From Wikipedia, the free encyclopedia
|
|
| Appearance |
silvery white solid
 |
| General properties |
| Name, symbol, number |
magnesium, Mg, 12 |
| Element category |
alkaline earth metal |
| Group, period, block |
2, 3, s |
| Standard atomic weight |
24.3050(6) g·mol−1 |
| Electron configuration |
[Ne] 3s2 |
| Electrons per shell |
2, 8, 2 (Image) |
| Physical properties |
| Phase |
solid |
| Density (near r.t.) |
1.738 g·cm−3 |
| Liquid density at m.p. |
1.584 g·cm−3 |
| Melting point |
923 K, 650 °C, 1202 °F |
| Boiling point |
1363 K, 1091 °C, 1994 °F |
| Heat of fusion |
8.48 kJ·mol−1 |
| Heat of vaporization |
128 kJ·mol−1 |
| Specific heat capacity |
(25 °C) 24.869 J·mol−1·K−1 |
| Vapor pressure |
| P/Pa |
1 |
10 |
100 |
1 k |
10 k |
100 k |
| at T/K |
701 |
773 |
861 |
971 |
1132 |
1361 |
|
| Atomic properties |
| Oxidation states |
2, 1 [1]
(strongly basic oxide) |
| Electronegativity |
1.31 (Pauling scale) |
Ionization energies
(more) |
1st: 737.7 kJ·mol−1 |
| 2nd: 1450.7 kJ·mol−1 |
| 3rd: 7732.7 kJ·mol−1 |
| Atomic radius |
160 pm |
| Covalent radius |
141±7 pm |
| Van der Waals radius |
173 pm |
| Miscellanea |
| Crystal structure |
hexagonal |
| Magnetic ordering |
paramagnetic |
| Electrical resistivity |
(20 °C) 43.9 nΩ·m |
| Thermal conductivity |
(300 K) 156 W·m−1·K−1 |
| Thermal expansion |
(25 °C) 24.8 µm·m−1·K−1 |
| Speed of sound (thin rod) |
(r.t.) (annealed)
4940 m·s−1 |
| Young's modulus |
45 GPa |
| Shear modulus |
17 GPa |
| Bulk modulus |
45 GPa |
| Poisson ratio |
0.290 |
| Mohs hardness |
2.5 |
| Brinell hardness |
260 MPa |
| CAS registry number |
7439-95-4 |
| Most stable isotopes |
| Main article: Isotopes of magnesium |
|
|
|
This box: view • talk • edit
|
Magnesium (pronounced
/mæɡˈniːziəm/,
mag-NEE-zee-əm) is a
chemical element with the symbol
Mg,
atomic number 12 and common oxidation number +2. It is an
alkaline earth metal and the eighth most
abundant element in the Earth's crust, where it constitutes about 2% by mass,
[2] and ninth in the known
Universe as a whole.
[3][4] This preponderance of magnesium is related to the fact that it is easily built up in supernova stars from a sequential addition of three helium nuclei to carbon (which in turn is made from three helium nuclei).
.^ Cobalamin is water-soluble (can dissolve in water) and must be taken in every day.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Sources and uses Titanium, the ninth most abundant element in the earth's crust, is widely distributed.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Natural Occurrence Titanium is the ninth most abundant element in the earth's crust.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[5]
.^ Thus, the aortic bodies of the cat play a significant role in the hyperventilation produced by cytotoxic hypoxia, although it is less marked than that induced through the carotid bodies.
Hundreds of enzymes thus require magnesium ions in order to function. Magnesium is also the metallic ion at the center of
chlorophyll, and is thus a common additive to fertilizers.
[6] .^ The number of mature and immature abnormal white blood cells in the bone marrow and blood is higher than normal, but lower than in the accelerated or blast phase.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Surgery in which a healthy blood vessel taken from another part of the body is used to make a new path for blood around a blocked artery leading to the heart.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ A benign, slow-growing tumor in the cerebellum (part of the brain at the back of the head), made up of abnormal blood vessel growth.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Magnesium ions are sour to the taste, and in low concentrations help to impart a natural tartness to fresh mineral waters.
