From Wikipedia, the free encyclopedia
|
|
| Appearance |
crystalline, reflective with bluish-tinged faces

Broken silicon ingot |
| General properties |
| Name, symbol, number |
silicon, Si, 14 |
| Element category |
metalloid |
| Group, period, block |
14, 3, p |
| Standard atomic weight |
28.0855(3) g·mol−1 |
| Electron configuration |
[Ne] 3s2 3p2 |
| Electrons per shell |
2, 8, 4 (Image) |
| Physical properties |
| Phase |
solid |
| Density (near r.t.) |
2.3290 g·cm−3 |
| Liquid density at m.p. |
2.57 g·cm−3 |
| Melting point |
1687 K, 1414 °C, 2577 °F |
| Boiling point |
3538 K, 3265 °C, 5909 °F |
| Heat of fusion |
50.21 kJ·mol−1 |
| Heat of vaporization |
359 kJ·mol−1 |
| Specific heat capacity |
(25 °C) 19.789 J·mol−1·K−1 |
| Vapor pressure |
| P/Pa |
1 |
10 |
100 |
1 k |
10 k |
100 k |
| at T/K |
1908 |
2102 |
2339 |
2636 |
3021 |
3537 |
|
| Atomic properties |
| Oxidation states |
4, 3 , 2 , 1[1] -1, -2, -3, -4
(amphoteric oxide) |
| Electronegativity |
1.90 (Pauling scale) |
Ionization energies
(more) |
1st: 786.5 kJ·mol−1 |
| 2nd: 1577.1 kJ·mol−1 |
| 3rd: 3231.6 kJ·mol−1 |
| Atomic radius |
111 pm |
| Covalent radius |
111 pm |
| Van der Waals radius |
210 pm |
| Miscellanea |
| Crystal structure |
diamond cubic |
| Magnetic ordering |
diamagnetic[2] |
| Electrical resistivity |
(20 °C) 103 [3]Ω·m |
| Thermal conductivity |
(300 K) 149 W·m−1·K−1 |
| Thermal expansion |
(25 °C) 2.6 µm·m−1·K−1 |
| Speed of sound (thin rod) |
(20 °C) 8433 m/s |
| Young's modulus |
185[3] GPa |
| Shear modulus |
52[3] GPa |
| Bulk modulus |
100 GPa |
| Poisson ratio |
0.28[3] |
| Mohs hardness |
7 |
| CAS registry number |
7440-21-3 |
| Band gap energy at 300 K |
1.12 eV |
| Most stable isotopes |
| Main article: Isotopes of silicon |
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This box: view • talk • edit
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Silicon (pronounced
/ˈsɪlɨkən/ SIL-ə-kən or
/ˈsɪlɨkɒn/ SIL-ə-kon,
Latin:
silicium) is the most common
metalloid.
.^ To the east of Brae, the Miller reservoir exists with a carbon dioxide concentration slightly less than than of Brae.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ What Gold forgets is that since there are no stable elements of (atomic) mass numbers 5 and 8, construction of the elements by this route is not tenable.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ In particular, therefore, the origin of nitrogen (atomic number 14) in the German reservoirs is unexplained.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
.^ Moreover, in these studies concomitant exposure to other elements such as silica seems to offer a more likely explanation of the fibrosis than the titanium dioxide itself.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ The inflammability of coal dust varies with different coals, but none can be said to be entirely free from risk.
^ Weak fibrosis, found in association with exposure to various titanium dusts, is likely to be due to concomitant exposure to other components rather than to the titanium dioxide.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ The different elements making up the drawing arrangements of a colliery are - (r) the cage, (2) the shaft or pit fittings, (3) the drawing-rope, (4) the engine and (5) the surface arrangements.
[4]
Silicon has many industrial uses. It is the principal component of most
semiconductor devices, most importantly
integrated circuits or
microchips.
.^ He uses a coarser granulation of sugar for his fruit jellies because it does not melt as easily.
^ Because it dissolves so instantly, it is particularly useful for sprinkling on berries to be consumed immediately because the berries keep all their juice instead of forming a syrup.
^ Mobility of aluminum in the Hubbard Brook soils is significantly lower than in the Dutch soils, because of higher soil-solution pH values.
.^ Aluminum compounds and materials also have a wide variety of uses, including production of glass, ceramics, rubber, wood preservatives, pharmaceuticals and waterproofing textiles.
