The presence of calcium hydroxide results in the alkaline swelling of skin. The result is the influx of water into the hide/skin and a marked increase in fibre diameter and fibre shortening. The thickness of the skin increases, but the surface area of the pelt decreases. The weight increase, due to the uptake of water results in a doubling of the hide/skin weight. But, this weight also needs to take into consideration that proteins (especially the hair) have been removed and the fleshing operation is often performed after liming.

Collagen fibre bundle splitting

• The action of liming, in particular the swelling of the skin results in the splitting of the fibre bundle sheath. Due to the fibre diameter increasing, the bundle sheath cannot contain the thicker fibres and it bursts open. This allows increased access to the fibres which allows better tanning, retanning, dyeing and fatliquoring.

References

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