.^ A metallic element that occurs naturally in tiny amounts in air, water, soil, and food.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ It is an antioxidant that helps prevent cell damage caused by free radicals (highly reactive chemicals).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
The free metal burns with a characteristic brilliant white light, making it a useful ingredient in flares. The metal is now mainly obtained by electrolysis of magnesium salts obtained from
brine.
.^ It is a byproduct of zinc refining, and is used to make batteries, pigments, plastics, alloys, and electroplate.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ When radioactive material is used to examine the thyroid with a scanner, nodules that collect less radioactive material than the surrounding thyroid tissue are considered "cold."- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ In medicine, chelating agents are used to remove toxic metals from the body.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Characteristics
Physical and chemical
.^ Soft, silvery white metal which oxidizes rapidly when cut.- Mineral Species sorted by the element Na Sodium 6 January 2010 8:54 UTC webmineral.com [Source type: FILTERED WITH BAYES]
^ A series of x-ray pictures of the esophagus taken after a patient drinks a liquid containing barium sulfate (a form of the silver-white metallic element barium).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ A drug used to treat certain types of leukemia and prevent the spread of leukemia to the meninges (three thin layers of tissue that cover and protect the brain and spinal cord).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ The fluid that flows in and around the hollow spaces of the brain and spinal cord, and between two of the meninges (the thin layers of tissue that cover and protect the brain and spinal cord).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ It is used to treat lymphoma that has spread to the meninges (three thin layers of tissue that cover and protect the brain and spinal cord).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ The occurrence of a larger-than-expected number of cases of cancer within a group of people in a geographic area over a period of time.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Titanium and its alloys may react strongly with oxidizing agents, especially when in the form of powdered metal (Mogilevskaja, 1972; ACGIH, 1973).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Titanium metal powder is usually produced by reaction of the metal with hydrogen; the resulting brittle titanium hydride is then crushed before heating in a vacuum to remove the hydrogen (Stamper, 1970).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The resulting cyanide ion may then form hydrogen cyanide or react with various metals present in natural water.
The reaction will occur faster with higher temperatures (see precautions). Magnesium also reacts exothermically with most acids, such as
hydrochloric acid (HCl). As with aluminium, zinc and many other metals, the reaction with hydrochloric acid produces the chloride of the metal and releases hydrogen gas.
.^ It is extremely resistant to corrosion and, in the form of a powder or dust, is highly flammable and explosive.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Magnesium Metal Powder .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
.^ This is usually done with a special instrument that contains liquid nitrogen or liquid carbon dioxide.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Titanium tetrachloride is a liquid, which is stable in dry air, but decomposes in cold water to form titanium oxide and hydrochloric acid.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ If Silver's stolen starter is Totodile , he uses Croconaw at level 16 in his second battle, despite Totodile only being able to evolve from level 18 onwards.- Silver (game) - Bulbapedia, the community-driven Pokémon encyclopedia 8 January 2010 3:31 UTC bulbapedia.bulbagarden.net [Source type: General]
^ During the Second World War, a protective film of cream containing titanium dioxide was used on exposed parts of the body to prevent flash burns (Fairhall, 1969).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
On burning in air, magnesium produces a brilliant white light. Thus magnesium powder (
flash powder) was used as a source of illumination in the early days of
photography. Later, magnesium ribbon was used in electrically ignited flash bulbs. Magnesium powder is used in the manufacture of
fireworks and marine
flares where a brilliant white light is required.
.^ Used as bulk metal and in lightweight alloys with magnesium for engines, also as a sacrificial electrode to protect other metals.- Mineral Species sorted by the element Mg Magnesium 16 January 2010 3:03 UTC webmineral.com [Source type: Reference]
^ Uses of Titanium Titanium, used as a construction material, is usually in the form of alloys, most of which have higher strength than pure titanium and enhanced corrosion resistance.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Klein & Russel (1973) reported that soils around a coal- burning power plant contained higher levels of trace metals than surrounding areas.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[8] .^ Titanium does not easily atomize and has a tendency to form refractory oxides, which may influence the use of atomic absorption assays.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Powdered Iron Oxide .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
^ Iron Oxide Powder .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
Magnesium compounds are typically white crystals. Most are soluble in water, providing the sour-tasting magnesium ion Mg
2+.