^ In addition, titanium dioxide is used in ceramic capacitors and electromechanical transducers, welding-rod coatings, and in the production of glass fibres.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ A substance made up of elements, such as hydrogen or sodium.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ They all contain carbon, hydrogen, oxygen and nitrogen , forming the carbonaceous or combustible portion, and some quantity of mineral matter, which remains after combustion as a residue or " ash ."
^ The amount of hydrogen is from 42 to 6%, while the oxygen may vary within much wider limits, or from about 3 to 14%.
Silicon is an essential element in biology, although only tiny traces of it appear to be required by animals.
[5] .^ Thus, the protective role of superoxide dismutase is particularly important.
^ But when there is much small duff, with intermixed shale, more elaborate sizing and washing plant becomes necessary.
^ The ionized forms of calcium, such as citrate and citrate malate, tend to be more soluble and have a greater absorption rate, especially in people who are deficient in hydrochloric acid.
Notable characteristics
.^ The same chemicals increased the frequency of radiation-induced aberrations during two periods of mitotic cycle, namely, in the end of the G1 stage and in the G2 stage.
^ The facts suggested that the six carbon atoms formed a chain, and that a hydroxy group was attached to five of them, for it is very rare for two hydroxy groups to be attached to the same carbon atom .
.^ Separate from acids, alkalies, halogenated compounds, oxidizers, combustible materials.
^ In some reservoirs, compaction of the rock grains has not been fully achieved, even though such reservoirs are many miles below the surface.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ Bilateral aortic neurotomy or unilateral carotid neurotomy did not affect significantly the minimal sensitivity to the drug, although maximal reactivity was reduced in some cats.
.^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
.^ A protein that is made by many different types of cells and is involved in processes that take place both inside and outside of the cell.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ The different lymphoma cells may form in the same tissue or organ or in many different tissues or organs.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Negative Temperature Coefficient Thermistors .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
.^ BRAHNOVA, I.T. & SKURKO, G.A. (1973) [Hygienic assessment of the effect produced on the body by transition metal hydrides with due regard for their electronic and crystal structure.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Known as "strong" sugar because it resists color changes and inversion at high temperatures due to the absence of impurities, this type of sugar is ideal for confections and cordials and also for preparing caramel because impurities can cause crystallization.
^ The multiple-effect evaporator, originally invented and constructed by Norberto Rilleux in New Orleans in 1840, has under gone many changes in design and construction since Effect that year.
In its
crystalline form, pure silicon has a gray color and a metallic luster. It is similar to glass in that it is rather strong, very brittle, and prone to chipping.
.^ Although I might not particularly like the taste of it, it is by far the easiest and cheapest way to disinfect water and make it drinkable, and it probably helped to save more lives than any other single chemical substance on Earth.- Alltop - Top Water News 28 January 2010 1:01 UTC water.alltop.com [Source type: General]
^ [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed.
^ The top of it was more than four feet down, one end higher than the other.- Fiction Liberation Front--Gold 27 January 2010 23:57 UTC www.lewisshiner.com [Source type: Original source]
History
Silicon was first identified by
Antoine Lavoisier in 1787 (as a component of the
Latin silex,
silicis for
flint, flints), and was later mistaken by
Humphry Davy in 1800 for a compound. In 1811
Gay-Lussac and
Thénard probably prepared impure
amorphous silicon through the heating of
potassium with
silicon tetrafluoride.
.^ Another method of enabling more work to be done in a given time in a given cistern is the use of a bag twice the ordinary length, open at both ends.
^ Xylose was discovered by Koch in 1886; its enantiomorph is prepared from d-gulose by Wohl's method.
^ The use of preparing rolls with corrugations, to crush and equalize the feed of canes to the mill, or to the first of a series of mills, has become general.
Berzelius also purified the product by repeatedly washing it.
[6][7]
Occurrence
.^ Natural Occurrence Titanium is the ninth most abundant element in the earth's crust.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Sources and uses Titanium, the ninth most abundant element in the earth's crust, is widely distributed.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ The cave has only one entrance, unlike all other caves found in Pokémon Gold, Silver , and Crystal , but goes deep into the mountain.- Mt. Silver - Bulbapedia, the community-driven Pokémon encyclopedia 8 January 2010 3:31 UTC bulbapedia.bulbagarden.net [Source type: Academic]
.^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
^ A slow-growing type of tumor usually found in the gastrointestinal system (most often in the appendix), and sometimes in the lungs or other sites.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ A rare form of lymphoma (cancer that begins in cells of the immune system) in which different types of lymphoma cells occur at the same time.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
Amethyst, agate,
quartz, rock crystal,
chalcedony,
flint,
jasper, and
opal are some of the forms in which silicon dioxide appears.
