The Full Wiki

Reducing agent: Wikis

Advertisements
  

Note: Many of our articles have direct quotes from sources you can cite, within the Wikipedia article! This article doesn't yet, but we're working on it! See more info or our list of citable articles.

Encyclopedia

From Wikipedia, the free encyclopedia

A reducing agent (also called a reductant or reducer) is the element or compound in a redox (reduction-oxidation) reaction (see electrochemistry) that reduces another species. In doing so, it becomes oxidized, and is therefore the electron donor in the redox. For example consider the following reaction:

2 [Fe(CN)6]4− + Cl2 → 2 [Fe(CN)6]3− + 2 Cl

The reducing agent in this reaction is ferrocyanide ([Fe(CN)6]4−): it donates an electron, converting to ferricyanide ([Fe(CN)6]3−), simultaneous with the reduction of chlorine to chloride.

In organic chemistry, reduction more specifically refers to the addition of hydrogen to a molecule, though the aforementioned definition still applies. For example, benzene is reduced to cyclohexane in the presence of a platinum catalyst:

C6H6 + 3 H2 → C6H12

In organic chemistry, good reducing agents are reagents that deliver H2.

Contents

Characteristics of reducing agents

Strong reducing agents easily lose (or donate) electrons. An atom with a relatively large atomic radius tends to be a better reductant. In such species, the distance from the nucleus to the valence electrons is so long that these electrons are not strongly attracted. These elements tend to be strong reducing agents. Good reducing agents tend to consist of atoms with a low electronegativity, the ability of an atom or molecule to attract bonding electrons, and species with relatively small ionization energies serve as good reducing agents too. "The measure of a material to oxidize or lose electrons is known as its oxidation potential".[1] The table below shows a few reduction potentials that could easily be changed to oxidation potential by simply changing the sign. Reducing agents can be ranked by increasing strength by ranking their oxidation potentials. The reducing agent is stronger when it has a more positive oxidation potential and weaker when it has a negative oxidation potential. The following table provides the reduction potentials of the indicated reducing agent at 25° C.

Oxidizing Agent Reducing Agent Reduction Potential (v)
Li+ + e- = Li -3.04
Na+ + e- = Na -2.71
Mg2+ + 2e- = Mg -2.38
Al3+ + 3e- = Al -1.66
2H2O(l) + 2e- = H2(g) + 2OH - -0.83
Cr3+ + 3e- = Cr -0.74
Fe2+ + 2e- = Fe -0.41
2H+ + e- = H2 0.00
Sn4+ + 2e- = Sn2+ +0.15
Cu2+ + e- = Cu+ +0.16
Ag+ + e- = Ag +0.80
Br2 + 2e- = 2Br- +1.07
Cl2 + 2e- = 2Cl- +1.36
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O +1.49

To tell which is the strongest reducing agent, change the sign of its respective reduction potential to make it oxidation potential. The bigger the number, the stronger the reducing agent.

For example, if you list Cu, Cl-, Na and Cr in order, you get their reduction potentials. Change the sign to make them oxidation potentials, and list them from greatest to least. The order is Na, Cr, Cu and Cl-, Na being the strongest reducing agent and Cl- the weakest one.

A few good common reducing agents include active metals such as potassium, calcium, barium, sodium and magnesium and also, compounds that contain the H- ion, those being NaH,LiH[2], LiAlH4 and CaH2.

Also, some elements and compounds can be both reducing or oxidizing agents. Hydrogen gas is a reducing agent when it reacts with non-metals and an oxidizing agent when it reacts with metals.

2Li(s) + H2(g) -->2LiH(s) hydrogen acts as an oxidizing agent because it accepts an electron donation from lithium, which causes Li to be oxidized.

Half Reactions 2Li(s)0 -->2Li(s)+1 + 2e-::::: H20(g) + 2e- --> 2H-1(g)

H2(g) + F2(g) --> 2HF(g) hydrogen acts as a reducing agent because it donates its electrons to fluorine, which allows fluorine to be reduced.

Half Reactions H20(g) --> 2H+1(g) + 2e-::::: F20(g) + 2e- --> 2F-1(g)

Importance of reducing and oxidizing agents

Reducing agents and oxidizing agents are the ones responsible for corrosion, which is the “degradation of metals as a result of electrochemical activity”.[1] Corrosion requires an anode and cathode to take place. The anode is an element that loses electrons (reducing agent), thus oxidation always occurs in the anode, and the cathode is an element that gains electrons (oxidizing agent), thus reduction always occurs in the cathode. Corrosion occurs whenever there’s a difference in oxidation potential. When this is present, the anode metal begins deteriorating, given there is an electrical connection and the presence of an electrolyte.

Example of redox reaction

The formation of iron(III) oxide;

4Fe + 3O2 → 2Fe2O3

In the above equation, the Iron (Fe) has an oxidation number of 0 before and 3+ after the reaction. For oxygen (O) the oxidation number began as 0 and decreased to 2−. These changes can be viewed as two "half-reactions" that occur concurrently:

  1. Oxidation Half Reaction: Fe0 → Fe3+ + 3e
  2. Reduction Half Reaction: O2 + 4e → 2 O2−

Iron (Fe) has been oxidized because the oxidation number increased and is the reducing agent because it gave electrons to the oxygen (O2). Oxygen (O2) has been reduced because the oxidation number has decreased and is the oxidizing agent because it took electrons from iron (Fe)

Common reducing agents

Common reducing agents and their products

Agent Product
H2 Hydrogen H+, H2O
metals metal ions
C CO2 carbon dioxide
hydrocarbons CO2 carbon dioxide, H2O

See also

References

  1. ^ a b http://www.siliconfareast.com/ox_potential.htm
  2. ^ Aufray M, Menuel S, Fort Y, Eschbach J, Rouxel D, Vincent B (2009). "New Synthesis of Nanosized Niobium Oxides and Lithium Niobate Particles and Their Characterization by XPS Analysis". JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 9 (8): 4780–4789. doi:10.1166/jnn.2009.1087. 
  • "Chemical Principles: The Quest for Insight", Third Edition. Peter Atkins and Loretta Jones pg. F76

External links

Advertisements

Simple English


Reducing agent refers to a chemical that gives away electrons to another chemical compound, the oxidizing agent. For example, zinc is a reducing agent. When it reacts with an oxidizing agent, it gives up two electrons, changing its oxidation state from 0 to +2 (all elements have an oxidation state of 0).

Examples

Other pages


Advertisements






Got something to say? Make a comment.
Your name
Your email address
Message