.^ A metallic element that occurs naturally in tiny amounts in air, water, soil, and food.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Magnesium ion in large amounts is an ionic laxative, and
magnesium sulfate (common name:
Epsom salt) is sometimes used for this purpose. So-called "milk of magnesia" is a water suspension of one of the few insoluble magnesium compounds,
magnesium hydroxide. The undissolved particles give rise to its appearance and name.
.^ A drug used to treat high blood pressure that is also being studied in the prevention of side effects caused by radiation therapy used in the treatment of cancer.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ They may be used as hormone replacement, to suppress the immune system, and to treat some side effects of cancer and its treatment.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ It is being studied in the prevention and treatment of some types of cancer and heart disease and in the relief of side effects caused by some cancer treatments.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Isotopes
Magnesium has three stable
isotopes:
24Mg,
25Mg and
26Mg. All are present in significant amounts (see table of isotopes above). About 79% of Mg is
24Mg.
.^ The average level of titanium in soils in the vicinity of this power plant was 92 mg/kg compared with a back- ground level of 56 mg/kg.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
This isotope has a relatively short half-life (21 hours) and so its use was limited by shipping times.
26Mg has found application in
isotopic geology, similar to that of aluminium.
26Mg is a
radiogenic daughter product of
26Al, which has a
half-life of 717,000 years.
.^ The concentration and distribution, in healthy human tissues, of a large number of stable elements including titanium was studied by Hamilton et al.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
The anomalous abundance of
26Mg is attributed to the decay of its parent
26Al in the inclusions. Therefore, the meteorite must have formed in the
solar nebula before the
26Al had decayed. Hence, these fragments are among the oldest objects in the
solar system and have preserved information about its early history.
It is conventional to plot
26Mg/
24Mg against an Al/Mg ratio. In an
isochron dating plot, the Al/Mg ratio plotted is
27Al/
24Mg.
.^ It has been suggested that levels in herbage samples are indicators of soil contamination (Barlow et al., 1960).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
Occurrence
.^ Sources and uses Titanium, the ninth most abundant element in the earth's crust, is widely distributed.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The detection limits for titanium in human tissues were 0.007 mg/kg for spark-source mass spectroscopy and 0.3 mg/kg wet weight for the XRF assay.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ In most studies on concentrations of titanium in blood, levels reported have been about 0.02-0.07 mg/litre.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
To extract the magnesium,
calcium hydroxide is added to
sea water to form
magnesium hydroxide precipitate.
- MgCl2 + Ca(OH)2 → Mg(OH)2 + CaCl2
.^ Consequently, as was pointed out by Bertine & Goldberg (1971), the contribution to the titanium concentrations in air and natural waters will be most evident at these latitudes.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The metal is highly resistant to corrosion by many agents including concentrated nitric acid, 5% sulfuric acid, and sea water.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Titanium tetrachloride is a liquid, which is stable in dry air, but decomposes in cold water to form titanium oxide and hydrochloric acid.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
- Mg(OH)2 + 2 HCl → MgCl2 + 2 H2O
- Mg2+ + 2 e− → Mg
At the
anode, each pair of
Cl− ions is oxidized to
chlorine gas, releasing two electrons to complete the circuit:
- 2 Cl− → Cl2 (g) + 2 e−
.^ Trans World Alloys View Website Gardena, CA 800-258-8180 Request For Quote Trans World Alloys Company is a full service supplier of metals such as titanium alloys.- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
^ Buy titanium from us today for a quality metal.- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
^ The products that are available in the United States may not contain the same amount or mixture of ingredients and may not be effective.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
[9]
.^ Our standard materials include Neoprene, EPDM, Bunga-N, Natural Rubber & high or low temperature silicone.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ Describes the process inside a cell that occurs when the same signal is shared by two or more signaling pathways.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ High Temperature Silicone Gaskets .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
History
The name originates from the
Greek word for a district in
Thessaly called
Magnesia. It is related to
magnetite and
manganese, which also originated from this area, and required differentiation as separate substances. See
manganese for this history.