.^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
.^ They may occur as one large stone or as many small ones, and vary from the size of a golf ball to a grain of sand.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ PEER REVIEWED** Interactions: Groups of 120 Atlantic salmon fry (Salmo salar, 1 g mass) were kept in through-flow tanks of water (pH 5) containing various concn of aluminum and silicic acid.
^ For example, one group may have been exposed to a particular substance that the other was not.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Back Would this have included limestone, sandstone and clay—the latter being another complex mineral made by God?- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ They may occur as one large stone or as many small ones, and vary from the size of a golf ball to a grain of sand.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ The problem is to explain how oil from the supposed source rock beneath the Bridport Sands in the south moved three miles to the north to enter Bridport and Sherwood sandstones.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
Feldspar,
pyroxene,
amphibole, and
mica are a few of the many common silicate mineral groups.
Silicon is a principal component of many
meteorites, and also is a component of
obsidian and
tektites, which are natural forms of glass.
Isotopes
.^ PEER REVIEWED** Absorption of inhaled aluminum compounds has not been studied in detail; one reason for this is probably the fact that no stable radioactive isotope of aluminum is available.
^ What Gold forgets is that since there are no stable elements of (atomic) mass numbers 5 and 8, construction of the elements by this route is not tenable.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ NATURALLY OCCURRING ISOTOPE: (27) ALUMINUM ; IN ADDN, 6 RADIOACTIVE ISOTOPES & 1 ISOMER ARE KNOWN [The Merck Index.
.^ The 32 separate size distributions were determined by proton-induced X-ray emission spectroscopy.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Twenty-four white women, aged 14 to 28 years, with hypothalamic amenorrhea or oligomenorrhea were prospectively enrolled for a 12-month intervention period.
^ In the two reports available, the biological half-life for titanium in man has been calculated to be about 320 days and 640 days, respectively.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
Production
.^ The Fisher-Tropsch process is an industrial process used to convert a material with a high carbon content (such as coal) into petroleum liquids in the presence of catalysts such as ferric oxides and/or silicates.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ PEER REVIEWED** Methods of Manufacturing: Sodium cyanide can be prepared by heating sodium amide with carbon, by melting sodium chloride and calcium cyanamide together in an electric furnace ...
^ Electric Arc Furnaces .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
At temperatures over 1,900
°C (3,450
°F), the carbon reduces the silica to silicon according to the
chemical equations:
- SiO2 + C → Si + CO2
- SiO2 + 2 C → Si + 2 CO
Liquid silicon collects in the bottom of the furnace, and is then drained and cooled. The silicon produced via this process is called
metallurgical grade silicon and is at least 98% pure.
.^ Titanium does not easily atomize and has a tendency to form refractory oxides, which may influence the use of atomic absorption assays.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
However, provided the concentration of SiO
2 is kept high, the silicon carbide can be eliminated:
- 2 SiC + SiO2 → 3 Si + 2 CO
In September 2008,
metallurgical grade silicon cost about
USD 1.45 per pound ($3.20/kg),
[9] up from $0.77 per pound ($1.70/kg) in 2005.
[10]
Pure silicon (>99.9%) can be extracted directly from solid silica or other silicon compounds by molten salt electrolysis.
[11][12][13][14] .^ American Water has set a goal to lower its greenhouse gas emissions per volume of water produced by 16 percent by the year 2017.- Alltop - Top Water News 28 January 2010 1:01 UTC water.alltop.com [Source type: General]
^ American Water to lower its greenhouse gas emissions per volume of water produced by 16 percent .- Alltop - Top Water News 28 January 2010 1:01 UTC water.alltop.com [Source type: General]
Crystallization
Silicon crystallizes in the diamond cubic crystal structure
.^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
^ PEER REVIEWED** Color/Form: White cubic crystals [Lide, D.R. (ed.
Silicon, in particular, forms a
face-centered cubic structure with a lattice spacing of 5.430710
Å (0.5430710 nm).
[16]
.^ The principal method for the commercial production of titanium sponge metal is the Kroll process, which involves the reduction of titanium tetrachloride with magnesium metal in an inert atmosphere.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ View Website Chicago, IL 800-782-7776 Request For Quote Accurate Products is capable of producing custom rubber products in a variety of materials.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ The two main methods used for aluminum production are Soderberg and prebake, which encompass a number of processes and job categories.
However, silicon single-crystals grown by the Czochralski method contain impurities since the
crucible which contains the melt dissolves.
.^ The risks of an adverse reaction between calcium citrate and aluminum-containing compounds are especially high for individuals with kidney failure, particularly those on dialysis.
For these applications,
float-zone silicon (FZ-Si) can be used instead. It is worth mentioning though, in contrast with CZ-Si method in which the seed is dipped into the silicon melt and the growing crystal is pulled upward, the thin seed crystal in the FZ-Si method sustains the growing crystal as well as the polysilicon rod from the bottom.
.^ In this method, particles were collected and segregated according to size, using cascade impactors.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Using a food processor it is possible to make a more finely granulated sugar, but the crystals will not be as uniform in size as in commercially produced finer grain sugars.
^ When used in cakes, it results in a fine crumb and lighter texture because, with smaller crystals, more surface area is available to trap air.
.^ Golden castor (fine granulated from the first boiling or crystallization) I use this sugar for all baking except meringues and fondants where I prefer a pristine white color and sugar syrups where more purity (refinement) helps to avoid crystallization.
^ This is partially because an inferior grade of industrial molasses is often used and the molasses merely coats the outside of the sugar crystal and is no longer part of the crystal itself.
Purification
The use of silicon in
semiconductor devices demands a much greater purity than afforded by metallurgical grade silicon.
.^ The two main methods used for aluminum production are Soderberg and prebake, which encompass a number of processes and job categories.
Physical methods
Early silicon purification techniques were based on the fact that if silicon is melted and re-solidified, the last parts of the mass to solidify contain most of the impurities.
.^ Numbers from 1 to 3 may be used to describe how abnormal the cells are and how much of the cervical tissue is involved.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ This is useful when the solution will be used in a way that will involve repeatedly dipping into it, such as for making spun sugar.
^ It is used by many cells in the body to make energy from fatty acids.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
When crushed, the silicon cracked so that the weaker impurity-rich regions were on the outside of the resulting grains of silicon.
.^ Although the color and therefore amount of molasses varies, I find that the resulting product has a flavor ranging from merely more pure to slightly more flavorful.
^ Amber crystal and golden caster sugar are the result of the first crystallization, where there is a higher proportion of sucrose to impurities.
^ The second and optional process in sugar production is refining to remove “impurities.” This refers to anything that is not purely sucrose such as molasses and minerals.
.^ And they are the ones most useful for human life (heating, plastics, petrol, and diesel).- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
^ Natural aluminum minerals, especially bentonite and zeolite, are used in water purification, sugar refining, brewing and paper industries.
^ Nish is known for his layers of flavors, He uses the “tarq” method in which oil and dry spices are heated until smoking.
Then, the heater is slowly moved down the length of the rod, keeping a small length of the rod molten as the silicon cools and re-solidifies behind it.
.^ I love your Mahogany Butter Crunch Toffee, however most times it comes out soft and chewy rather than hard and cruncy?
^ The production of elemental titanium is a comparatively difficult process since titanium in the molten state has a great affinity for oxygen, nitrogen, and moisture in the air, as well as for carbon and most refractory materials.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
This end is then cut off and discarded, and the process repeated if a still higher purity is desired.
Chemical methods
.^ Titanium(IV) compounds are easily hydrolysed into titanium dioxide (Stamper, 1970; ACGIH, 1973; Weast, 1980).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Metallic titanium, titanium dioxide, and titanium tetrachloride are the compounds most widely used in industry.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ For long-term therapy, an intermediate-acting agent such as prednisone in single, early morning doses is most commonly used to minimize suppression of the HPA axis.