.^ Natural Occurrence Titanium is the ninth most abundant element in the earth's crust.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Sources and uses Titanium, the ninth most abundant element in the earth's crust, is widely distributed.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[2] .^ Other titanium minerals are known which are locally abundant in some deposits, but have not been used commercially.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
In 1618, a farmer at Epsom in England attempted to give his cows water from a well. They refused to drink because of the water's bitter taste. However the farmer noticed that the water seemed to heal scratches and rashes. The fame of
Epsom salts spread. Eventually they were recognized to be hydrated magnesium sulfate, MgSO
4.
The metal itself was first produced in England by Sir
Humphry Davy in 1808 using electrolysis of a mixture of magnesia and
mercury oxide.
Antoine Bussy prepared it in coherent form in 1831. Davy's first suggestion for a name was magnium, but the name magnesium is now used.
Applications
As metal
.^ Metallic titanium, titanium dioxide, and titanium tetrachloride are the compounds most widely used in industry.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Exposure to titanium and its compounds occurs not only in the production of metallic titanium, but also in processes in which it is used.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The principal method for the commercial production of titanium sponge metal is the Kroll process, which involves the reduction of titanium tetrachloride with magnesium metal in an inert atmosphere.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Occupational exposure to titanium mainly occurs in the mining and production of the metal, and in the production and processing of titanium dioxide and carbide.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[10]
.^ A component of certain plants, including cayenne and red pepper, used topically for peripheral nerve pain.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ High concentrations of titanium in food, especially cheese, can arise from the use of titanium dioxide as a whitener in the manufacture of mozzarella cheese (Kosikowski & Brown, 1969; Leone, 1973).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ For example, trace metals collected on filter paper by a high volume air sampler for 25 h were analysed by Dittrich & Cothern (1971) using the XRF technique.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Specialty Magnesium Alloys .- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
In 1957, a
Corvette SS, designed for racing, was constructed with magnesium body panels. An earlier
Mercedes-Benz race car model, the
Mercedes-Benz 300 SLR, had a body made from
Elektron, a magnesium alloy; these cars ran (with successes) at
Le Mans, the
Mille Miglia, and other world-class race events in 1955 (though one was involved in the
single worst accident in auto racing history, in terms of human casualties, at the Le Mans race.) Porsche's all-out quest to decrease the weight of their race cars led to the use of magnesium frames in the famous 917/053 which won Le Mans in 1971, and still holds the absolute distance record. The 917/30 Can-Am car also featured a magnesium frame, helping it to make the most of its prodigious 1100–1500 hp.
.^ We design, engineer & assemble close tolerance custom rubber molded OEM components for many uses, including respiratory/safety appliances & power distribution products.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
.^ Engineering Magnesium Alloys .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
There is renewed interest in magnesium engine blocks, as featured in the 2006
BMW 325i and 330i models.
.^ Elements in titanium alloys fall into two categories, i.e., those that strengthen and stabilize the alpha or room temperature modification, and those that strengthen the beta or high temperature modification.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Other alloys used widely include those containing either, 8% aluminium, 1% each of molybdenum, and vanadium, or 5% aluminium and 2.5% tin.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Metallic titanium is mainly used in the aircraft industry and in the production of high-strength, corrosion-resistant alloys.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Our standard materials include Neoprene, EPDM, Bunga-N, Natural Rubber & high or low temperature silicone.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ Elements in titanium alloys fall into two categories, i.e., those that strengthen and stabilize the alpha or room temperature modification, and those that strengthen the beta or high temperature modification.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Custom High Temperature Alloys .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
.^ Used as bulk metal and in lightweight alloys with magnesium for engines, also as a sacrificial electrode to protect other metals.- Mineral Species sorted by the element Mg Magnesium 16 January 2010 3:03 UTC webmineral.com [Source type: Reference]
The general strategy for such alloys is to form
intermetallic precipitates at the
grain boundaries, for example by adding
mischmetal or
calcium.