^ Titanium tetrachloride is also widely employed as the intermediate raw material for the production of most organic titanium compounds, such as alkyl esters of titanium, alkyl titanates, other titanium esters, and butyl titanate (Feld & Cowe, 1965), which are used as cross-linking agents and catalysts.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Our standard materials include Neoprene, EPDM, Bunga-N, Natural Rubber & high or low temperature silicone.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ High Temperature Silicone Adhesives .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
^ High Temperature Silicone Gaskets .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
At one time,
DuPont produced ultra-pure silicon by reacting silicon tetrachloride with high-purity
zinc vapors at 950 °C, producing silicon:
- SiCl4 + 2 Zn → Si + 2 ZnCl2
However, this technique was plagued with practical problems (such as the
zinc chloride byproduct solidifying and clogging lines) and was eventually abandoned in favor of the Siemens process.
In the Siemens process, high-purity silicon rods are exposed to trichlorosilane at 1150 °C. The trichlorosilane gas decomposes and deposits additional silicon onto the rods, enlarging them:
- 2 HSiCl3 → Si + 2 HCl + SiCl4
Silicon produced from this and similar processes is called
polycrystalline silicon.
.^ No patient on sodium valproate monotherapy had subnormal levels of calcium (less than 2.1 mmol/l).
^ After 10 doses of gentamicin, blood-urea nitrogen values in group 1 averaged 213 +/- 15 (SE) and 25 +/- 3 (P less than 0.001) in group 2.
^ FCaA was 30.8 +/- 3.7% lower than the normal of 42.2 +/- 2.5% (P less than 0.025), and baseline 25-OHD levels were 30.5 +/- 3.4 ng/ml (normal 15 to 50 ng/ml).
In 2006
REC announced construction of a plant based on fluidized bed technology using silane:
[17]
- 3 SiCl4 + Si + 2 H2 → 4 HSiCl3
- 4 HSiCl3 → 3 SiCl4 + SiH4
- SiH4 → Si + 2 H2
Different forms of silicon
Silicon wafer with mirror finish (NASA)
|
|
|
One can notice the color change in silicon nanopowder. This is caused by the quantum effects which occur in particles of nanometric dimensions. See also
Potential well,
Quantum dot, and
Nanoparticle.
Compounds
PDMS – a silicone compound
.^ A series of x-ray pictures of the esophagus taken after a patient drinks a liquid containing barium sulfate (a form of the silver-white metallic element barium).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ A procedure that uses gold salts (a salt form of the metal element gold) to treat diseases, such as rheumatoid arthritis.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
magnesium silicide, Mg
2Si through high melting refractory compounds such as
molybdenum disilicide, MoSi
2.
[18] Silicon carbide, SiC (carborundum) is a hard, high melting solid and a well known abrasive.
Silane, SiH
4, is a
pyrophoric gas with a similar tetrahedral structure to
methane, CH
4. Additionally there is a range of catenated silicon hydrides that form a homologous series of compounds,
SinH2n+2 where
n = 2-8 (analogous to the
alkanes).
[19] These are all readily hydrolyzed and are thermally unstable, particularly the heavier members.
[19] Disilenes contain a silicon-silicon double bond (analogous to the
alkenes) and are generally highly reactive requiring large substituent groups to stabilize them.
[20] A
disilyne with a silicon-silicon triple bond was first isolated in 2004; although as the compound is non-linear, the bonding is dissimilar to that in
alkynes.
[21] Tetrahalides, SiX
4, are formed with all of the halogens.
[18] Silicon tetrachloride, for example, readily reacts with water; unlike its carbon analogue, carbon tetrachloride.
[19] .^ Our standard materials include Neoprene, EPDM, Bunga-N, Natural Rubber & high or low temperature silicone.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ The risks of an adverse reaction between calcium citrate and aluminum-containing compounds are especially high for individuals with kidney failure, particularly those on dialysis.
^ High Temperature Silicone Adhesives .- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
[19] Silicon difluoride condenses to form a polymeric compound,
(SiF2)n.
[19] .^ Blackstrap Molasses is the most concentrated form of molasses produced during the third and final centrifuging of the raw sugar crystals.
^ The most common titanium minerals are ilmenite (TiFeO 3 ), which can contain a maximum concentration of titanium dioxide (TiO 2 ) of 530 g/kg, and rutile, which is 100% titanium dioxide.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ I tried making caramelized sugar and the granulated sugar was forming hard, crystal chunks before it even got to melt.
[18] In quartz each silicon atom is surrounded by four oxygen atoms that bridge to other silicon atoms to form a three dimensional lattice.
[18] .^ Aluminum was transferred to the patients' blood during the dialysis treatments, because of the high metal content in the tap water used to prepare the dialysates.