[11] New alloy development and lower costs, which are becoming competitive to aluminium, will further the number of automotive applications.
[citation needed]
Products made of magnesium: firestarter and shavings, sharpener, magnesium ribbon
The second application field of magnesium is electronic devices. Because of low weight, good mechanical and electrical properties, magnesium is widely used for manufacturing of mobile phones, laptop computers, cameras, and other electronic components.
.^ A world renowned metal service center fully stocked with aluminum, stainless steel, titanium, copper, brass, tungsten, nickel alloys, magnesium, aircraft quality steel, waspaloy, cobalt, etc.
^ Aerospace Metal Alloys .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
Because of perceived hazards with magnesium parts in the event of fire, the application of magnesium in the commercial aerospace industry was generally restricted to engine related components. Currently the use of magnesium alloys in aerospace is increasing, mostly driven by the increasing importance of fuel economy and the need to reduce weight.
. The development and testing of new magnesium alloys continues, notably Elektron 21 which has successfully undergone extensive aerospace testing for suitability in engine, internal and airframe components.
^ Engineering Magnesium Alloys .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
The European Community runs three R&D magnesium projects in the Aerospace priority of Six Framework Program.
Niche uses of the metal
Magnesium being cheaply available and relatively nontoxic has variety of uses:
- Magnesium is flammable, burning at a temperature of approximately 3,100 °C (3,370 K; 5,610 °F) [12], and the autoignition temperature of magnesium ribbon is approximately 630 °C (903 K; 1,166 °F) in air.[13] It produces intense, bright, white light when it burns. .^ A type of external radiation therapy that uses a special machine to make invisible, high-energy particles (protons or helium ions) that kill cancer cells.
- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ An x-ray is a type of high-energy radiation that can go through the body and onto film, making pictures of areas inside the chest, which can be used to diagnose disease.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Other alloys used widely include those containing either, 8% aluminium, 1% each of molybdenum, and vanadium, or 5% aluminium and 2.5% tin.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Catechol is used as an astringent, an antiseptic, and in photography, electroplating, and making other chemicals.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Magnesium firestarter (in left hand), used with a
pocket knife and flint to create sparks which ignite the shavings
- To photoengrave plates in the printing industry.
- In the form of turnings or ribbons, to prepare Grignard reagents, which are useful in organic synthesis.
- As an additive agent in conventional propellants and the production of nodular graphite in cast iron.
- As a reducing agent for the production of uranium and other metals from their salts.
- As a sacrificial (galvanic) anode to protect underground tanks, pipelines, buried structures, and water heaters.
As magnesium compounds
Magnesium ion is necessary for all life (see
magnesium in biology), so magnesium salts are an additive for foods, fertilizers (Mg is a component of chlorophyll), and culture media.
Magnesium compounds, primarily
magnesium oxide (MgO), are used mainly as
refractory material in
furnace linings for producing
iron,
steel, nonferrous metals,
glass and
cement.
.^ Used as bulk metal and in lightweight alloys with magnesium for engines, also as a sacrificial electrode to protect other metals.- Mineral Species sorted by the element Mg Magnesium 16 January 2010 3:03 UTC webmineral.com [Source type: Reference]
.^ A procedure that uses gold salts (a salt form of the metal element gold) to treat diseases, such as rheumatoid arthritis.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Niche and illustrative uses of magnesium compounds
- Magnesium hydroxide is used in milk of magnesia, its chloride, oxide, gluconate, malate, orotate and citrate used as oral magnesium supplements, and its sulfate (Epsom salts) for various purposes in medicine, and elsewhere (see the article for more). Oral magnesium supplements have been claimed to be therapeutic for some individuals who suffer from Restless Leg Syndrome (RLS).[citation needed]
- Magnesium borate, magnesium salicylate and magnesium sulfate are used as antiseptics.
- Magnesium bromide is used as a mild sedative (this action is due to the bromide, not the magnesium).
- Dead-burned magnesite is used for refractory purposes such as brick and liners in furnaces and converters.
- Magnesium carbonate (MgCO3) powder is also used by athletes, such as gymnasts and weightlifters, to improve the grip on objects – the apparatus or lifting bar.
- Magnesium stearate is a slightly flammable white powder with lubricating properties. In pharmaceutical technology it is used in the manufacturing of tablets, to prevent the tablets from sticking to the equipment during the tablet compression process (i.e., when the tablet's substance is pressed into tablet form).
- Magnesium sulfite is used in the manufacture of paper (sulfite process).
- Magnesium phosphate is used to fireproof wood for construction.
- Magnesium hexafluorosilicate is used in mothproofing of textiles.
Biological role
.^ All living things are made up of one or more cells.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ The sum of all chemical changes that take place in a cell through which energy and basic components are provided for essential processes, including the synthesis of new molecules and the breakdown and removal of others.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ CI-958 binds to DNA and stops cells, including cancer cells, from repairing damage to DNA and from making more DNA, RNA, and protein.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
ATP exists in cells normally as a chelate of ATP and a magnesium ion.
Food sources of magnesium
Magnesium is a vital component of a healthy human diet.
.^ It is used as a drug to increase calcium levels in the body in order to treat skeletal and tissue-related calcium deficiencies caused by kidney or thyroid disorders.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ It is linked to ATSM, which is taken up by tissues that have low levels of oxygen, such as some tumor tissues.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
[15]
Adult human bodies contain about 24 grams of magnesium, with 60% in the skeleton, 39% intracellular (20% in skeletal muscle), and 1% extracellular.
.^ Some tumors have high levels of cyclooxygenase-2 and blocking its activity may reduce tumor growth.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ This type of radiation may cause less damage to nearby healthy tissue than radiation therapy with high-energy x-rays.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ An inherited disorder in which there is a lower-than-normal number of neutrophils (a type of white blood cell that is important in fighting infections).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Intracellular magnesium is correlated with intracellular potassium. Magnesium is absorbed in the gastrointestinal tract, with more absorbed when status is lower. In humans, magnesium appears to facilitate calcium absorption. Low and high protein intake inhibit magnesium absorption, and other factors such as
phosphate,
phytate, and
fat affect absorption. Absorbed dietary magnesium is largely excreted through the urine, although most magnesium "administered orally" is excreted through the feces.
[16] .^ In working environments, the air concentration may reach several mg/m 3 .- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Higher urinary excretion levels of 0.41 and 0.46 mg/litre have been reported in two adults (Tipton et al., 1966).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ In most studies on concentrations of titanium in blood, levels reported have been about 0.02-0.07 mg/litre.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[17] In these tests, magnesium is injected intravenously; a retention of 20% or more indicates deficiency.
[18] Other nutrient deficiencies are identified through
biomarkers, but none are established for magnesium.
[19]
.^ A substance found in the leaves and beans of the coffee tree, in tea, yerba mate, guarana berries, and in small amounts in cocoa.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ A substance found in yellow and orange fruits and vegetables and in dark green, leafy vegetables.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Outside occupational settings, the amount of titanium absorbed via the lungs is of little significance in relation to the intake from food, and the intake by inhalation is less than 1% of the total intake.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ A person with celiac disease may become malnourished no matter how much food is consumed.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
[16]
Numerous magnesium
dietary supplements are available.
Magnesium oxide, one of the most common because it has high magnesium content per weight, has been reported to be the least bioavailable.
[20][21] .^ Titanium tetrachloride is a liquid, which is stable in dry air, but decomposes in cold water to form titanium oxide and hydrochloric acid.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[22]
.^ The kidneys filter carbamide out of the blood and into the urine.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
[15] .^ The dose administered was not reported but the compound used was characterized as "pure".- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
[23] Alcoholism can produce a magnesium deficiency which is easily reversed by oral or parenteral administration, depending on the degree of deficiency.