^ Ordinarily, stearic acid, which chemically combines with aluminum to form aluminum stearate, was used as a lubricant to retard surface oxidation during milling of such flake.
^ The addition of a significant amount of an ingredient, such as nuts, can lower the temperature considerably and this will cause crystallization to occur instantly if no interfering agent was used.
[18]
.^ It is present in the form of titanium(IV) compounds; the rarer oxidation form of titanium(III) is also known in certain iron minerals as are complex titanium(IV) compounds (Vinogradov 1959; Stamper, 1970).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Corticosteroids have many different effects in the body, and are used to treat many different conditions.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
[19] Silicates are also important constituents of concretes.
[18] .^ Our standard materials include Neoprene, EPDM, Bunga-N, Natural Rubber & high or low temperature silicone.- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ Aluminum occurs ubiquitously in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium and fluorine and as complexes with organic matter.
^ High Temperature Silicone Tubing .- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
[19] .^ Soda Lime Borosilicate Glass .- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
^ Soda Lime Float Glass .- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
Silicon sulfide, SiS
2 is a polymeric solid (unlike its carbon analogue the liquid
CS2).
[18] Silicon forms a nitride,
Si3N4 which is a ceramic.
[18] Silatranes, a group of tricyclic compounds containing five-coordinate silicon, may have physiological properties.
[22] .^ Bonded Silicon to Metal .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
^ Silicon Bonded to Metal .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
^ Silicon Bonded to Metal Parts .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
[22] Silicones are large group of polymeric compounds with an (Si-O-Si) backbone. An example is the silicone oil PDMS (polydimethylsiloxane).
[18] These polymers can be crosslinked to produce resins and
elastomers.
[18] Many
organosilicon compounds are known which contain a silicon-carbon single bond.
.^ Even so, many healthcare provider trained in nutritional therapies s have suggested the need for calcium supplementation by some patients using these drugs.
Long chain polymers containing a silicon backbone are known, such as polydimethysilylene
(SiMe2)n.
[23] .^ The products that are available in the United States may not contain the same amount or mixture of ingredients and may not be effective.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Silicon Carbide Products .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Rubber Molding Information and Resources 30 January 2010 3:18 UTC www.rubbermolding.org [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
[23]
Applications
.^ [Bjorksten JA; Comp Therapy 8: 73-6 (1982)]**PEER REVIEWED** Natural Pollution Sources: WIDELY DISTRIBUTED IN EARTH'S CRUST IN COMBINATION WITH OXYGEN, FLUORINE, SILICON AND OTHER CONSTITUENTS. ITS MOST IMPORTANT SOURCES FROM THE INDUSTRIAL POINT OF VIEW ARE BAUXITE, CRYOLITE, ALUMINUM , CORUNDUM AND THE KAOLIN MINERALS. [Browning, E. Toxicity of Industrial Metals.
.^ Abstract: The long-term use of glucocorticoid drugs frequently results in the development of osteoporosis.
^ The long-term use of glucocorticoid drugs frequently results in the development of osteoporosis.
Alloys
.^ There are about 30 commercially available grades of pure titanium and alloys.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Metallic titanium is mainly used in the aircraft industry and in the production of high-strength, corrosion-resistant alloys.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ This is partially because an inferior grade of industrial molasses is often used and the molasses merely coats the outside of the sugar crystal and is no longer part of the crystal itself.
Silicon is an important constituent of
electrical steel, modifying its
resistivity and
ferromagnetic properties.
.^ Iron Alloy Castings .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
^ OTHER ELEMENTS MAY BE ADDED AS ALLOYING COMPONENTS, SUCH AS BERYLIUM, COPPER, MAGNESIUM, MANGANESE, IRON & SILICA IN DURALUMIN. [Clayton, G. D. and F. E. Clayton (eds.
^ Cast Iron Alloys .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
Electronics
.^ The remainder is used in the chemical and electrochemical processing industries, for handling some of the most corrosive processes, and in marine and ordnance applications.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ Cholestyramine-fed rats had a net negative balance for calcium and a lower net positive balance for magnesium, iron, and zinc than the controls.