[24]
Precautions
.^ Symptoms include body aches, pain in the lower back and genital area, a burning feeling during urination, and problems with emptying the bladder all the way.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Schlesser was killed.
.^ It is extremely resistant to corrosion and, in the form of a powder or dust, is highly flammable and explosive.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Titanium powders are highly pyrophoric and molten titanium burns in air.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Uses of Titanium Titanium, used as a construction material, is usually in the form of alloys, most of which have higher strength than pure titanium and enhanced corrosion resistance.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Burns in air and reacts with hot water.- Mineral Species sorted by the element Mg Magnesium 16 January 2010 3:03 UTC webmineral.com [Source type: Reference]
.^ It is estimated that over half of all non-permanent white or light-coloured surface coatings include a titanium dioxide level of 0.1-0.3 kg/litre.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The third largest and apparently fastest growing application of titanium dioxide is in the plastics industry, because of its resistance to degradation by ultraviolet light, high refractive index, whiteness, and chemical inertness (Stamper, 1970).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ A thin layer of tissue that is part of the middle layer of the wall of the eye, between the sclera (white outer layer of the eye) and the retina (the inner layer of nerve tissue at the back of the eye).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
[25]
- Mg (s) + 2 H2O (l) → Mg(OH)2 (s) + H2 (g)
As a result, water cannot be used to extinguish magnesium fires; the hydrogen gas produced will only intensify the fire. Dry sand is an effective smothering agent but is usable only on relatively level and flat surfaces.
- 2 Mg (s) + CO2 → 2 MgO (s) + C (s)
.^ To destroy tissue using a hot or cold instrument, an electrical current, or a chemical that burns or dissolves the tissue.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
References
- ^ Bernath, P. F., Black, J. H., & Brault, J. W. (1985). "The spectrum of magnesium hydride". Astrophysical Journal 298: 375. http://bernath.uwaterloo.ca/media/24.pdf.
- ^ a b (PDF) Abundance and form of the most abundant elements in Earth’s continental crust. http://www.gly.uga.edu/railsback/Fundamentals/ElementalAbundanceTableP.pdf. Retrieved 2008-02-15.
- ^ Housecroft, Catherine E; Sharpe, Alan G. (2007). "Group 2 metals". Inorganic Chemistry (3 ed.). Harlow, England: Pearson. ISBN 9780131755536.
- ^ Ash, Russell (2005). The Top 10 of Everything 2006: The Ultimate Book of Lists. Dk Pub. ISBN 0756613213. http://plymouthlibrary.org/faqelements.htm. .
- ^ Anthoni, J Floor (2006). "The chemical composition of seawater". http://www.seafriends.org.nz/oceano/seawater.htm#composition.
- ^ "Magnesium in health". http://www.mg12.info.
- ^ Dreizin, Edward L.; Berman, Charles H. and Vicenzi, Edward P.. "Condensed-phase modifications in magnesium particle combustion in air". Scripta Materialia 122. doi:10.1016/S0010-2180(00)00101-2.
- ^ DOE Handbook - Primer on Spontaneous Heating and Pyrophoricity. U.S. Department of Energy. December 1994. p. 20. DOE-HDBK-1081-94. http://www.hss.doe.gov/nuclearsafety/ns/techstds/standard/hdbk1081/hbk1081c.html.
- ^ Vardi, Nathan (February 22, 2007). "Man With Many Enemies". Forbes.com. http://www.forbes.com/forbes/2002/0722/044_print.html. Retrieved 2006-06-26.