^ However, the exposure in these studies was not to pure titanium dioxide and a possible explanation for the fibrogenic activity may be concomitant exposure to other elements, such as silica (SiO 2 ).- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
.^ It is also used together with other drugs to treat advanced, metastatic, or recurrent non-small cell lung cancer and is being studied in the treatment of other types of cancer.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ A type of cell that makes neurohormones (chemicals that are made by nerve cells and used to send signals to other cells) and releases them into the blood.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ A type of neurohormone (a chemical that is made by nerve cells and used to send signals to other cells).- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ Continuous Wave Lasers .- Titanium Information and Resources 9 January 2010 0:56 UTC www.titanium.cc [Source type: Reference]
- Aluminum Suppliers Information and Resources 10 February 2010 11:10 UTC www.aluminumsuppliers.net [Source type: Reference]
.^ Leukemia is a cancer that starts in blood-forming tissue such as the bone marrow, and causes large numbers of abnormal blood cells to be produced and enter the blood.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ A slowly progressing cancer that starts in blood-forming tissues such as the bone marrow, and causes large numbers of white blood cells to be produced and enter the blood stream.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ This condition may result from the hydrogen fluoride that evolves from the use of fluorine-bearing materials in the production of metallic aluminum .
Silicones
.^ It is also used in the chemical industry as a lining material, because of its corrosion-resistant properties.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Titanium tetrachloride is the common intermediate in the production of titanium catalysts and is also used for the synthesis of organic titanium compounds.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ A chemical used to disinfect water and as a bleach.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
.^ In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
^ It is also used to treat metastatic breast cancer that has not improved after treatment with certain other anticancer drugs.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ PEER REVIEWED** SRP: The scientific literature for the use of contact lenses in industry is conflicting.
[24]
.^ Titanium dioxide is also used in the production of titanium carbides.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
^ Calcium in the form of antacids, milk products, and supplements should be avoided while using tetracycline.
^ Uses of Titanium Titanium, used as a construction material, is usually in the form of alloys, most of which have higher strength than pure titanium and enhanced corrosion resistance.- Titanium (EHC 24, 1982) 9 January 2010 0:56 UTC www.inchem.org [Source type: Academic]
Glass can be made into a great variety of shapes and with many different physical properties.
.^ It is used by many cells in the body to make energy from fatty acids.- Dictionary of Cancer Terms - National Cancer Institute 10 February 2010 12:52 UTC www.cancer.gov [Source type: Academic]
^ Glass blowers Didymium Safety Glasses may be used to block out this emission to observe the less intense colors from other elements.- Mineral Species sorted by the element Na Sodium 6 January 2010 8:54 UTC webmineral.com [Source type: FILTERED WITH BAYES]
^ Although my ascribing the origin of oil to the direct creation of God is something new, the idea that minerals were already present on the earth (and oil is one of many minerals) as part of the rich diversity in creation has been made before, and therefore strengthens the case I am making.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
[25]
Energy storage
It has been proposed
[26] that, given sufficient solar energy, silicon might be refined for use as a coal replacement
In popular culture
.^ Industrial exposure to high concentrations of aluminum -containing airborne dusts has resulted in a number of cases of occupational pneumoconiosis.
^ What Gold forgets is that since there are no stable elements of (atomic) mass numbers 5 and 8, construction of the elements by this route is not tenable.- The Origin of Oil—A Creationist Answer - Answers in Genesis 1 February 2010 3:34 UTC www.answersingenesis.org [Source type: FILTERED WITH BAYES]
Other geographic locations with connections to the industry have since characterized themselves as Siliconia as well, for example
Silicon Forest in
Oregon,
Silicon Hills in
Austin,
Silicon Saxony in
Germany, and
Silicon Border in
Mexicali.
See also
References
- ^ R. S. Ram et al. "Fourier Transform Emission Spectroscopy of the A2D–X2P Transition of SiH and SiD" J. Mol. Spectr. 190, 341–352 (1998)
- ^ Magnetic susceptibility of the elements and inorganic compounds, in Handbook of Chemistry and Physics 81st edition, CRC press.
- ^ a b c d http://www.ioffe.ru/SVA/NSM/Semicond/Si
- ^ "Silicon: the essentials". WebElements Ltd.. http://www.webelements.com/silicon/. Retrieved 2009-09-30.
- ^ Nielsen, FH (1984). "Ultratrace Elements in Nutrition". Annual Review of Nutrition 4: 21–41. doi:10.1146/annurev.nu.04.070184.000321. PMID 6087860.