- ^ Ketil Amundsen, Terje Kr. Aune, Per Bakke, Hans R. Eklund, Johanna Ö. Haagensen, Carlos Nicolas, Christian Rosenkilde, Sia Van den Bremt, Oddmund Wallevik “Magnesium” in Ullmann’s Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH. doi: 10.1002/14356007.a15_559
- ^ Luo, Alan A. and Powell, Bob R. (2001) (PDF). Tensile and Compressive Creep of Magnesium-Aluminum-Calcium Based Alloys. Materials & Processes Laboratory, General Motors Research & Development Center. http://doc.tms.org/ezmerchant/prodtms.nsf/productlookupitemid/01-481x-137/%24FILE/01-481X-137F.pdf. Retrieved 2007-08-21.
- ^ Dreizin, Edward L.; Berman, Charles H. and Vicenzi, Edward P.. "Condensed-phase modifications in magnesium particle combustion in air". Scripta Materialia 122. doi:10.1016/S0010-2180(00)00101-2.
- ^ Ravi Kumar, N. V. et al.. Effect of alloying elements on the ignition resistance of magnesium alloys. doi:10.1016/S1359-6462(03)00263-X.
- ^ "Lack Energy? Maybe It's Your Magnesium Level". United States Department of Agriculture. http://www.ars.usda.gov/is/AR/archive/may04/energy0504.htm?pf=1. Retrieved 2008-09-18. Last paragraph
- ^ a b University of Maryland Medical Center. Magnesium
- ^ a b Wester PO (May 1987). "Magnesium". Am. J. Clin. Nutr. 45 (5 Suppl): 1305–12. PMID 3578120. http://www.ajcn.org/cgi/pmidlookup?view=long&pmid=3578120.
- ^ Arnaud MJ (2008). "Update on the assessment of magnesium status". Br. J. Nutr. 99 Suppl 3: S24–36. doi:10.1017/S000711450800682X. PMID 18598586.
- ^ Rob PM, Dick K, Bley N, et al. (October 1999). "Can one really measure magnesium deficiency using the short-term magnesium loading test?". J. Intern. Med. 246 (4): 373–8. doi:10.1046/j.1365-2796.1999.00580.x. PMID 10583708. http://www.blackwell-synergy.com/openurl?genre=article&sid=nlm:pubmed&issn=0954-6820&date=1999&volume=246&issue=4&spage=373.
- ^ Franz KB (2004). "A functional biological marker is needed for diagnosing magnesium deficiency". J Am Coll Nutr 23 (6): 738S–41S. PMID 15637224.
- ^ Firoz M, Graber M (December 2001). "Bioavailability of US commercial magnesium preparations". Magnes Res 14 (4): 257–62. PMID 11794633.
- ^ Lindberg JS, Zobitz MM, Poindexter JR, Pak CY (1990). "Magnesium bioavailability from magnesium citrate and magnesium oxide". J Am Coll Nutr 9 (1): 48–55. PMID 2407766.
- ^ Walker AF, Marakis G, Christie S, Byng M (2003). "Mg citrate found more bioavailable than other Mg preparations in a randomised, double-blind study" (free text on-line). Magnes Res 16 (3): 183–91. PMID 14596323. http://www.john-libbey-eurotext.fr/medline.md?issn=0953-1424&vol=16&iss=3&page=183.
- ^ Kontani M, Hara A, Ohta S, Ikeda T (2005). "Hypermagnesemia induced by massive cathartic ingestion in an elderly woman without pre-existing renal dysfunction". Intern. Med. 44 (5): 448–52. doi:10.2169/internalmedicine.44.448. PMID 15942092.
- ^ Giannini, A. J. (1997). Drugs of Abuse (Second ed.). Los Angeles: Physicians Management Information Co..
- ^ "Science Safety: Chapter 8". Government of Manitoba. http://www.edu.gov.mb.ca/k12/docs/support/scisafe/chapter8.html. Retrieved 2007-08-21.
- ^ "Chemistry : Periodic Table : magnesium : chemical reaction data". webelements.com. http://www.webelements.com/webelements/elements/text/Mg/chem.html. Retrieved 2006-06-26.
- ^ "Demo Lab: Reaction Of Magnesium Metal With Carbon Dioxide". http://www.ilpi.com/genchem/demo/co2mg/. Retrieved 2006-06-26.
External links