- ^ Weeks, Mary Elvira (1932). "The discovery of the elements: XII. Other elements isolated with the aid of potassium and sodium: beryllium, boron, silicon, and aluminum". Journal of Chemical Education: 1386–1412.
- ^ . doi:10.1134/S1070427207120397.
- ^ "Phosphorus - 32". sciencegateway.org. http://sciencegateway.org/isotope/phosp32.html. Retrieved 2008-02-20.
- ^ "Metallurgical silicon could become a rare commodity – just how quickly that happens depends to a certain extent on the current financial crisis". Photon International. http://www.photon-magazine.com/news_archiv/details.aspx?cat=News_PI&sub=worldwide&pub=4&parent=1555. Retrieved 2009-03-04.
- ^ "Silicon". usgs.gov. http://minerals.usgs.gov/minerals/pubs/commodity/silicon/silicmcs06.pdf. Retrieved 2008-02-20.
- ^ Rao, Gopalakrishna M. (1980). "Electrowinning of Silicon from K2SiF6-Molten Fluoride Systems". Journal of the Electrochemical Society 127: 1940. doi:10.1149/1.2130041.
- ^ De Mattei, Robert C. (1981). "Electrodeposition of Silicon at Temperatures above Its Melting Point". Journal of the Electrochemical Society 128: 1712. doi:10.1149/1.2127716.
- ^ R. Monnier et al. "Dual cell refining of silicon and germanium" U.S. Patent 3,219,561 Issue date: Nov 1965
- ^ R. Monnier et al. "Refining of silicon and germanium" U.S. Patent 3,254,010 Issue date: May 1966
- ^ H. St. C. Deville (1854). "Recherches sur les métaux, et en particulier sur l'aluminium et sur une nouvelle forme du silicium". Ann. Chim. Phys. 43: 31. http://gallica.bnf.fr/ark:/12148/bpt6k34784b.image.f31.langFR.
- ^ O'Mara, William C. (1990). Handbook of Semiconductor Silicon Technology. William Andrew Inc.. p. 349–352. ISBN 0815512376. http://books.google.com/books?id=COcVgAtqeKkC&pg=PA351&dq=Czochralski+Silicon+Crystal+Face+Cubic&lr=&as_brr=3&sig=ht-dgSy1lzBMYC7IXPp9W5QBqYo. Retrieved 2008-02-24.
- ^ "Analyst_silicon_field_trip_March_28,_2007". hugin.info. http://hugin.info/136555/R/1115224/203491.pdf. Retrieved 2008-02-20.
- ^ a b c d e f g h i j Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.
- ^ a b c d e f g h Holleman, A. F.; Wiberg, E.; Wiberg, N. (2001). Inorganic Chemistry, 1st Edition. Academic Press. ISBN 0123526515.
- ^ (Multiply Bonded Main Group Metals and Metalloids: Multiple Bonded Main Group Metals and Metalloids, F. G. Stone, Robert West, Academic Press, 1996, ISBN 0120311399)
- ^ Sekiguchi, A; Kinjo, R; Ichinohe, M (2004). "A stable compound containing a silicon-silicon triple bond.". Science (New York, N.Y.) 305 (5691): 1755–7. doi:10.1126/science.1102209. PMID 15375262.
- ^ a b Lickiss, Paul D. (1994). Inorganic Compounds of Silicon, in Encyclopedia of Inorganic Chemistry. John Wiley & Sons. pp. 3770–3805. ISBN 0471936200.
- ^ a b Mark, James. E (2005). Inorganic polymers. Oxford University Press. pp. 200–245. ISBN 0195131193.
- ^ Koch, E.C.; Clement, D.. Special Materials in Pyrotechnics: VI. Silicon - An Old Fuel with New Perspectives. http://www3.interscience.wiley.com/cgi-bin/abstract/114279686/ABSTRACT.
- ^ Walsh, Tim (2005). "Silly Putty". Timeless toys: classic toys and the playmakers who created them. Andrews McMeel Publishing. ISBN 9780740755712. http://books.google.com/books?id=jftapGDTmYUC&pg=PA90.
- ^ Prof. W. Earl Bardsley, Department of Earth and Ocean Sciences, University of Waikato, Private Bag 3105, Hamilton, 3240, New Zealand. "The Sustainable Global Energy Economy: Hydrogen or Silicon?". Springer Link. http://www.springerlink.com/content/4m534g6833jv7487/.
External links